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It was reported in a preceding paper7) that the Ando soils from Uemura, Choyo, and Kawanishi contained an unknown mineral colloid which was distinctly different in some respects from coexisting allophane. In the Uemura soil, this clay fraction made up more than 20 per cent of the total clay and more than 6 per cent of the soil7). 相似文献
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Naganori Yoshinaga 《Soil Science and Plant Nutrition》2013,59(6):238-246
In this paper are described the properties of filmy gel substances occurring in the Imaichi (Imaichi-tsuchi) and Shichihonzakura (formerly called Jobukanuma-tsuchi (2,5)) pumice beds. The properties of such filmy materials from the Kanuma (Kanuma-tsuchi) , Imaichi, and Kitakami pumice beds have been described by many investigators (1,8, 9, 10,12, 13, 14, 15, 19, ). KANNO et al. (9) concluded that they were a mixture of poorly crystalline montmorillonite, allophane, and free sesquioxides. However, the presence of montmorillonite as an important constituent has been disproved by MIYAUCHIA nd AOMINE (12), ho concluded that the gel films from the Kitakami and Kanuma pumice beds consist principally of imogolite. 相似文献
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Toru Takahashi Makoto Miura Naganori Ohisa Katsumi Mori Shoichi Kobayashi 《Cereal Chemistry》2005,82(2):228-232
The effects of autoclave and oven treatments on the gelatinization of rice flour and on the rheological characteristics of its pastes were studied by differential scanning calorimetry (DSC), rapid viscoanalysis (RVA), and rotational viscometry. Flours from autoclave‐treated rice (ATR) and oven‐treated rice (OTR) were prepared, respectively, by heating at 120°C for 60 min and 160°C for 60 min followed by drying (ATR sample), and grinding at 2.2–12.9% moisture content. The rice flour dispersions were adjusted between pH 6.3 and 2.8 using 0.2M citrate buffer. The retort processing of rice flour in water pastes were done at 120°C for 20 min either once or twice. The gelatinization peak temperature (PT and To) and the peak temperature corresponding to the amylose‐lipid complexes (Tp3) of ATR increased at pH 6.3 and 2.8 compared with OTR and UTR flour. This indicates that the internal structures of the starch granules in ATR became more stable to heat and acid, even though the damaged starch content of ATR was 23% compared with 16 and 7%, respectively, for untreated rice flour (UTR) and OTR. The OTR flour pastes showed a gel‐like behavior at pH 4.5 after retort processing in water at 120°C for 20 min; however, the ATR mixture behaved more like a liquid paste. Decreases in the reducing sugar content of OTR and ATR pastes suggested that enzymes in the heat‐treated rice were denatured, which retarded the hydrolysis of glucose chains and the rupture of starch granules during pasting. 相似文献
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Allophane has been known to occur widely in volcanic ash soils in Japan and New Zealand. However, exact knowledge of its nature has not been well established, mainly because of extreme difficulty to separate it in pure state and of its x-amorphous nature. In the course of the studies on soil allophane, it was noticed that certain Ando soils contained two different mineral colloids together, in addition to crystalline clay minerals and free sesquioxides. X-ray examination revealed that one was x-amorphous colloid which would be called allophane, and the other an unknown colloid of low crystallinity. Imogolite*** was proposed as the name of the latter colloid by the present authors after imogo in which imogolite was first found. Imogo is a brownish yellow, volcanic ash soil. in the Kuma basin in the Kumamoto Prefecture3). When deferration treatment is applied to the soils, allophane disperses both in an acid and alkaline media, whereas imogolite disperses in an acid medium and flocculates in an alkaline one. 相似文献
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Although many investigations have been carried out on the reaction of phosphates with allophane as well as with crystalline clays, they have been almost with the orthophosphates (2, 13, 19, 21). Recent investigations have revealed that certain condensed phosphates (polyphosphates) have a considerable promise as a long-term, slow-release source of phosphorus for plants (3, 7, 9, 10. 14, 17. 18, 20. 25). Relatively little information is available, however, on the reaction of those substances with soil clay minerals (8. 15). 相似文献
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In the determination of Si in dithionite-citrate-bicarbonate (DCB) extract (2) by the molybdenum blue heteropply method, the color develppment, is interfered by the presence of dithionite and citrate. Weaver el al. (4) have eliminated the interference by introducing air-bubbling for oxidation of the former and by the use of a large excess of molybdate solution as a complexing agent of the latter. This method, while,giving satisfactory results, has a disadvantage that air-bubbling is time-consuming. Moreover it often occurs that the analysis is delayed also due to the limitation of bubbling facilities particularly when many samples are treated at a time. 相似文献
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Since its first discovery in 1962 (24, 25), imogolite has been known to occur widely in ando-sols from subfrigid to temperate to tropical regions(1, 2, 3, 6, 7, 9, 14) and, peculiarly as gel films, in certain weathered pumice beds of Japan (11, 23). Its morphology and chemical and mineralogical properties have been investigated fairly well and the investigations have reached the 'stage where its structural models can be hypothesized (13, 16, 19, 20, 26). Relatively little attention has been paid, however, to the mechanism of its formation and to its genetic relationship to other clay minerals(18). Elucidation of these points will be very important in establishing imogolite as a member of weathering sequence in soils, and for this to be done will be needed much more extensive study of its distribution, clay mineral suits associated, environmental conditions in soils, etc. 相似文献
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