新型高分子有机硅材料集流效率试验研究

将高分子有机硅材料喷施在夯实的坡面上,在坡表面形成一层致密的防水膜,减少土壤入渗,增加径流量,从而提高了坡面的集流效率,并减少土壤的侵蚀量,是一种简单、方便的集雨方式。本试验以一种新型有机硅材料作为对象,采用室内渗透和室外人工模拟降雨试验,探讨其应用于集雨工程的可能性,并确定其最佳配比和最适宜用量。研究结果表明:硅水最优配比(体积比,文中所有硅水配比均指体积比)在1∶5～1∶7,适宜用量为150ml/m2。当雨强在1.2～1.5mm/min,前期含水率17%左右,干容重为1.3g/cm3左右,其集流效率可以达到70%以上,是对照夯实坡面集流效率的2～3倍,而侵蚀量只是对照坡面侵蚀量的1/5。新型有机硅材料具有集流效率高、成本低、施工简单等优点,在集雨工程中具有广阔的应用前景。     

Silicon nutrition of tomato and bitter gourd with special emphasis on silicon distribution in root fractions

Two plant species, tomato (Lycopersicon esculentum Mill.) and bitter gourd (Momordica charantia), were used for in‐depth studies on the dynamics of silicon (Si) uptake and translocation to the shoots and compartmentation of Si in the roots. The experiments were conducted under controlled environmental conditions in nutrient solutions, which were partly amended with 1 mM Si in the form of silicic acid. At harvest, xylem exudates were collected, and Si concentrations and biomass of roots and shoots were determined. Mass flow of Si was calculated based on the Si concentration of the nutrient solution and transpiration determined in a parallel experiment. Plant roots were subjected to a fractionated Si analysis, allowing attributing Si to different root compartments. Silicon concentrations in the roots compared to the shoots were higher in tomato but lower in bitter gourd. A more ready translocation from the roots to the shoots in bitter gourd was in agreement with Si concentrations in the xylem exudates which were higher than in the external solution. In tomato, the xylem‐sap Si concentration was lower than in the nutrient solution. Calculated Si mass flow to the root exceeded Si uptake in tomato, which was consistent with the measured accumulation of Si in the root water‐free space (WFS). In contrast, Si concentration in the root WFS was lower than in the nutrient solution in bitter gourd, reflecting the calculated Si depletion at the root surface based on the comparison of Si mass flow and Si uptake. Within the roots, more than 80% of the total Si was located in the cell wall and less than 10% in the cytoplasmic fractions in tomato. In bitter gourd, between 60% and 70% of the total root Si was attributed to the cell‐wall fraction whereas the proportion of the cytoplasmic fraction reached more than 30%. Our results clearly confirm that tomato belongs to the Si excluders and bitter gourd to the Si‐accumulator plant species for which high Si concentrations in the cytoplasmic root fraction appear to be characteristic.     

Rapid, Micro-Methods to Estimate Plant Silicon Content by Dilute Hydrofluoric Acid Extraction and Spectrometric Molybdenum Method

By treating 0.5 g DW of a plant sample directly with 10 ml of a dilute hydrofluoric acid solution (HF solution, 1.5 M HF—0.6 M HCl), all the silica in plant (as much as 150 mg SiO₂) was dissolved within 1 h. After dilution of the extract with 40 mL of distilled water, the silica in the extract was measured by the spectrometric molybdenum yellow method. The molybdenum yellow method, in which silica in 0.1 mL of the diluted extract can be determined in 8 min, is well suited to rapid, micro-estimations of the silica content in plants. In the micro-modification, the size of the plant sample was reduced to 100 mg DW. The analytical procedure was simple, and the analytical time was less than 2 h. The method can save much labor and time, compared with the gravimetric analysis. The dissolution with HF solution and the molybdenum yellow method were also applied to the measurement of the content of silica separated by acid digestion of rice plants. Excellent agreement in the silica measurement of rice plants was confirmed among the direct extraction method, the gravimetric method and the digestion-separation-dissolution method. In the molybdenum yellow method, the addition of boric acid enabled to mask the interference of hydrofluoric acid, and the least amount of citric acid required for the elimination of phosphorus interference was proposed. In conclusion in this report, recommended methods for the rapid estimation of the silica content in rice plants were presented.     

Effect of silicon on the eutectic carbides in as-heated M2 high speed steel

The effect of silicon on the eutectic carbides in as-heated M2 high speed steels is investigated by using optical microscope, scanning electron microscope, energy dispersive spectrometer and X-ray diffraction analysis. The high speed steel ingots with different silicon additions are produced by electroslag remelting process (the mass content of silicon is 0.3%, 0.8%, 1.6% and 2.4%, respectively). The ingots are annealed at 780 ℃ for 10 h and heated at 1 165 ℃ for 2.5 h. The results show that the eutectic carbides distributed in the dendrites with continuous or semi-continuous net-shape in the as-annealed ingots. The eutectic carbides change from lamellar-like M2C to herringbone-like M6C with the increase of silicon content. After 2.5 h heating at 1 165 ℃, the lamellar-like M2C decomposes into granular M6C and MC, and the size of granules in M2 high speed steel ingot with 0.8%Si addition is smaller than that in the 0.3%Si. Whereas herringbone-like M6C is unchanged during heating treatment, and coarse primary blocky carbides which are harmful for properties still exists after the deformation.     

纳米二氧化硅对脲醛树脂胶性能的影响

研究了纳米SiO2对低摩尔比脲醛树脂游离甲醛含量、粘度、固化时间、羟甲基含量及胶合强度的影响,结果表明:纳米SiO2的加入可降低脲醛树脂胶的游离醛含量,增大粘度,提高胶合板的胶合强度,使羟甲基含量略有降低,但对固化速度影响不大     

多元醇对聚酯改性有机硅树脂性能的影响

通过对包括三羟甲基丙烷、季戊四醇及乙二醇这几种不同的多元醇合成的聚酯,利用有机硅中间体改性成膜后,对基材的附着力、硬度、柔韧性所做的探讨,可知在硅含量相同时,乙二醇的附着力最好,且柔韧性也最好,但耐热性能最差,在综合考虑的基础上,三羟甲基丙烷的性能最好。     

植物中硅的生物化学作用研究进展

介绍了一些关于硅在植物中的生物化学作用的最新研究进展,包括对硅藻类的基础研究,硅在植物抗病生理中的生化作用,硅对于缓解重金属毒害的作用,硅对植物生长及酶活性的影响和硅对其它营养元素吸收利用的影响。     

黄泥田改良培肥效应研究

为探寻黄泥田综合改良技术,在黔西县进行了为期2年的黄泥田改良试验研究,结果表明:硅钙肥和油菜壳配施对水稻产量有较明显的增产效果,增产率达10%以上,稻谷的粗蛋白也显著增加;硅钙肥和油菜壳配施可提高土壤pH,促进土壤有机质转化,有效氮增加。在施用硅钙肥和油菜壳的同时,应适当增加磷、钾肥用量。     

水工泄水建筑物高性能抗冲磨混凝土试验研究

针对水工泄水建筑物高性能混凝土高抗裂性和高抗冲磨性的要求,通过掺用具有梳型结构的聚羧酸减水剂实现水工泄水建筑物高性能混凝土,同时研究了聚丙烯纤维、粉煤灰和硅粉等因素对混凝土抗冲磨性能的影响。研究表明：聚羧酸减水剂掺量为1.0%,粉煤灰掺量为15%,硅粉掺量为10%,聚丙烯纤维掺量0.9 kg/m3时,混凝土的抗裂性和抗冲磨性能满足水工泄水建筑物高性能混凝土工程的使用要求。     

The status of atmospheric concentrations of ammonia in an intensive dairy farming area in central Japan

(pp. 41–46)
Silicon availability in 36 commercial nursery bed soils was evaluated by four methods the phosphate buffer (pH 6.2, 40 mmol L⁻¹), incubation, supernatant and acetate buffer (pH 4.0, 1 mol L⁻¹) Methods. The influence of silicon availability in the nursery bed soils on the silicon uptake of rice Oryza sativa L. cv. Hitomebore seedlings and the effect of silicon fertilizer application were examined in a glass house in 2002.
The results revealed that the best correlation between silicon content in rice seedlings and available silicon in soils was obtained with the phosphate buffer-solution method ( r  = 0.86). More precise evaluation of available silicon was achieved by grouping soils based on these phosphate absorption coefficients (PAC). The correlation coefficients between silicon content in rice seedlings and available silicon in soils were 0.92 and 0.72 for volcanic soils (PAC > 1500) and non volcanic soils (PAC < 1500), respectively.
We concluded that the phosphate buffer method is the most easily adjusted method for estimation of silicon availability in nursery bed soils, and silicon fertilizers should be applied when silicon availability in non-volcanic nursery bed soils goes below 200 mg kg⁻¹, whereas the level is less than 350 mg kg⁻¹ in volcanic soils.