Can forest-soil liming mitigate acidification of surface waters in Sweden?

Acidification of surface waters and forest soils is severe in large parts of southern Sweden. The shallow groundwaters are also affected. Large scale liming of surface waters and streams is in operation, often combined with wetland liming to limit the effects of acid episodes, e.g. at snow melt. Acid episodes are perhaps the most severe problem in limed surface waters and in many as yet well buffered waters, because of temperature-layered acid inflow, often superficial. As a result of some investigations, a large scale forest liming programme covering 6.500–10.000 km² was recently suggested. The main objectives of this forest liming programme are to retard cation depletion and to prevent nutrient imbalance and forest decline in acidified areas. This paper deals with the effects of forest soil liming on streams and surface waters. The response of water chemistry is very dependent on hydrological and soil properties. Although pH itself may be little affected by liming, the acidity (or negative ANC) decreases, inorganic Al-species decrease and the Al/BC-ratio increases in the runoff water. Especially interesting is that this is also true during acid episodes. This means that toxicity for acid sensitive biota decreases. These results indicate that large scale liming may have beneficial effects on surface water chemistry. Furthermore, as surface waters are expected to respond to smaller decreases in acid deposition than do forests soils, forest soil liming may allow less frequent liming of lakes. Consequently, forest soil liming in combination with the anticipated emission reductions may have very beneficial results on surface waters in certain areas of Sweden.     

Output of methylmercury from a Catchment in northern Sweden

The runoff output of methylmercury (MeHg) from the 50 ha Svartberget Catchment in northern Sweden was studied during 1993. These outputs are compared to those from the Gårdsjön Catchment in the southwestern part of Sweden. Although the wet deposition of MeHg is several times higher in southern Sweden the output of MeHg per unit area from the two catchments was comparable (0.12 g /km_* ²yr). Furthermore, the concentration of MeHg (0.4 ng/L) in the Svartberget Catchment was more than twice that from the Gårdsjön Catchment. These results suggest that the contemporary wet deposition of MeHg in itself is not a good indicator of runoff concentration or output per unit area. DOC transport and catchment characteristics such as wetland area, or possibly other forms of contemporary atmospheric deposition may all be more important for explaining MeHg output from the terrestrial ecosystem.     

Recovery from acidification in Lake Örvattnet,Sweden

Lake Örvattnet has been monitored extensively for both chemical and biological variables since 1967. The lake acidified during the 1960's and pH was mostly below 5 throughout the 1970's. Due to the acidification, peat moss (Sphagnum spp.) expanded over the lake bottom and the only surviving fish species was perch (Perca fluviatilis), but it experienced reproduction problems. In the mid 1980's, the Sphagnum cover collapsed, and by 1989 it had almost disappeared. There has been a clear recovery of the perch population. Recovery of the lake is also recorded by diatom assemblages in the lake sediment. Diatom-inferred pH increased from 4.7 to 4.9. The development of measured lake-water pH is unclear, but acid episodes in spring have become less severe. By 1993, atmospheric sulphate deposition had decreased by 30–40% in this area of Sweden compared to the late 1960's. Lake-water sulphate concentrations have decreased by ～30% since the 1960's. Nitrogen deposition has increased over the last decades, but is not yet contributing to lake acidification. No major land-use changes have occurred and changes in hydrology cannot explain the observed changes in chemistry and biology. We ascribe the recent recovery in the lake to reduced deposition of sulphate. In conclusion, Lake Örvattnet has begun to recover from acidification.     

Monitoring of heavy metals in protected forest catchments in Sweden

Long-term integrated catchment monitoring within the Swedish Environmental Monitoring Programme (PMK) aims primarely at the fate and effects of pollutants in mature ecosystems, mainly protected boreal forests. The measurements that were conducted since the early eighties, with some variation, included deposition, throughfall, litterfall and the chemistry of soil water, groundwater and runoff water.Together with, or perhaps partly due to acidification, accumulation and transport of heavy metals are a serious threat to the ecosystem and in the end to the health of human beings. This paper discuss the behaviour of Hg, Pb, Cd, Zn and Cu based on the experiece gained from the studies in the small catchment areas. The importance of present deposition, soil storage and biogeochemical condition for metal mobility to the transport of metals is discussed The storages of Hg and Pb have been built up during a long time span and are very large in comparison with the flux. The present atmospheric deposition have probably little impact on the flux, which rather is governed by the biogeochemical conditions. There is still a small accumulation of Cd, but its great mobility under acidic conditions makes input and output almost in balance. A reduction in deposition will probably have an immediate effect on flux, which also is the case for Zn. Cu generally accumulates in soil. The mobility and hence the flux are certainly regulated by the biogeochemical conditions, but more detailed studies are required to reveal the general mecanisms for Cu transport within the catchment.     

Impacts from Deposition on Swedish Forest Ecosystems Identified by Integrated Monitoring

Integrated monitoring of ecosystems (IM) is an international co-operative programme (ICP) to control effects of air pollution and climate change on water, soil and biological systems. It is a part of the Convention on Long-Range Transboundary Air Pollution (CLRTAP) of the United Nations Economic Commission of Europe (UN/ECE). The ICP-IM is undertaken on sites/catchments to investigate acidification, eutrophication and heavy metals with an integrated approach. In Sweden, long-term time series from forest ecosystems, with a long and stable continuity, will reveal trends and changes in processes and enable modelling to be undertaken. Investigations of acidity/alkalinity in relation to mineral and organic acids indicated the importance of atmospheric deposition. Recent results show very high inorganic nitrogen retention (99%), a net loss of sulphur originating mainly from organic horizons, and a high inorganic aluminium content in the illuvial soil horizons which could be detrimental to forests. Forest deficiency could also be caused by an observed ongoing translocation of Zn to deeper soil layers implying a movement towards increased release to surface waters.     

Liming and reacidification reactions of a forest lake ecosystem,lake Lysevatten,in SW Sweden

Long-term monitoring, 1973 to 1987, of reactions to liming and reacidification of a forest lake ecosystem near the Swedish west coast is reported in this study. Treatment of Lake Lysevatten with a slag product of limestone in 1974 resulted in neutralization and a positive alkalinity. Prolonged dissolution proceeded for about 7 yr whereby 86% dissolved. During 1984–86 Lake Lysevatten approached maximum reacidification with high Al concentrations and an affected biota. Asellus aquaticus L. decreased and dominance within chironomid groups approached preliming conditions. However, the most obvious biological change was the development of the filamentous algal genus Mougeotia and increased growth of Sphagnum. Populations of both plants increased notably when pH declined to about 5. Our study suggests that extensive reacidification (pH < 6.0) of limed lakes should be avoided by successive treatments to prevent development of destabilized lake ecosystems.     

Effects on soils and leaching after application of dolomite to an acidified forested catchment in the Lake Gårdsjön watershed,south-west Sweden

The dry forest soils (80%) of a 3.3 ha catchment in Gårdsjön, were treated with 1.5 ton/ha dolomite in 1984. In half the catchment an additional dose of 4.5 ton/ha was added in 1986 (i.e. totaly 6 ton/ha). By 1991 the concentrations of exchangeable calcium and magnesium had increased by 450% to 800% in the humus layer and upper 0–5 cm of the mineral soils and by 500% and 300%, respectively, in the 5–10 cm and 10–20 cm soil depth in the 6 ton/ha part. By 1.5 ton, Ca and Mg increased in humus and 0–5 cm in the mineral soil. Potassium decreased in the humus and the mineral soil with both 1.5 ton and 6 ton per ha. The accumulated output of K by runoff was however only 1 kg during the 6 years until 1992, which indicates that the losses from the soil also may have resulted in increased uptake by the forest. Tree growth and nutrient content in current needles was, however, unchanged. Increased contents of Mg, Ca and Zn was observed in some species of ground vegetation. Nitrate and ammonium concentrations and fluxes in runoff were identical to the reference catchment, while inorganic Al and Mn decreased by 40–50% and H⁺ by 30%. The accumulated extra output by runoff of Mg was about 7% and of Ca 0.6% of the amounts applied by the two treatments in 1984 and 1986.     

Fermentation of Cauliflower and White Beans with Lactobacillus plantarum – Impact on Levels of Riboflavin,Folate, Vitamin B12, and Amino Acid Composition

Plant Foods for Human Nutrition - As diets change in response to ethical, environmental, and health concerns surrounding meat consumption, fermentation has potential to improve the taste and...     

Results from the Covered Catchment Experiment at Gårdsjön, Sweden, after Ten Years of Clean Precipitation Treatment

The Covered Catchment Experiment at Gårdsjön is a large scale forest ecosystem manipulation, where acid precipitation was intercepted by a 7000 m² plastic roof and replaced by `clean precipitation' sprinkled below the roof for ten years between 1991 and 2001. The treatment resulted in a strong positive response of runoff quality. The runoff sulphate, inorganic aluminium and base cations decreased, while there was a strong increase in runoff ANC and a moderate increase in pH. The runoff continued to improve over the whole duration of the experiment. The achieved quality was, however, after ten years still considerably worse than estimated pre-industrial runoff at the site. Stable isotopes of sulphur were analysed to study the soil sulphur cycling. At the initial years of the experiment, the desorption of SO₄ from the mineral soil appeared to control the runoff SO₄ concentration. However, as the experiment proceeded, there was growing evidence that net mineralisation of soil organic sulphur in the humus layer was an additional source of SO₄ in runoff. This might provide a challenge to current acidification models. The experiment convincingly demonstrated on a catchment scale, that reduction in acid deposition causes an immediate improvement of surface water quality even at heavily acidified sites. The improvement of the runoff appeared to be largely a result of cation exchange processes in the soil due to decreasing concentrations of the soil solution, while any potential change in soil base saturation seemed to be less important for the runoff chemistry over the short time period of one decade. These findings should be considered when interpreting and extrapolating regional trends in surface water chemistry to the terrestrial parts of ecosystems.     

Gårdsjön Project: lake acidification,chemistry in catchment runoff,lake liming and microcatchment manipulations

The Gårdsjön Project is an ecosystem approach in studying acid deposition and its effects on terrestrial parts and lakes within a catchment. The study is an attempt to quantify the processes causing the acidification as well as an analyses of the chemical and biological conditions before liming of the lake and manipulations in microcatchments. This paper gives a brief overview of some studies already performed and recently started experiments within the project, such as lake liming, lime application on land, forest fertilization, clearcutting and applications of acid and neutral sulphate on land.