羧甲基纤维素钠对壤砂土水分运动及水力参数的影响

科学使用羧甲基纤维素钠(CMC)实现保水控盐对于滨海壤砂盐碱土改良具有重要意义,而明晰CMC对滨海壤砂土水分运动规律的影响是科学使用CMC的重要基础。为研究施加CMC滨海壤砂土水分运动规律,本文通过开展一维垂直土柱积水入渗试验,探索不同CMC施量(0、0.1、0.2、0.4、0.6 g?kg-1) 对壤砂土入渗特性、水分分布和土壤水力参数的影响。结果表明,施用CMC土壤的最终累积入渗量增加了4.90％～15.17％、达到预设湿润锋深度的入渗时间增加了61.90%～604.73%;Philip入渗模型参数吸渗率S和Green-Ampt模型参数KsSf均随CMC施量的增加而减少,吸渗率S和平均土壤水扩散率与CMC施量之间的数学关系分别可用二次多项式和指数函数来表示;CMC增强了土壤的持水能力,土壤剖面含水量提高了0.72%～3.74%;CMC通过改变土壤结构影响了土壤水力参数,滞留含水率θr、饱和含水率θs及进气吸力倒数α均与CMC施量呈正相关关系,而与饱和导水率Ks和形状系数n呈反比关系。通过对变异系数CV的分析发现,CMC对饱和导水率Ks和进气吸力倒数α影响表现为中等差异,对滞留含水率θr、饱和含水率θs和形状系数n表现为弱差异。研究结果揭示了CMC对滨海壤砂土减渗保水的内在机理,为滨海盐碱地的改良提供了理论参考。     

基于EDEM的猪粪接触参数标定

为准确快速获得畜禽粪便的接触参数,该研究通过物理堆积试验与仿真方法对猪粪接触参数进行了标定。测定了不同含水率下猪粪的堆积角,建立了含水率与堆积角的回归方程;基于Hertz-Mindlin with JKR球体粘结模型,进行了离散元仿真模拟;采用筛选试验设计(Plackett-BurmanDesign,P-BD)对10个初始参数进行了筛选,发现JKR(Johnso-Kendall-Roberts)表面能、颗粒间滚动摩擦系数、颗粒间碰撞恢复系数对猪粪堆积角影响显著;并根据响应曲面试验设计(Box-BehnkenDesign,B-BD)建立了堆积角与显著性参数的二阶回归模型,得到了3个显著性参数值分别为JKR表面能0.03J/m~2、颗粒间滚动摩擦系数0.27、颗粒间碰撞恢复系数0.54;将仿真所得堆积角与物理试验值进行对比验证,相对误差为4.27%。结果表明,该研究提出的标定方法能准确模拟物理堆积试验,可为畜禽粪便接触参数的标定提供参考。     

添加秸秆对不同有机含量土壤酸度及缓冲性能的影响

通过向低（LSOM）、中（MSOM）、高（HSOM）及去除（RSOM）有机质土壤中添加玉米秸秆进行室内培养试验,研究秸秆添加量对不同有机质含量土壤酸度及缓冲性能的影响。结果表明,在15℃恒温培养150天后,土壤pH、交换性盐基离子、CEC和盐基饱和度的含量均随着秸秆添加量的增加而上升,交换性H⁺、交换性Al³⁺含量均随着秸秆添加量的增加而降低;其中,秸秆添加量为10~15 g/kg时,LSOM处理中土壤pH增幅、交换性Al³⁺及交换性H⁺含量减幅最大;秸秆添加量为15~20 g/kg时,在MSOM和HSOM处理中土壤pH增幅及土壤交换性Al³⁺、交换性H⁺含量减幅最大;且HSOM处理添加秸秆后对降低土壤酸度效果最好。土壤中添加秸秆后可明显提高土壤酸碱缓冲能力,且土壤对加碱侧表现出的缓冲区间比酸侧明显;土壤的缓冲容量随秸秆添加量增加而升高,且HSOM处理对酸碱缓冲能力 > MSOM处理 > LSOM处理 > RSOM处理。     

关中平原农田土壤水力参数空间分异与模拟

土壤水力参数是土壤水分和污染物迁移等陆面过程数值模拟的重要基础参数。为探明关中平原农田土壤水力参数空间分异特征,建立空间分布预测模型,在关中平原网格布设124个样点,采集根层0-20 cm原状和扰动土壤样品,利用van Genuchten模型拟合获取土壤水分特征曲线,获得残余含水量(θr)、饱和含水量(θs)以及系数α和n等土壤水力参数。采用经典统计学、地统计学和结构方程方法分析了θr、θs、α和n的空间变异特征及影响因子,建立了水力参数传递函数预测模型。结果表明:θr和α为强变异,θs为中等变异,n为弱变异。θr、θs、α和n半方差函数最佳拟合模型分别为球状模型、指数模型、指数模型和球状模型。θs和n具有强烈的空间依赖性,变程分别为32.7,54.3 km;θr和α具有中等程度空间依赖性,变程均为52.8 km。土壤质地、容重、pH、有机质和海拔是影响土壤水力参数空间分布的主要因子。基于土壤理化性质和海拔建立的水力参数传递函数模型具有较好的模拟效果,可用于关中地区大尺度农田生态系统土壤水力参数的模拟预测。     

Detachment of road surface soil by flowing water

An agricultural watershed generally consists of two land use categories, farmland and the unpaved road or path networks with different traffic frequency and size. Road surfaces are quite different from farmland soil in physical properties, resulting in it's distinguish production transportation process. Hydraulic flume experiments were conducted with the flow discharges ranging from 1 to 5 L s^− 1 and the slope gradients ranging from 8.8% to 46.6% to simulate the soil detachment process on a road surface and to develop tools in order to calculate detachment rates occurring on that road surfaces. The results illustrate that road surfaces behave characteristically in the runoff detachment and sediment delivery process due to the difference in the bulk density and functions of agricultural soils. The soil detachment rate is closely related to flow depth, slope gradient and other hydraulic parameters such as shear stress, stream power and unit stream power. Multiple non-linear regression analyses indicate that detachment rates for all roads can be accurately predicted by power functions of flow depth and slope gradient. According to the experimental results, stream power was suggested as an indicator to estimate soil detachment rate instead of shear stress in soil erosion models. However, considering the simplicity and availability, power function of flow depth and slope gradient is also recommended to predict detachment rate on the road surfaces.     

耕地棕壤酸碱缓冲性能及酸化速率研究

辽宁省耕地棕壤自第二次土壤普查以来酸化趋势明显,pH整体平均值从第二次普查时期的6.42降至5.73。对辽宁省4个典型地区(昌图、沈阳、瓦房店、清原)的耕地棕壤耕层(0-20cm)缓冲性能、酸化速率及其影响因素进行研究,结果表明:各地区酸碱缓冲容量变幅为29.66～39.87mmol/kg.pH unit,其中辽宁北部和中部地区酸碱缓冲容量明显高于辽南和辽东地区。酸化速率以辽南地区下降速率最快,其值为2.69H+kmol/(hm2.a),而速率最慢的地区为辽东,其酸化速率为1.44H+kmol/(hm2.a)。土壤初始pH、阳离子交换量、颗粒组成及有机质含量均是影响酸碱缓冲容量变化的主要因素。北部和中部质地以粉(砂)壤土为主,阳离子交换量、盐基饱和度及粘粒含量均高于南部和东部地区,因此缓冲性能也较强。施肥及其他人为因素对辽宁耕地棕壤酸碱缓冲容量及酸化速率的影响有待进一步研究。     

土壤持水特性参数与土壤质地尺度关系的联合多重分形分析

Soil water-retention characteristics at measurement scales are generally different from those at application scales, and there is scale disparity between them and soil physical properties. The relationships between two water-retention parameters, the scaling parameter related to the inverse of the air-entry pressure (αvG, cm-1) and the curve shape factor related to soil pore-size distribution (n) of the van Genuchten water-retention equation, and soil texture (sand, silt, and clay contents) were examined at multiple scales. One hundred twenty-eight undisturbed soil samples were collected from a 640-m transect located in Fuxin, China. Soil water-retention curves were measured and the van Genuchten parameters were obtained by curve fitting. The relationships between the two parameters and soil texture at the observed scale and at multiple scales were evaluated using Pearson correlation and joint multifractal analyses, respectively. The results of Pearson correlation analysis showed that the parameter αvG was significantly correlated with sand, silt, and clay contents at the observed scale. Joint multifractal analyses, however, indicated that the parameter αvG was not correlated with silt and sand contents at multiple scales. The parameter n was positively correlated with clay content at multiple scales. Sand content was significantly correlated with the parameter n at the observed scale but not at multiple scales. Clay contents were strongly correlated to both water-retention parameters because clay content was relatively low in the soil studied, indicating that water retention was dominated by clay content in the field of this study at all scales. These suggested that multiple-scale analyses were necessary to fully grasp the spatial variability of soil water-retention characteristics.     

磺胺嘧啶在黑土及其不同粒径组分中的吸附行为研究

采用批平衡吸附试验法,研究了磺胺嘧啶在黑土及其不同粒径中的吸附行为。结果表明,磺胺嘧啶的吸附不同程度地偏离线性模型,但均可用Freundlich模型和Langmuir模型进行良好地线性拟合。黑土（〈0.2mm）及其不同粒径（粘粒：〈0.002mm、粉粒：0.002~0.02mm、砂粒：0.02~0.2mm）的Freundlich容量因子Kf值分别为29.6、53.1、32.9L.kg-1和21.6L.kg-1,说明磺胺嘧啶在黑土及其不同粒径中的吸附行为存在差异。将吸附参数Kf进行碳标化处理后,Koc值除粉粒外,其他基本一致。随着溶液pH的持续增加（1.0~10.0）,黑土及其不同粒径中的磺胺嘧啶的吸附参数lgKf呈现先急剧降低然后稍微回升的趋势,由此推测,阳离子交换作用可能是磺胺嘧啶土壤吸附的重要机制。过氧化氢处理去除土壤有机质后,黑土的Kd值从1.92L.kg-1降为1.22L.kg-1,磺胺嘧啶的吸附量由16.5mg.kg-1降低到11.2mg.kg-1,说明有机质含量也是影响磺胺嘧啶吸附行为的重要因素。     

基于Markov链地统计模型的区域土壤性质研究进展

土壤水力学性质的空间变异对于区域土壤水分溶质循环模拟研究至关重要。基于Markov链的条件模拟是一种能融合多源信息技术的地统计学模拟方法,与传统插值法和基于变异函数的条件模拟相比有诸多优势。目前,该方法在土壤水力学性质空间变异性领域的研究并未全面展开。实现区域土壤水力学模型参数的随机模拟,对于实现区域土壤水分运动和溶质运移的随机模拟,分析土壤水力学性质空间变异性对土壤水分运动和溶质运移模拟结果的影响,特别是参数采样点变化对土壤水分运动和溶质运移结果影响的不确定性等研究都有重要意义。本文旨在综述基于Markov链的地统计学模拟在土壤学相关领域的研究进展,以期为区域模拟中面临的参数获取难题提供帮助,为区域农业生产管理,水分高效利用,农田生态环境保护提供科学依据。     

流域尺度土壤厚度的模糊聚类与预测制图研究

基于土壤厚度与景观位置和特征之间的关系,运用模糊c均值聚类(FCM)方法对西苕溪流域的土壤厚度分布进行了空间预测。选取高程、坡度、平面曲率、剖面曲率、径流强度系数和地形湿度指数6个地形因子进行模糊聚类,根据相应的聚类参数将流域地形组合分为8类。利用部分调查获得的土壤剖面数据,结合样点属性和专家经验为典型区赋值,最后由加权平均得到流域土壤厚度预测图。验证结果表明,FCM方法可以对地形因子组合进行有效合理的分级,其预测精度较高,模型的稳定性较好,是一种低成本高效率的制图方法。该方法在土壤厚度预测方面具有一定的可靠性。