Efficient near-infrared polymer nanocrystal light-emitting diodes

Conjugated polymers and indium arsenide-based nanocrystals were used to create near-infrared plastic light-emitting diodes. Emission was tunable from 1 to 1.3 micrometers--a range that effectively covers the short-wavelength telecommunications band--by means of the quantum confinement effects in the nanocrystals. The external efficiency value (photons out divided by electrons in) is approximately 0.5% (that is, >1% internal) and is mainly limited by device architecture. The near-infrared emission did not overlap the charge-induced absorption bands of the polymer.     

Increased inhibitory effect of cation as a clay-complex on fungi

The toxic effect of Ni, Cu, Ag, Cd, and Zn adsorbed to clay minerals on six fungal species was studied. In some cases the ions adsorbed to the clay were more effective as growth inhibitors than those in solution. This phenomenon was especially prominent with Cu and Ag. Though Ca was found to be non-toxic to the fungi, Ca-clay complexes inhibited fungal growth. It is postulated that clay may inhibit fungi through: (1) adsorptive effects when the cation is non toxic; and (2) direct heavy metal toxicity.     

Effect of potassium on soil structure in relation to hydraulic conductivity

The effect of exchangeable K⁺ on soil structure and permeability has been studied. A loamy sand, a light clay and a heavy clay soil were leached with solutions adjusted to potassium adsorption ratios (PAR) of 0.0, 0.72, 3.74 and ∞. Exchangeable K⁺ percentage (EPP) and hydraulic conductivity (HC) were measured on the leached soils. SEM observations on undisturbed soil samples were used to evaluate changes in soil structure and pore size.

EPP values for the three soils ranged as follows: 0.8–1.3, 5.5–9.2, 16.0–21.0 and 58.0–76.0 for PAR's of 0.0, 0.72, 3.74 and ∞, respectively. HC incrased slightly (20%) up to EPP values of about 20% for the loamy sand and heavy clay soil, while a decrease in HC corresponding to any increase of EPP was observed for the light clay soil. This soil was richer in illite and also exhibited higher affinity for K⁺. At the highest EPP values (58.0–76.0) HC of the three soils decreased to about 20% of the values measured for the Ca²⁺ saturated soils.

SEM observations were performed and Ca²⁺ saturated soils compared with the K⁺ enriched ones. Ca²⁺ treated loamy sand exhibited discrete clay aggregates located in the spaces between sand particles or attached to them. K⁺ enrichment resulted in the formation of a dense network of clay microaggregates filling up the pore space. The microaggregate structure of the two Ca²⁺ clay soils changed to a dense layer composed of much smaller particles following K⁺ enrichment. Pores were mostly smaller than 10 μm in the K⁺ soil compared to several tens of microns in the Ca²⁺ form.

SEM observations and the fact that clay content did not vary with depth suggest that dispersion of clay microaggregates and their rearrangement in situ were the major mechanisms involved in HC reduction, rather than long-range clay migration and the formation of a clay enriched layer with impeded drainage.     

Estimating aboveground biomass in forest and oil palm plantation in Sabah, Malaysian Borneo using ALOS PALSAR data

Conversion of tropical forests to oil palm plantations in Malaysia and Indonesia has resulted in large-scale environmental degradation, loss of biodiversity and significant carbon emissions. For both countries to participate in the United Nation’s REDD (Reduced Emission from Deforestation and Degradation) mechanism, assessment of forest carbon stocks, including the estimated loss in carbon from conversion to plantation, is needed. In this study, we use a combination of field and remote sensing data to quantify both the magnitude and the geographical distribution of carbon stock in forests and timber plantations, in Sabah, Malaysia, which has been the site of significant expansion of oil palm cultivation over the last two decades. Forest structure data from 129 ha of research and inventory plots were used at different spatial scales to discriminate forest biomass across degradation levels. Field data was integrated with ALOS PALSAR (Advanced Land-Observing Satellite Phased Array L-band Synthetic Aperture Radar) imagery to both discriminate oil palm plantation from forest stands, with an accuracy of 97.0% (κ = 0.64) and predict AGB using regression analysis of HV-polarized PALSAR data (R² = 0.63, p < .001). Direct estimation of AGB from simple regression models was sensitive to both environmental conditions and forest structure. Precipitation effect on the backscatter data changed the HV prediction of AGB significantly (R² = 0.21, p < .001), and scattering from large leaves of mature palm trees significantly impeded the use of a single HV-based model for predicting AGB in palm oil plantations. Multi-temporal SAR data and algorithms based on forest types are suggested to improve the ability of a sensor similar to ALOS PALSAR for accurately mapping and monitoring forest biomass, now that the ALOS PALSAR sensor is no longer operational.     

Adsorption von Wasser, Äthylenglycolmonoethyläther sowie Stickstoff und ihre Beziehung zu Eigenschaften deutscher und israelischer Bodenproben

Adsorption of Water, Ethylene Glycol Monoethyl Ether as well as Nitrogen and its Relation to Properties of German and Israeli Soil Samples To determine the specific surface area, samples taken from 140 soil horizons were selected and the significant physical and chemical properties were investigated. The specific surface area of the samples was determined by adsorption of H₂O, ethylene glycol monoethyl ether (EGME) and N₂. A comparison of the three methods shows that the specific surface area determined by the adsorption of H₂O and EGME does not differ significantly. However, the specific surface determined by N₂-adsorption differs markedly from the results obtained using the polar substances. As a dependent variable the specific surface area is mainly influenced by the clay content and clay mineral type. Further, the organic substance content as well as the iron- and manganoxide content have a more significant influence on the specific surface area the lower the clay content is, or the content of three layer minerals. As an independent variable, the specific surface area determined by adsorption of EGME, proved to be the characteristic soil factor which reflects the effective cation exchange capacity as well as the hygroscopicity with the highest degree of accuracy.     

Effect of Long-Term Effluent Recharge on Phosphate Sorption by Soils in a Wastewater Reclamation Plant

The Soreq recharge basins, used for wastewater reclamation employing the Soil-Aquifer Treatment (SAT) system, have been recharged, on average, by about 1,800 m depth of secondary effluent during their operation period of ～25 years. An estimated amount of ～6 kg P m^?2 was added to the soil/sediment column during this period. The objective of this study was to compare phosphorous sorption characteristics of representative pristine soils in the Soreq recharge site to those of the basin soils sampled after a long period of effluent recharge. Batch isotherm experiments were conducted: samples of one g of soil were equilibrated with 25 mL of 0.02 M NaCl solution containing 0–3.2 mM of phosphate for 7 days at 25± 1^°C and P sorption was measured. Long-term effluent recharge significantly decreased the maximum P sorption capacity of the top sandy soil (0.15–0.3 m) and only very slightly decreased maximum P isotherm capacity of the deep clayey-sand soil (10–10.5 m). The retention of P in the basin sandy soil primarily involved sorption and surface precipitation reactions on soil carbonates. In the basin clayey-sand soil, P was retained by its sorption on surfaces of Fe, Al, Mn oxide/hydroxides and clay minerals. Long-term effluent recharge increased EPC₀, (the equilibrium P concentration in solution at which there is no sorption or desorption to or from the soil under the given conditions), of the basin soils compared to the pristine soils. Due to loading of the top horizons with P by prolonged recharge and reduced P concentration in the effluent, EPC₀ of the basin sandy soil is now equal to the average P concentration of the recharged effluents. If effluent P concentration will decrease further, the top sandy soil will become a source of P to the reclaimed water, rather than a sink. The clayey-sand layers and lenses in the vadose zone of the SAT system of the Soreq site offer a large capacity for P adsorption. With gradual leaching of carbonate minerals and synthesis of secondary clay minerals, driven by long-term effluent recharge, P retention mechanisms in the basin soil may be changed, but this process would be extremely slow.     

Long-term accumulation and material balance of organic matter in the soil of an effluent infiltration basin

The fate of organic matter (OM) in large-scale infiltration basins used for wastewater treatment by the soil aquifer treatment (SAT) system was investigated. Measured changes in the organic matter concentrations in the soil profiles of the infiltration basins and detailed long-term records of OM concentrations in the recharged effluent and in the observation wells and recovery wells water, were used to calculate OM material balances in the SHAFDAN wastewater treatment plant, serving the City of Tel-Aviv, Israel, since 1977. The average annual total organic matter (TOM) load delivered by the effluents to the soil was ~ 5 kg m^− 2 y^− 1. Soil OM concentrations increased from 0.11% in the pristine soil to ~ 0.8% and ~ 0.6%, in the 0-0.15 m and 0.15-0.30 m soil layers, respectively, after ~ 20 y of effluent recharge, but did not change significantly in the 1.80-2.10 m deep layer. The OM accumulation rates in the top two soil layers were fast initially, then declined slowly and the OM concentrations approached a steady state following 10-15 y of effluent recharge. This suggests that stabilization of the ‘active biofilm’ layer in the infiltration basins' soils is a relatively slow process. Material-balance calculations showed, that accumulated OM in the top 0-2.1 m soil layer amounted to only ~ 4% of the TOM added by the effluents during ~ 20 y of recharge. Along the flow pathway of the effluent through the vertical 50-100 m thick soil-sediment column, DOC concentrations decreased by 70-90% (from ~ 18.9 mg L^− 1 to ~ 3.7 mg L^− 1). Continued flow in the aquifer from the observation wells to the recovery wells further decreased DOC concentrations by about 50% (from ~ 3.7 to ~ 1.5 mg L^− 1).     

Selective growth of metal tips onto semiconductor quantum rods and tetrapods

We show the anisotropic selective growth of gold tips onto semiconductor (cadmium selenide) nanorods and tetrapods by a simple reaction. The size of the gold tips can be controlled by the concentration of the starting materials. The new nanostructures display modified optical properties caused by the strong coupling between the gold and semiconductor parts. The gold tips show increased conductivity as well as selective chemical affinity for forming self-assembled chains of rods. Such gold-tipped nanostructures provide natural contact points for self-assembly and for electrical devices and can solve the difficult problem of contacting colloidal nanorods and tetrapods to the external world.     

Heavily doped semiconductor nanocrystal quantum dots

Doping of semiconductors by impurity atoms enabled their widespread technological application in microelectronics and optoelectronics. However, doping has proven elusive for strongly confined colloidal semiconductor nanocrystals because of the synthetic challenge of how to introduce single impurities, as well as a lack of fundamental understanding of this heavily doped limit under strong quantum confinement. We developed a method to dope semiconductor nanocrystals with metal impurities, enabling control of the band gap and Fermi energy. A combination of optical measurements, scanning tunneling spectroscopy, and theory revealed the emergence of a confined impurity band and band-tailing. Our method yields n- and p-doped semiconductor nanocrystals, which have potential applications in solar cells, thin-film transistors, and optoelectronic devices.