The Ogallala Agro-Climate Tool

A Visual Basic™ agro-climate application capable of estimating crop evapotranspiration and irrigation demand over the Ogallala aquifer region is described here. The application's meteorological database consists of daily precipitation and temperature data from 141 U.S. Historical Climatology Network stations during 1976-2005. From that daily data the program calculates climate and crop evapotranspiration (ET_c) statistics over arbitrarily defined periods within summer or winter growing seasons at user-selected latitude-longitude coordinates. The statistics reported include: estimates of seasonal and sub-seasonal ET_c derived from the FAO-56 single crop coefficient algorithm, probabilities of exceedance of cumulative rainfall, irrigation demand and growing degree days, the probability that minimum and maximum daily temperatures will exceed user-defined temperature thresholds, and the probability of heat stress, cold stress and dry periods of varying duration.     

Contaminants in Arctic Snow Collected over Northwest Alaskan Sea Ice

Snow cores were collected over sea ice from four northwest Alaskan Arctic estuaries that represented the annual snowfallfrom the 1995–1996 season. Dissolved trace metals, major cationsand anions, total mercury, and organochlorine compounds weredetermined and compared to concentrations in previous arctic studies. Traces (<4 nanograms per liter, ng L^-1) of cis- and trans-chlordane, dimethyl 2,3,5,6-tetrachloroterephthalate, dieldrin, endosulfan II, andPCBs were detected in some samples, with endosulfan I consistently present. High chlorpyrifos concentrations (70–80 ng L^-1) also were estimated at three sites. The snow washighly enriched in sulfates (69–394 mg L^-1), with highproportions of nonsea salt sulfates at three of five sites (9 of 15 samples), thus indicating possible contamination throughlong-distance transport and deposition of sulfate-rich atmospheric aerosols. Mercury, cadmium, chromium, molybdenum, and uranium were typically higher in the marine snow (n = 15) in relation to snow from arctic terrestrial studies, whereas cations associated with terrigenous sources, such as aluminum,frequently were lower over the sea ice. One Kasegaluk Lagoon site (Chukchi Sea) had especially high concentrations of totalmercury (mean = 214 ng L^-1, standard deviation = 5 ng L^-1), but no methyl mercury was detected above the method detection limit (0.036 ng L^-1) at any of the sites. Elevated concentrations of sulfate, mercury, and certain heavymetals might indicate mechanisms of contaminant loss from the arctic atmosphere over marine water not previously reported overland areas. Scavenging by snow, fog, or riming processes and thehigh content of deposited halides might facilitate the loss of such contaminants from the atmosphere. Both the mercury and chlorpyrifos concentrations merit further investigation in view of their toxicity to aquatic organisms at low concentrations.     

An Exploratory Investigation of Polar Organic Compounds in Waters from a Lead�CZinc Mine and Mill Complex

Surface water samples were collected in 2006 from a lead mine?Cmill complex in Missouri to investigate possible organic compounds coming from the milling process. Water samples contained relatively high concentrations of dissolved organic carbon (DOC; greater than 20 mg/l) for surface waters but were colorless, implying a lack of naturally occurring aquatic humic or fulvic acids. Samples were extracted by three different types of solid-phase extraction and analyzed by electrospray ionization/mass spectrometry. Because large amounts of xanthate complexation reagents are used in the milling process, techniques were developed to extract and analyze for sodium isopropyl xanthate and sodium ethyl xanthate. Although these xanthate reagents were not found, trace amounts of the degradates, isopropyl xanthyl thiosulfonate and isopropyl xanthyl sulfonate, were found in most locations sampled, including the tailings pond downstream. Dioctyl sulfosuccinate, a surfactant and process filtering aid, was found at concentrations estimated at 350 ??g/l at one mill outlet, but not downstream. Release of these organic compounds downstream from lead?Czinc mine and milling areas has not previously been reported. A majority of the DOC remains unidentified.