An Analysis of Urban Size and Territorial Location Effects on Employment Probabilities: The Spanish Case

The probability of being employed varies depending on several factors. Many of these are related to personal characteristics such as educational level, age, gender, or number and age of children. Nevertheless, other factors may be relevant, in particular the geographical environment. The purpose of this paper is to analyse the relevance of urban size and the position of each territory (in terms of its distance from large metropolises) for the probability of being employed in the Spanish economy. Following the set of economic regions suggested by Polése, Shearmur and Rubiera (2007 ), we try to explain the spatial patterns of employment distribution. Our results show some relevant differences between these alternative economic areas. We find that municipalities with similar sizes and located at a similar distance from a metropolis but belonging to different Autonomous Communities or provinces share similar employability patterns.     

Calcium ions make phytohemagglutinin resistant to trypsin proteolysis

To investigate the mechanism of phytohemagglutinin (PHA) susceptibility or resistance to the action of proteolytic enzymes, its in vitro proteolysis by trypsin was studied. It was found that Ca (2+) gives resistance to the native PHA molecule to trypsin proteolysis. In the absence of Ca (2+) trypsin performs a thorough hydrolysis of PHA. At the first stage of trypsin hydrolysis of PHA the formation of a relatively stable high molecular mass product occurs (PHA-T) as a result of non-co-operative proteolysis. At the second stage, the degradation of PHA-T occurs, and this degradation is performed by parallel co-operative proteolysis. This type of proteolysis differs from the action of trypsin on phaseolin, the main storage protein from common bean ( Phaseolus vulgaris L.). The implications of Ca (2+)influence of PHA hydrolysis by trypsin are discussed.     

The percolation phase transition in sea Ice

Sea ice exhibits a marked transition in its fluid transport properties at a critical brine volume fraction pc of about 5 percent, or temperature Tc of about -5 degreesC for salinity of 5 parts per thousand. For temperatures warmer than Tc, brine carrying heat and nutrients can move through the ice, whereas for colder temperatures the ice is impermeable. This transition plays a key role in the geophysics, biology, and remote sensing of sea ice. Percolation theory can be used to understand this critical behavior of transport in sea ice. The similarity of sea ice microstructure to compressed powders is used to theoretically predict pc of about 5 percent.