改性玉米芯制备太阳能界面蒸发体及其性能分析

针对天然生物质材料应用于海水淡化领域,蒸发效率较低、材料容易降解等问题,采用多巴胺对天然玉米芯进行改性处理,以改性玉米芯为基底,在其表面包覆炭黑-纤维素薄膜,制备了一种集光热转换、输水、隔热于一体的太阳能界面蒸发体。对改性玉米芯蒸发体的光学吸收性能、输水性能、接触角进行表征,并搭建了室内蒸发试验和户外蒸发试验系统,测试了改性玉米芯的蒸发性能,与天然玉米芯相比,改性玉米芯蒸发体的蒸发速率相对未改性的提升了约10.4%。对改性玉米芯蒸发体进行了30次循环试验,蒸发体均保持稳定的蒸发速率,整个循环测试中蒸发速率波动不超过1%。并且,长期工作后,蒸发体表面没有盐分沉积,没有出现材料软化、降解现象。改性玉米芯蒸发体在海水环境中能够保持良好、稳定的蒸发性能,且能够有效降低海水中的Na⁺、K⁺、Mg²⁺、Ca²⁺等离子浓度,达到世界卫生组织所规定的饮用标准中的相应限值。改性玉米芯蒸发体的制备方法简单、成本低廉、蒸发性能稳定,为扩展生物质材料在海水淡化领域的应用提供了有效途径。     

咸水灌溉对麦—玉两熟制农田土壤水稳性团聚体的影响

为探明咸水灌溉对麦—玉两熟轮作农田土壤团聚体的影响效应,在长期定位咸水灌溉试验(始于2006年)的基础上,研究了不同矿化度咸水连续灌溉第13~14年农田土壤盐分(EC e)及水稳性团聚体分布和稳定性指标的变化规律。试验设置5个灌溉水矿化度处理,分别为1,2,4,6,8 g/L。结果表明,0—40 cm土层土壤EC e随灌溉水矿化度增加而增大,4,6,8 g/L灌水处理与1 g/L处理间差异达显著水平。咸水灌溉改变土壤水稳性团聚体的粒级分布,灌溉水矿化度≤4 g/L时,0—40 cm土壤水稳性团聚体以大团聚体(>0.25 mm)为优势粒级,随灌溉水矿化度增加,大团聚体质量分数降低,微团聚体(0.053~0.25 mm)和粉+黏团聚体(<0.053 mm)质量分数增大,当灌溉水矿化度达到6 g/L时,粉+黏团聚体占比最大。咸水灌溉降低土壤水稳性团聚体的稳定性,随灌溉水矿化度的增加,土壤团聚体平均重量直径和几何平均直径减小,分形维数增大,但2 g/L与1 g/L灌水处理间无显著差异。在该研究灌溉制度下,≥4 g/L咸水灌溉显著增加土壤盐分,破坏土壤团粒结构,应谨慎使用。     

不同施肥措施及复垦年限下土壤团聚体的大小分布及其稳定性

土壤团聚体的数量和质量直接影响着土壤性质和有机碳固存。研究长期不同施肥措施及复垦年限对采煤塌陷区土壤团聚体的重量分布比例及其稳定性的影响,为该区域的农业生产和土壤质量提升提供科学依据。采集复垦6年和11年定位试验不同施肥处理耕层土样,选取不施肥(CK)、平衡施氮磷钾肥(NPK)、单施有机肥(M)、有机无机肥配施(MNPK)4个处理,利用干筛法和湿筛法获得4种粒径的团聚体/粉黏粒组分(> 2 mm、0.25-2 mm、0.053-0.25 mm和< 0.053 mm),用> 0.25 mm团聚体含量(R_0.25)、平均重量直径(MWD)、团聚体破坏率(PAD)和土壤不稳定团粒指数(E_LT)表示团聚体的稳定性,并测定了土壤有机碳含量。结果表明：复垦年限对土壤团聚体的含量及稳定性影响产生了显著影响。干筛条件下,复垦6年和11年均显著降低了各处理0.053-0.25 mm团聚体和< 0.053 mm组分的含量,降幅分别为68.39%-87.37%、69.63%-78.32%(6年)和90.01%-93.68%、78.29%-83.93%(11年);湿筛条件下,复垦11年显著提高了各处理> 2 mm团聚体的含量,增幅达473.35%-645.16%,但是显著降低了0.053-0.25 mm团聚体的含量,降幅为43.67%-57.54%。土壤团聚体的稳定性也随着复垦年限的增加而逐渐增强,表现为DR_0.25、WR_0.25和MWD值呈增加趋势,而PAD和E_LT值呈降低趋势。土壤有机碳含量与DR_0.25、WR_0.25、MWD_水稳性呈极显著正相关关系,而它与PAD和E_LT呈极显著负相关关系。本研究表明,该区域连续复垦11年提高了土壤大团聚体的含量而伴随着微团聚体含量的显著减少,导致土壤结构越来越稳定。它对提高采煤塌陷区复垦土壤肥力、改善土壤结构效果最佳。     

滇东岩溶山地不同类型云南松林地土壤团聚体稳定性差异

[目的]研究滇东岩溶山地不同类型云南松林地土壤团聚体稳定性差异,为岩溶脆弱生境土壤培肥、质量提升、水土固持提供依据。[方法]通过野外调查和室内分析,研究了滇东岩溶山地云南松纯林、云南松人工混交林、云南松天然混交林、灌丛和原生林5种植被类型水稳性团聚体及团聚体有机碳分布特征,揭示不同类型云南松林团聚体稳定性差异。[结果]①云南松纯林、人工混交林和天然混交林的0.25 mm粒径质量分数(5.77%～9.39%)显著低于灌丛(20.92%)和原生林(27.47%)(p0.05),且人工混交林和天然混交林5 mm,2～5 mm粒径质量分数高于纯林。②湿筛处理的0.25 mm水稳性团聚体比例(R_(0.25))排序为:人工混交林天然混交林纯林灌丛原生林;平均重量直径(MWD)排序为:人工混交林天然混交林原生林灌丛纯林;几何平均直径(GMD)排序为:人工混交林天然混交林原生林纯林灌丛;分形维数(D)排序为:原生林灌丛纯林天然混交林人工混交林。③纯林、人工混交林、天然混交林的大粒级团聚体(0.25 mm)对土壤有机碳的贡献率高于小粒级团聚体(0.25 mm),且5,2～5,0. 25 mm粒径水稳性土壤团聚体有机碳含量均显著小于灌丛、原生林(p0.05)。[结论]云南松人工混交林的土壤团聚体稳定性最高,其养分积累和固碳能力低于灌丛和原生林,高于纯林,作为该区域水土保持的主要植被类型时需要避免人为干扰以提高土壤养分。     

不同含水率高易溶盐含量的伊犁黄土流变特性

流变学研究方法可以揭示黏弹性物质的流动和变形规律,常被应用于土体结构的力学稳定性及长期变形参数研究。为了深入探究伊犁黄土类土的黏弹性和结构稳定性,该研究采用流变仪对不同含水率和易溶盐(Na₂SO₄)含量的伊犁黄土类土进行了稳态和动态流变试验,引入Bingham模型对小剪切速率下的流变曲线进行了拟合,并分析解释了稳态和动态流变试验的演化过程。同时,讨论了含水率及易溶盐含量对稳态和动态流变参数的影响规律,定量分析了流变参数与各变量之间的关系。结果表明：稳态剪切过程中土体由固态向类固态转化,并最后趋于流态,具有剪切变稀行为;随着含水率及易溶盐含量增大,屈服应力和黏度均减小,且屈服应力在300～1 100 Pa之间。随着含水率和易溶盐含量增大,动剪切强度参数和黏弹性参数均线性减小,土体的结构稳定性降低。当剪切应变小于0.1%时,土体处于线性黏弹区,损耗因子变化不大;剪切应变大于0.1%时,损耗因子逐渐增大。高含水率及高易溶盐含量的土壤最先到达屈服点,说明高含水率和高易溶盐含量不利于土体结构的稳定性。随着含水率的增大,易溶盐含量对流变参数的影响程度变小...     

季节性冻融对色季拉森林土壤团聚体稳定性的影响

为分析季节性冻融对土壤团聚体稳定性的影响,以藏东南色季拉山森林土壤为研究对象,通过野外控制性试验利用湿筛法测定团聚体组成,分析了0—10 cm, 10—20 cm, 20—30 cm深度土层各粒径团粒结构变化,以及土壤含水量(SWC),0.25 mm水稳性团聚体含量(WSA)、平均质量直径(MWD)、平均几何直径(GMD)、分形维数D、可蚀性K值各指标之间的关系。结果表明：(1)季节性冻融导致大团粒含量减少,小团粒含量增加,土壤结构失调。(2)含水量是影响团聚体稳定性的重要因素之一。(3)季节性冻融作用整体上导致MWD,GMD变小,D值与K值变大,降低了土壤团聚体稳定性。(4)当土壤冻融次数在一定范围内STF-One中,WSA有所增加,土壤稳定性有所增强。(5)土壤团聚体WSA,MWD和GMD均与D值和K值呈负相关。(6)在SFT-Ys类型土壤中土壤结构变化,0.5 mm粒级是重要临界点。综上,研究为季节性冻融对土壤稳定性的影响提供数据支持,为冻土潜在受侵蚀情况提供理论依据。     

Impacts of wetting-drying cycles on short-term carbon and nitrogen dynamics in Amynthas earthworm casts

Effects of earthworm casts on soil nutrient dynamics and their responses to changing moisture availability in subtropical ecosystems remain poorly understood. This study aimed to examine short-term carbon(C) and nitrogen(N) dynamics and their interactions with wetting-drying cycles in three different structural forms(i.e., granular, globular, and heap-like) of Amynthas earthworm casts. The rates of C and N mineralization in the earthworm casts were examined under two different wetting-drying cycles(i.e., 2-d and 4-d wetting intervals) using a rainfall simulation experiment. After three simulated rainfall events, subsamples of the earthworm casts were further incubated for 4 d for the determination of CO_2 and N_2O fluxes. The results of this study indicated that the impacts of wetting-drying cycles on the short-term C and N dynamics were highly variable among the three cast forms, but wetting-drying cycles significantly reduced the cumulative CO_2 and N_2O fluxes by 62%–83% and 57%–85%, respectively, when compared to the control without being subjected to any rainfall events. The C mineralization rates in different cast forms were affected by the amount of organic substrates and N content in casts, which were associated with the food preference and selection of earthworms. Meanwhile, the cumulative N_2O fluxes did not differ among the three cast forms. Repeated wetting and drying of casts not only enhanced aggregate stability by promoting bonds between the cast particles, but also inhibited microbial survival and growth during the prolonged drying period, which together hindered decomposition and denitrification. Our findings demonstrated that the interactions between the structural forms, aggregate dynamics, and C and N cycling in the earthworm casts were highly complex.     

增减施有机肥对红壤性水稻土团聚体稳定性及胶结物的影响

利用具有35a的长期定位试验,在保证原定位试验继续正常开展的前提下,将原化肥处理改施有机肥,原有机肥处理改施化肥或增施有机肥,分析增减施有机肥后耕层土壤团聚体稳定性总有机碳(TOC)及其组分和铁铝氧化物的变化与作用关系,探究胶结物对红壤性水稻土团聚体稳定性变化的影响。结果表明:化肥(CF)及常量有机肥(NOM)处理增施有机肥后,团聚体平均重量直径(MWD)变化不明显,易氧化有机碳(EOC)分别升高87.44%和20.53%;高量有机肥(HOM)及NOM处理减施有机肥后,MWD分别显著降低8.39%和6.80%,高改化(H-C)处理的TOC、轻组有机碳(LFOC)及粗颗粒态有机碳(cPOC)含量显著降低,而常改化(N-C)处理的TOC及其组分变化不明显。无论增施还是减施有机肥,铁铝氧化物含量的变化规律不明显。相关及结构方程模型分析表明,大于0.25mm团聚体含量是影响团聚体稳定性的唯一直接影响因素;影响MWD及大于0.25mm团聚体含量的效应系数由大到小依次为:易氧化有机碳、轻组有机碳、游离氧化铁、络合态铁。因此,大于0.25mm大团聚体在红壤性水稻土的团聚体稳定性中发挥主导作用,有机碳活性组分对大团聚体的形成与破坏具有重要影响。     

秸秆还田对麦粱两熟农田土壤团聚体特征的短期效应

冬小麦—夏高粱种植系统作为一种新型农业两熟制系统,是山西省杂粮可持续发展的一项有效措施。为阐明该种植系统农田土壤团聚体粒级分布及稳定性对秸秆还田量的短期响应,试验基于麦粱种植系统,分析了不还田（CK）、半量还田（HR）和全量还田（WR）对土壤团聚体粒级分布特征和稳定指数的影响。结果表明:秸秆还田后,能够显著降低0—30 cm土层 > 10 mm和 < 0.25 mm粒级机械稳定性团聚体含量,增加0.25～2 mm各亚粒级水稳性大团聚体含量,同时显著降低了土壤团聚体破坏率和不稳定团粒指数（p < 0.05）;全量秸秆还田后较半量秸秆还田对农田土壤团聚体特征改善效果更为明显,但对10—20,20—30 cm土层改善效果逐渐减弱;全量还田相比半量还田,土壤机械稳定性团聚体平均重量直径、几何平均直径和大团聚体（> 0.25 mm）含量分别显著降低了12.2%,23.0%和5.3%,并显著提升了水稳性团聚体几何平均直径和大团聚体（> 0.25 mm）含量,降低了水稳性团聚体分形维数（p < 0.05）。此外,土壤团聚体稳定性与有机碳含量、孔隙度、含水量和作物产量呈显著正相关（p < 0.05）。综合表明,全量还田在短期年限内能够显著提高土壤团聚体稳定性,是改善晋中区麦粱两熟农田土壤团粒结构和增加作物产量的有效措施。     

Differential and successive effects of residue quality and soil mineral N on water-stable aggregation during crop residue decomposition

Residue quality has been shown to influence soil water-stable aggregation (WSA) during crop residue decomposition, but there is still little information about its interactive effect with soil mineral N availability. The aim of this study was to determine the effect of soil mineral N on WSA during the decomposition of two high-C/N crop residues (wheat straw with C/N = 125.6 and miscanthus straw with C/N = 311.3). The two crop residues were combined with three mineral N addition rates (0, 60, and 120 mg N kg⁻¹ dry soil). Respiration, soil mineral N content, and WSA (expressed as mean-weight diameter, MWD) were measured on several dates during a 56-d incubation. The effect of decomposing crop residues on WSA followed two phases. (i) Between 0 and 7 d, the increase in WSA was related to intrinsic residue quality with higher decomposability of the wheat straw resulting in higher WSA. (ii) Thereafter, and until the end of the experiment, mineral N addition rates had a predominant but negative influence on WSA. In this second phase, the average MWD of residue-treated soils was 0.92, 0.55, and 0.44 mm for the 0, 60 and 120 mg N kg⁻¹ dry soil addition rates, respectively. Mineral N addition which did result in higher crop residue decomposition did not lead to higher WSA. WSA during crop residue decomposition is therefore not simply positively related to the induced microbial activity, and changes in microbial community composition with differential effects on WSA must be involved. The impact of high-C/N crop residues inputs on WSA, initially assumed to be low, could actually be strong and long-lasting in situations with low soil mineral N content.