基于纳米压痕技术的木材胶合界面力学行为

【目的】研究木材胶合界面的静态和动态力学行为,探讨树脂渗透对木材管胞壁层力学性能的影响,为木质复合材料制造工艺优化和增强改性提供理论依据。【方法】采用纳米压痕静态和动态力学测试技术(Nano-DMA),对针叶材火炬松与酚醛树脂(PF)、脲醛树脂(UF)胶黏剂所形成胶合界面区域各相材料的静态弹性模量、硬度、蠕变性能以及储能模量和损耗模量等力学行为进行分析。【结果】静态力学行为方面,在界面区域,PF和UF渗透进入管胞壁层后,木材管胞壁的弹性模量( E r)和硬度( H )提高;经PF渗透后,木材管胞壁的 E r和 H 分别增加7%和26%;Burgers蠕变力学模型可有效描述胶合界面区域管胞壁的纳米压痕蠕变特性,经树脂渗透后,木材管胞壁的瞬时弹性模量增加,黏弹性模量和黏性系数减小;在保载初期,PF界面区域木材管胞壁的蠕变柔量约下降60%,UF界面区域木材管胞壁的蠕变柔量约下降58%。动态力学行为方面,随着加载频率增加,界面材料的储能模量( E ′ r)逐渐增大,而损耗模量( E ″ r)和损耗因子(tan δ)呈减小趋势;当加载频率为10 Hz时,PF和UF树脂渗透使得管胞壁层的储能模量分别增加16%和29%。【结论】胶合界面区域胶黏剂进入管胞壁层,对木材管胞的静态力学性能具有增强作用,同时胶黏剂可提高管胞壁的短期抗蠕变能力;木材管胞壁具有较高的储能模量和损耗模量,而树脂的储能模量和损耗模量较低,经树脂渗透后,木材管胞壁的储能模量增加,但损耗模量和损耗因子呈下降趋势,可能对界面传递和分散应力产生不利影响。     

竹-短木组合梁受弯性能试验研究

为解决木材利用率低、成本高的问题,提出了一种以零碎短木粘结竹集成而成的竹-短木组合梁。通过3根木梁、3根直拼的竹-短木组合梁(SBT)和3根搭接的竹-实木组合梁(OBT)的三分点加载受弯对比试验,研究了其破坏形态、极限承载力和位移延性等。结果表明:竹-短木组合梁破坏类型为脆性破坏;竹-短木组合梁跨中截面沿高度应变仍基本符合平截面假定;OBT试件受弯承载力平均提高1.6%,力学性能媲美木梁;最后提出了受弯承载力计算简式,与试验结果较为吻合。竹-短木组合梁替代木梁,在小跨度木结构工程中具有应用价值。     

松褐天牛交尾产卵行为和卵期、孵化率测定

松褐天牛 Monochamus alternatus Hope成虫交尾 ,雌雄均无专一性 ,既能一雄多雌 ,也能一雌多雄 ;交尾次数对产卵量和卵的孵化率无显著影响 ;成虫对产卵场所的树种和树性有显著的偏嗜性选择行为。据测定 ,在 6月下旬至 7月下旬平均卵期 4.0 4天 ,卵的孵化率为 85 .76%。     

Reproductive strategies and seeds behavior ofBetula platyphylla Suk. population

By the methods of morphological anatomy and investigation in the sample fields, the main studies were carried out such as morphological anatomy of reproductive organs, birch population’s reproductive ages, reproductive allotment value and seed behavior. The relationship between birch population and their surroundings was studied. The results showed that birch’s flower organs and its seeds were suitable well for spreading by wind. The seeds by wind can fly far away in a short time. The quantity of seed spreading greatly varied with different communities. Birch’s reproduction age can be changed in different ecological surroundings. The reproductive allotment value of birch was obviously different at different reproductive stages. In the mesic habitat, birch can grow well. The lowest reproductive age of them was 12, average age 15. In most cases the age of branches to bearing fruits was more than 18. The order of reproductive allotment values was as follows: a flowering phase > flower bud phase > fruit phase.     

Relationship between stomatal behavior and characteristics of photosynthesis and transpiration of Adenophora Iobophylla and A. potaninii at different altitudes

The photosynthesis and transpiration characteristics ofAdenophora Iobophylla and A. potaninii, as well as stomatal behavior such as stomatal size, stomatal density, stomatal open and stomatal conductivity were measured at different altitudes. The relationship between the photosynthesis and transpiration characteristics and the stomatal behavior was analysed by correlation coefficient and path coefficient analysis with altitude changes.The results showed that the influences of stomatal behavior were not evident on the photosynthesis and transpiration characteristics of A. Lobophylla, but evident on that of A. potaninii.     

野生雉鸡求偶行为与繁殖观察

在吉林省白城马场卧地来窝铺北荒漠草原与农田库泡交接地带,采用直观法对雉鸡求偶行为与繁殖进行了观察。结果表明,野生雉鸡繁殖求偶期种群仅限3~5只雌鸟和1只雄鸟组成,成一雄多雌结构;每窝产卵6~22枚,雌鸟产卵后独自承担孵化任务,孵化期21~24 d,幼鸟出壳即能随亲鸟觅食或隐匿于草丛中;繁殖季节食大量昆虫,以增加动物性蛋白,其它季节以植物嫩芽和谷物种实为主。     

寄生小蜂对小青×黑杨树皮及杨圆蚧挥发油的行为反应

Four-armed airflow olfactometer was used to determining the foraging behavior ofPteroptrix longgiclava (Girault) (Hymenoptera: Aphelinidae) andEncarsia gigas (Tshumakova) (Hymenoptera: Aphelinidae) to the essential oils which emitted from the healthy bark ofPopulus pseudo-simonii×P. nigra, the infested bark injured byQuadraspidiotus gigas (Thiem & Gerneck), the body and scale of fixed 1st-instar-nymph ofQ. gigas. The results from these experiments showed that the volatile oils produced from the injured bark and from the scale of fixed 1st-instar-nymph had a higher attractive ability to female adults of the two species of wasps. The essential oil produced from the scale of the pest at dosages of 3–7 μL and the essential oil emitted by injured bark at dosages of 5–9 μL had a stronger alluring effect on the host searching behavior ofPteroptrix longgiclava. The essential oil from the body of fixed 1st-instar-nymph ofQ. gigas also had certain effect on the host locating effort ofPteroptrix longgiclava andEncarsia gigas. Those two wasps did not shown any reaction to the essential oil produced by the healthy bark of poplar. Foundation item: This paper was supported by National Natural Science Foundation of China (39970620) and the “TRAPOYT” Biography: CHI De-fu (1962-), male, Ph.D., Professor in Northeast Forestry University, Harbin 150040, P.R. China Responsible editor: Chai Ruihai     

无溶剂法制备丙烯海松酸蔗糖酯及其在空气-水界面吸附行为研究

在无溶剂条件下,以丙烯海松酸和蔗糖为原料,在高温熔融状态下通过酯化反应制备了丙烯海松酸蔗糖酯,运用红外光谱、核磁共振和凝胶渗透色谱对其结构进行了表征,并测试了其临界胶束浓度(CMC),利用再定向理论分析了丙烯海松酸蔗糖酯表面活性剂在空气-水界面的形态转变和吸附量等吸附行为。研究结果表明:成功合成了丙烯海松酸蔗糖酯,其CMC值为2.2 g/L。丙烯海松酸蔗糖酯在空气-水界面的吸附状态分为状态1和状态2,随着表面压的增加,溶剂摩尔分数逐渐降低,2种状态丙烯海松酸蔗糖酯分子在空气-水界面上的摩尔分数之和逐渐增加。计算了吸附在界面上的状态1和状态2丙烯海松酸蔗糖酯的吸附量,随着表面压增大,状态1吸附量先增大后减小,状态2吸附量占主导且持续增多,吸附量最高可达1.9 mmol/m²。丙烯海松酸蔗糖酯的吸附和胶束化摩尔自由能(ΔG)分别为-20.67和-15.16 kJ/mol,表明丙烯海松酸蔗糖酯优先吸附在界面上,达到饱和后就形成胶束。     

北京市越冬长耳鸮食物中的蝙蝠成分

为研究越冬长耳鸮对冬眠蝙蝠的捕食影响,2003—2005年采用食团分析法对北京市2个长耳鸮群体食物中的蝙蝠成分进行比较研究。结果表明,在2个长耳鸮群体食团中均鉴别出大棕蝠、山蝠、普通伏翼和东方蝙蝠4种蝙蝠,普通伏翼为主要猎物,但2个群体被捕食蝙蝠的数量组成存在明显差异。在不同年度和越冬阶段,2个群体对蝙蝠的捕食强度均为普通伏翼最高、大棕蝠和山蝠占据较小比例,2个群体各年度捕食蝙蝠的组成以及城外群体不同越冬期捕食蝙蝠的组成存在明显差异。2005/2006年度,2个群体普通伏翼被捕食强度均明显下降。长耳鸮的捕食可能给北京地区蝙蝠类群生存带来负面影响,建议适当采取措施控制长耳鸮的捕食。     

Effect of maleic anhydride grafted styrene-ethylene-butylene-styrene （MA-SEBS） on impact fracture behavior of polypropylene / wood fiber composites

MA-SEBS as compatibilizer and impact modifier was incorporated into Polypropylene/Wood Fiber （PP/WF） to enhance interface adhesion and impact strength of the composite. The effect of MA-SEBS content on the impact fracture behavior of PP/WF composites was studied. The impact properties of composites with 8% MA-SEBS reached the maximum value. And further increasing of MA-SEBS content to 10% did not improve the fracture toughness, but improved the stiffness of composites by DMA analysis. This was attributed to the improved PP/WF adhesion. As the MA-SEBS content is more than 8%, the molecule interaction of PP and WF was expected to much stronger than lower MA-SEBS. Scanning electron microscopy （SEM） was performed to analyze the impact fracture surface and showed a stronger affinity for the wood surfaces.