Behaviour of some pesticides in a nutrient-film and in a rock-wool system

Adsorption of ethoprophos, tetrachlorvinphos and etridiazole onto rock-wool was found to be much weaker than adsorption onto soils. The rates of transformation in water and in water plus rock-wool at 20°C were low. The concentration of etridiazole was measured in a nutrient-film system with recirculating nutrient solution. The decrease was rapid in the first few hours but was more gradual afterwards, to low values at 8 days after application. Etridiazole penetrated poorly into the lower part of a rock-wool system when the solution was trickled near the stem-base of the tomato plants.     

Computed leaching of pesticides from soil under field conditions

With a computer model, pesticide behavior in soil after spring application to a sandy loam field with a potato crop, was simulated. Special attention was paid to the risk of leaching through the upper meter of soil in catchment areas. Unsaturated water flow resulting from rainfall was modeled in some detail. Uptake of water and solute by the developing root system of the annual crop was included in the model. The computations were carried out for hypothetical pesticides with first-order decomposition rate constants in soil of 0.03, 0.01, 0.003, and 0.001 day^–1 at 20°C. Adsorption decreased with increasing soil depth and the adsorption coefficient for the top layer ranged from 0.0 to 10.0. For 20 combinations of decomposition rates and adsorption strengths, the extent of leaching from a top layer 1 m thick was computed. With a decomposition rate constant at 20°C of 0.03 day^–1 or higher, leaching was extremely low; with 0.01 days^–1 leaching was 1.7% of the dosage or lower. For compounds with a high persistence and mobility, leaching from the soil ranged up to about 10% of the dosage or more. Besides decomposition, uptake by plants was an important factor in reducing leaching, particularly for the weakly adsorbed and comparatively persistent compounds.     

Emission of methyl isothiocyanate to the air after application of metham-sodium to greenhouse soil

Greenhouse soils are regularly treated with metham-sodium, which in soil is quickly transformed to the fumigant methyl isothiocyanate. An experimental fumigation was carried out in a greenhouse with sandy soil. Data were collected on the behavior of methyl isothiocyanate in soil and its permeation through a film of low-density polyethene (LDPE) covering the soil. This cover was found to be highly permeable to methyl isothiocyanate. When the fumigation of greenhouse soil was simulated with a computation model, the use of LDPE film only appreciably reduced the rate of emission into the air in the first two days. The cumulative emission corresponded to about half of the dosage for some practical situations. It is concluded that dosages should be lower and applied more effectively, and less permeable soil covers should be used.     

Measured and computed concentration patterns of propyzamide in field soils

The persistence of propyzamide in soil was studied by analysing soil samples taken at intervals two or three times after application in the spring to experimental fields. Single samples were taken from other fields. 8 to 12 months after autumn application. The concentrations were measured by electron-capture gas chromatography. Persistence is expressed in first-order dissipation rate constants and half-life values. Data were measured and collected on the adsorption of propyzamide on soils, the soil characteristics and the weather conditions. Computations of the mobility of propyzamide in soil were carried out for simplified systems. Results of measurements and computations are compared.     

Behaviour of metamitron and hydroxy-chlorothalonil in low-humic sandy soils

The behaviour of the herbicide metamitron and of the main transformation product, hydroxy-chlorothalonil (HTI), of the fungicide chlorothalonil was studied to assess the risk of leaching from low-humic sandy soil. The adsorption of metamitron corresponded to a K_om value of about 60 dm³ kg⁻¹ (moderate adsorption). The half-life of metamitron in soil at 15 °C was only three days, presumably due to adaptation of the micro-organisms. In the autumn, the residue of metamitron in the soil profiles corresponded to less than 1% of the cumulative dosage. The half-life of chlorothalonil at 15 °C was about 12 days and about 45% of it was transformed to HTI. The adsorption of HTI to the soils corresponded to a K_om value of 260 dm³ kg⁻¹. The incubation study (15 °C) showed the transformation of HTI in the soils to be very slow. The amounts of HTI remaining in the soil profiles in the autumn corresponded to 4 and 16% of the cumulative dosage of chlorothalonil. In winter, the HTI residue decreased by 40% relative to the autumn level. Occasionally, HTI could be detected in the upper ground-water level (at a depth of about 1 m), at an average concentration of 0.1 to 0.2 µg dm⁻³. © 1999 Society of Chemical Industry     

Movement and conversion of aldicarb and its oxidation products in potato fields

In Spring, the insecticide and nematicide aldicarb in the granular formulation Temik 10G (supplied by Union Carbide) was broadcast on three potato fields and incorporated by rotary cultivation. Ridges were formed by repeated runs with ridging implements. The soil was sampled in layers of 0.1 m up to 0.8 m depth three to four times during the growing season. Aldicarb itself was almost completely converted on a humic sand soil and two loam soils within one month. During the growing season, its sulphoxide and sulphone, which are toxic and are formed by oxidation, were retained mainly in the top 0.3 m of all three soils. Relatively high concentrations were measured only in the top 0.2 m, indicating limited redistribution by leaching.Low to very low contents were found up to 0.8 m depth especially on one of the loam soils where the highest total rainfall was measured from May to October (328 mm). In a humic sand soil, leaching in the furrow was deepter than below the ridge. At the end of the growing season, the sulphoxide plus sulphone corresponded to a mass fraction of 5.7 to 6.7% of the dosage in the two loam soils and to 17% in the humic sand soil. These residues were mainly concentrated in the centre of the ridges.Samenvatting In het voorjaar werd op drie aardappelvelden het insecticide en nematicide aldicarb als Temik 10G breedwerpig toegediend en met een frees ingewerkt. Ruggen werden opgebouwd door herhaalde bewerkingen met aanaardwerktuigen. Gedurende het groeiseizoen werd de grond drie tot viermaal bemonsterd in laagjes van 0,1 m tot op 0,8 m diepte. Aldicarb zelf was binnen een maand bijna geheel omgezet zowel in een humeuze zandgrond als in twee zavelgronden. Gedurende het groeiseizoen bleven het sulfoxide en het sulfon, welke produkten eveneens toxisch zijn en door oxidatie van aldicarb worden gevormd, voornamelijk in de toplaag van 0,3 m bij alle drie gronden. Relatief hoge concentraties werden alleen gemeten in de bovenste 0,2 m, wat wijst op een beperkte herverdeling door uitspoeling.Lage tot zeer lage gehalten werden tot 0,8 m diepte gevonden, met name in één van de zavelgronden waar ook de grootste hoeveelheid neerslag van mei tot oktober (328 mm) werd gemeten. In een humeuze zandgrond was de uitspoeling in de voor groter dan die beneden de rug. Aan het eind van het groeiseizoen kwam de hoeveelheid resterend sulfoxide plus sulfon in de twee zavelgronden overeen met een massafractie van 5,7 tot 6,7% van de dosering en in de humeuze zandgrond met 17%. Deze residuen waren voor het grootste deel geconcentreerd in het centrum van de ruggen.     

Non-pruritic granuloma in Norwegian forest cats

The eosinophilic granuloma complex is a group of skin disorders common in cats. This paper describes the clinical, haematological and histopathological features of 17 related Norwegian forest cats, six of which had a linear granuloma on the caudal thigh, three of which also had a granuloma on the lower lip, and one of which had a granuloma in combination with an indolent ulcer. The high prevalence of the disease in this population is suggestive of a genetic background.     

Conversion rates of aldicarb and its oxidation products in soils. II. Aldicarb sulphoxide

The loss of aldicarb sulphoxide was studied in incubation experiments with soil from four plough layers and two deeper layers. The loss during the 111 days of the experiment could be described by first-order kinetics. The half-lives at 15°C ranged from 20 days in a clay loam to 46 days in a peaty sand. The loss of sulphoxide in deeper layers was considerably slower than in the corresponding top layers of a soil profile. In soil from a silty layer at 70–90 cm depth the half-life was about 53 days. In soil from a sand layer at 90–110 cm depth a loss of only about 15% was measured after 111 days of incubation. First-order rate constants for sulphoxide conversion in a clay loam at 6, 15 and 25°C were found to be 0.009, 0.033, and 0.05 day^?1 respectively; in a greenhouse soil these rate constants were 0.0052, 0.019 and 0.04 day^?1 respectively. The fractions of aldicarb sulphoxide that were oxidised to sulphone at 15°C in soil from plough layers were computed to range from 0.52 to 0.76.