A new sensitive and portable mercury vapor analyzer Gardis-1A

A possibility to build a mercury (Hg) analyzer based on the cold vapor atomic absorption spectrometry (CVAAS) with a sub-picogram detection limit was investigated. Construction of the gold traps and the optical cell, carrier gas flow rate and gold traps heating power were chosen in order to effectively concentrate sampled Hg vapor and to obtain highest possible response in the optical and electronic system. The newly created analyzer is able to detect 0.5 pg of elemental Hg vapor. Optimization of construction resulted in stable performance and good selectivity for gaseous Hg of the analyzer. The instrument is commercially available.     

Crop stand density enhances competitive ability of spring barley (Hordeum vulgare L.)

Abstract

The aim of the research was to establish weediness, competitive ability and productivity of the crop. The experimental object was agrophytocenoses of spring barley – Hordeum vulgare L. – crop of spring barley ‘Aura’ and unsown soil, and weeds growing in them. The crop was formed sowing 0, 120, 200 and 280 kg ha^?1 (0, 2.7, 4.5 and 6.2 million seeds per ha^?1 respectively) seeds of spring barley ‘Aura’. Spring barley crop was not harrowed and herbicides were not applied. In the field experiment estimates were made of changes of weeds and spring barley inter- and within- species competition optimizing crop density. During three years of field experiment in the crop of spring barley annual weeds prevailed at 88–99%, such as Chenopodium album, Stellaria media, Erysimum cheiranthoides. Perennial weeds formed 1–12% of the crop weeds, such as Sonchus arvensis, Cirsium arvense, Equisetum arvense. General number of weed species in spring barley crops varied from 13 to 21. Weed abundance proportionally declined in the crops of higher density, hence, higher seed rate should be recommended for organic agriculture where weeds are controlled in non-chemical ways. Consistently increasing barley stand density, the competition between species (spring barley with weeds) gradually turned into competition within species (between barley plants) when a higher number of weaker and non-productive stems started forming. Spring barley yield did not significantly depend on the stand density. Increasing stand density enhanced cultivated crop yield to a certain level (200 kg ha^?1), since an increase in spring barley plant number resulted in the reduction in weight per plant and 1000 grain weight, which was compensated by an increase in the number of spring barley plants. Different spring barley density had an essential influence on the chemical composition of weeds which was similar to that of spring barley. Weeds accumulated the greatest amount of crude proteins, crude fat and crude fibre growing without spring barley.     

Denuder-based techniques for sampling,separation and analysis of gaseous and participate mercury in air

A denuder-based method for sampling and separating gaseous and participate mercury in the air is described. Two different denuder configurations developed in Vilnius, Lithuania (silver) and in Gothenburg, Sweden (gold) are compared. Data were acquired at different sampling locations around the cities of Vilnius and Gothenburg. The concentration of particulate Hg was found to be 0.04 to 0.40 ng m^?3 in the Vilnius region, and 0.11 to 0.57 ng m^?3 in the Gothenburg region. Intel-calibration results for the silver and gold denuders are presented. The results obtained by the two different denuder configurations and sampling set-ups display satisfactory agreement.     

Phylogenetic analysis of intestinal bacteria of freshwater salmon Salmo salar and sea trout Salmo trutta trutta and diet

The microbial diversity of culturable intestinal microflora of wild freshwater salmonid fishes salmon Salmo salar and sea trout Salmo trutta trutta juveniles (0+ years old) from the same environmental conditions were investigated by means of molecular identification techniques and analysis of diet. Significant differences in the intestinal microbial diversity were observed in different fish species. The predominant group in the intestinal tract of the salmon comprised representatives of the Enterobacteriaceae family (23%), Plesiomonas (19.2%) and Carnobacterium (15.3%). Predominant microbiota in sea trout intestinal tract were Enterobacteriaceae (52%), Aeromonas (22%) and Pseudomonas (14%). The results show that Enterobacteriaceae were predominant in the intestinal tract of the salmon and the sea trout juveniles raised on diets of different compositions. However, molecular identification of the intestinal microbiota at the species or genus level revealed differences in these fish species. Bacteria in the hindgut of salmon included Pragia and Serratia. However, bacteria in the gut contents of sea trout from the Enterobacteriaceae family were Buttiauxella, Enterobacter, Moellerella, Pantoea, Rahnella and Tiedjeia arctica. A novel phylotype of T. arctica is harbored in the intestinal tract of wild salmon, and may correspond to a previously undescribed species.     

Are cadmium, lead and mercury concentrations in mosses across Europe primarily determined by atmospheric deposition of these metals?

Purpose

This study aimed at investigating correlations between heavy metal concentrations in mosses and modelled deposition values as well as other site-specific and regional characteristics to determine which factors primarily affect cadmium, lead and mercury concentrations in mosses. The resulting relationships could potentially be used to enhance the spatial resolution of heavy metal deposition maps across Europe.

Materials and methods

Modelled heavy metal deposition data and data on the concentration of heavy metals in naturally growing mosses were integrated into a geographic information system and analysed by means of bivariate rank correlation analysis and multivariate decision trees. Modelled deposition data were validated annually with deposition measurements at up to 63 EMEP measurement stations within the European Monitoring and Evaluation Programme (EMEP), and mosses were collected at up to 7,000 sites at 5-year intervals between 1990 and 2005.

Results and discussion

Moderate to high correlations were found between cadmium and lead concentrations in mosses and modelled atmospheric deposition of these metals: Spearman rank correlation coefficients were between 0.62 and 0.67, and 0.67 and 0.73 for cadmium and lead, respectively (p?<?0.001). Multivariate decision tree analyses showed that cadmium and lead concentrations in mosses were primarily determined by the atmospheric deposition of these metals, followed by emissions of the metals. Low to very low correlations were observed between mercury concentrations in mosses and modelled atmospheric deposition of mercury. According to the multivariate analyses, spatial variations of the mercury concentration in mosses was primarily associated with the sampled moss species and not with the modelled deposition, but regional differences in the atmospheric chemistry of mercury and corresponding interactions with the moss may also be involved.

Conclusions

At least for cadmium and lead, concentrations in mosses are a valuable tool in determining and mapping the spatial variation in atmospheric deposition across Europe at a high spatial resolution. For mercury, more studies are needed to elucidate interactions of different chemical species with the moss.