室温固化淀粉基水性异氰酸酯胶的研究

以复合改性淀粉乳液、乙二酸、聚乙烯醇、聚合异氰酸酯(PMDI)为主要影响因素,以压缩剪切强度为评价指标,通过试验优化出满足JISK6806-2003指标要求的常温固化型淀粉基API的配比。经验证试验证明:优化出的较佳配比,在生产中具有可操作性,PMDI可不经封闭直接使用,能够满足现有的木制品生产工艺的要求。     

竹材原态多方重组材指接设备优化设计

对竹材原态多方重组材料纵向指接机进行了优化设计,阐述了指接机的工作原理、液压结构及设计原理,对指接机进行了运行试生产.将铣指加工的短料坯件涂胶后对接,通过指接机加压挤压,经过冷固化后使其成型.试验表明,竹材原态多方重组纵向指接机设计压力合理,运行平稳,能有效阻止多方重组材对接后因受压而产生的错位与滑动,生产的多方重组竹材的力学性能可达到相关标准的要求.     

桉树油桐尺蛾室内化学防治技术研究

以25%灭幼脲粉剂(增效型)、25%阿维菌素.灭幼脲悬浮剂、5%吡虫啉乳油、AS-2型杀虫乳剂四种化学药剂进行油桐尺蛾室内防治试验,结果表明:4种药剂对油桐尺蛾4龄幼虫具有较好的杀虫效果。25%灭幼脲粉剂(增效型)和AS-2型杀虫乳剂具有较好的杀虫速效作用;5%吡虫啉乳油具有较好的杀虫缓效作用;25%阿维菌素.灭幼脲悬浮剂兼具速效和缓效作用,为生产防治的首选药剂。     

紫外光固化油漆涂布量对木地板漆膜性能的影响

为优化番龙眼实木地板基材的紫外光固化油漆涂布量,研究油漆涂布量对漆膜附着力、耐磨性、硬度及柔韧性的影响。结果表明:随着涂布量的增加,漆膜附着力降低,耐磨性能呈线性增大,柔韧性逐渐降低。在生产中,需综合考虑漆膜性能和基材种类,以确定最佳涂布量。     

茶油皂脚脂肪酸甲酯制备的水溶性改性胺固化物性能研究

以茶油皂脚脂肪酸甲酯制备的水溶性改性胺(CA-921)与水性环氧树脂固化,通过热重分析、差示扫描量热法(DSC)、机械性能测试及扫描电镜分析,研究了环氧树脂分散相粒子的粒径和黏度、环氧基与胺氢物质的量之比及固化温度对固化物性能的影响.研究结果表明,黏度及粒径均较小的水性环氧乳液AB-EP-20与固化剂CA-921复配所...     

Nickel-catalyzed carbonization of wood for coproduction of functional carbon and fluid fuels I: production of crystallized mesoporous carbon

Japanese larch wood loaded with nickel (1%–4%) alone or with nickel and calcium (0.25%–1.5%) was carbonized at 800°–900°C for 0–120min with a heating rate of 5°–20°C min⁻¹ in a helium flow of 5.8−46.4 ml STP cm⁻² min⁻¹ to examine the influence of these variables on the crystallization of carbon (the formation of T component) and the development of mesoporosity. From the obtained results, reaction conditions suitable for effective production of carbon with the dual functions of adequate electroconductivity and adsorption capacity in liquid phase were established, thereby explaining the factors that govern the process. It was also confirmed that mesopore having a diameter of about 4 nm was selectively produced at the cost of specific (BET) surface area in parallel with the formation of T component. This result provided good insight into how the simultaneous dual function could be realized.     

新型弹性漆面实木地板漆膜耐磨性的测试

分别采用国家标准和欧洲标准,测试并对比弹性漆面地板和常规UV漆面地板的漆膜耐磨性能。结果表明:弹性漆面地板漆膜耐磨性较优,适合采用欧洲标准进行检测;而常规UV漆面实木地板宜采用相关国标进行检测。     

腰果酚环氧稀释剂与E-51树脂共混体系固化性能研究

以天然腰果酚为原料制备了一种高活性腰果酚基环氧稀释剂(CDE),利用所制备的CDE与双酚A型环氧树脂(E-51)共混,再与甲基四氢苯酐进行交联固化反应,通过力学性能测试,研究了稀释剂含量对固化物性能的影响。实验结果表明:CDE对E-51有显著的稀释增韧作用;随着CDE含量的增加,固化树脂的玻璃化转变温度逐渐降低;当CDE的加入量为20%时,固化物的冲击强度及拉伸强度达到最大值,分别为19.17 k J/m2和56.81 MPa,弯曲强度为108.8 MPa。     

枞酸烯丙酯与异海松酸烯丙酯光固化反应的比较研究

研究了枞酸烯丙酯(AA)和异海松酸烯丙酯(AI)发生UV光固化反应的区别。采用红外光谱法表征双键转化率,两者均随引发剂用量的增加先变大后减小;均随光照时间的增加呈先增大后趋于平缓的趋势,但200 s前,AA的UV固化产物双键转化率高;同等光照强度条件下AA的双键转化率高于AI。在同等固化条件下AA的表干时间比AI短,对应的相对固化速率快。以2-羟基-2-甲基苯丙酮(Darocure-1173)为光引发剂,用量为原料质量的6%,光照时间200 s,光照距离4.5 cm,光照强度100%,在此条件下,AA和AI固化产物的数均相对分子质量分别为4 176和9 407,数均聚合度分别为12和28,两者的UV固化产物均有光滑透明的外观,均具有较好的附着力、耐冲击强度及柔韧性,均通过了耐酸、耐碱、耐盐及耐水性测定,AA和AI的硬度分别为H和HB。     

Comparation on UV curing reactivity of Allyl abietate and allyl isopimarate北大核心CSCD

The UV curing reaction of the difference between allyl abietate(AA) and allyl isopimarate(AI) was studied. The conversion rate of the vinyl double bond was characterized and detected by FT-IR analysis. Results showed that conversion of double bonds are firstly increased then decreased with the increases of the dosage of initiators. Conversion of double bonds firstly increased and then leveling off with the increases of the illumination time, and AA is higher before the 200 s. AA is higher then AI under the same illumination intensity. Surface drying time of AA is shorter than AI, and relative curing speed become faster at the same conditions. Under the conditions of 2-hydroxy-2-methylpropiophenone(Darocure-1173)as photo initiator and dosage 6%, illumination time 200 s, illumination distance 4.5 cm and illumination intensity 100%, number average molecular weight of cure products of AA and AI are 4 176 and 9 407 with polymerisation degrees of 12 and 28, respectively. The obtained UV cured coating all have smooth and transparent appearance. It represented some superior properties in flexibility, mechanical impact strength, adhesive power, hardness, acid resistance, alkali resistance, salt resistance, water resistance, etc.. The hardness of AA and AI cured products are H and HB, respectively.