Synthesis of dihydroxyphenacyl glycosides for biological and medicinal study: β-oxoacteoside from Paulownia tomentosa

The protected structure of -oxoacteoside (tomentoside A), 2-oxo-2-(3,4-dihydroxyphenyl)ethyl 3-O-(2,3,4-tri-O-acetyl--l-rhamnopyranosyl)-4-O-caffeoyl--d-glucopyranoside 14 was synthesized in 14% overall yield in 11 steps, starting from d-glucose for biological and medicinal studies of phenylpropanoid glycosides. The first step was the preparation of a 3-O-rhamnopyranosyl disaccharide sugar core 2 from a suitably protected rhamnosyl trichloroacetimidate 10 and glucose derivative (diacetone-d-glucose 1) in 71% yield. To the glucose moiety of this sugar core, several protection/deprotection procedures were performed sequentially to obtain a fully acetylated sugar core 7 with a 4-OH group on the glucose moiety, in 57% yield in five steps. Thereafter, to the 4-OH group of the glucose moiety, selective 4-O-caffeoylation was achieved by proton-transfer esterification with 3,4-di-O-allylcaffeic acid 16 to give the caffeoyl disaccharide 11 in 97% yield. Then, it was converted to trichloroacetimidate 13 for a glycosylation donor in 90% in two steps. Finally, anomeric glycosylation was conducted with 2-oxo-2-(3,4-di-allyloxyphenyl)ethyl alcohol 19 with catalytic amounts of BF₃·Et₂O to give 2-oxo-2-(3,4-di-allyloxyphenyl)ethyl 2,6-di-O-acetyl-3-O-(2,3,4-tri-O-acetyl--l-rhamnopyranosyl)-4-O-(3,4-di-allyloxycaffeoyl)--d-glucopyranoside 14 in 60% yield. Deprotected intermediates of compounds 2, 11, 14, and 19 which were obtained in high yield would be useful for biological and medicinal studies of phenylpropanoid glycosides.Part of this study was presented at the 52nd Annual Meeting of the Japan Wood Research Society, Gifu, April, 2002     

探索低成本连续生产中、高密度纤维薄板和异型板的方式

连续生产中、高密度薄板的方式是采用连续双钢带冷热压机,而国内人造板设备制造行业尚无制造连续双钢带冷热压机的能力。本文依据木纤维薄板矫直原理,提出采用简易连续热辊压压机加矫直机的方案,探索低成本连续生产中、高密度纤维薄板和异型板的方式,以解决实际生产问题。     

ＦＲ—１、ＦＲ—２及ＰＦ树脂对木材阻燃、防腐、尺寸稳定等效果的研究

功能性改良药剂ＦＲ－１、ＦＲ－２及ＰＦ树脂处理马尾松、毛白杨后对木材阻燃、防腐、尺寸稳定及ＭＯＥ／ＭＯＲ的研究结果表明，ＦＲ－１处理的马尾松吸药量为３４．５kg/m^3时，氧指数可达６１％。ＦＲ－１处理的马尾松、毛白杨达到阻燃标准时，其用药理根据板材的厚度进行了初步确定，剂量范围为３０－９０kg/m^3。ＦＲ－１及ＦＲ－２在达到阻燃用药量的同时，处理后的马尾松、毛白杨耐腐试验的重量损失率小于或按拉１０％。ＦＲ－１处理的马尾松、毛白杨、吸药量分别为７５．６及９３．５kg/m^3时，吸水至饱和时，木材抗湿胀率（antiswelling ef-ficacy,ASE)分别为３０％、４６％；ＰＦ树脂处理的马尾松、毛白杨 、吸药量分别为７９．０％、６３．８kg/m^3时，ＡＳＥ分别为４６．２％、４１．４％。各处理对抗弯弹性模具（ＭＯＥ）影响为，ＦＲ－１处理的马尾松，ＭＯＥ差异不明显，ＦＲ－１处理的毛白杨，ＭＯＥ增加幅度为６．１％，ＰＦ树脂处理的马尾松，毛白杨、ＭＯＥ增加幅度分别为１０．６％及１７．９％。ＦＲ－１处理的马尾松、毛白杨对抗弯强度（ＭＯＲ）影响不明显。     

利用91卫图助手软件实现林业矢量数据坐标系的转换

以永平县林业矢量数据为例,利用91卫图助手软件和ArcGIS软件,通过北京54坐标系矢量数据在各坐标系下叠加、坐标系转换参数的计算、矢量数据坐标系的转换等步骤,阐述实现矢量数据坐标系WGS84、北京54、西安80和国家2000坐标系相互转换的方法,以实现各类自然资源矢量数据的共享。     

Use of Near Infrared Spectroscopy to Measure Mechanical Properties of Solid Wood

The visible and near infrared （NIR） （350-2500 nm） spectra and the MOE of 438 small clear wood samples from Chinese fir, eucalyptus and poplar 72 were measured. Using partial least-square （PLS） modeling, the NIR spectra could be used to predict MOE and MOR of the clear-wood samples from Chinese fir and eucalyptus solid wood. NIR spectra could only be used to Predict MOE but not MOR of poplar clear-wood samples. With the exception of MoR of poplar clear-wood samples, the correlations between NIR and the mechanical properties are very strong, and the calibration and test correlation coefficients are both above 0.80.     

城市道路网信息管理系统研究

针对国内城市交通规划缺乏完整的道路信息资料 ,提出了如何利用功能完善的EMME/2交通规划软件结合中国的交通特性 ,进行城市路网信息资料的获取 ,并提出相应的数据库记录规定 ,据此研制开发了城市道路网信息管理系统。     

森林土壤有机氮的X光吸收近边结构光谱技术测定

本研究通过采用氮的K边X光吸收近边结构(XANES)技术来了解森林土壤有机氮,以此深入研究土壤中有机氮种类与其转化的定量关系。土壤样品采自台湾中部的云杉、铁杉林与草地。结果表明,氮的 XANES 可以揭示样品中不同的氮的种类。在土壤腐植质、可溶性氮及本体土壤中胺态及吡咯氮占了主要的比率。然而不同处理及植被下的土壤样品氮的种类分布是不同的。云杉与铁杉土壤可溶性有机氮在402.3 eV 能量处有显著的差异。在A层土壤中,吡啶类氮含量要显著高于O层土壤,说明氮在不同土层中的转化率存在极大的差异,这种变化对于氮在森林土壤中的循环将起重要作用。图3表1参8。     

Salt distribution in response to optical stratification porosity and relative windspeed in a coastal forest in Niigata, Japan

Wind velocity, vertical stand structure and seasalt distribution were measured at various heights inside a plantation of coastal pine forest, with thinning and unthinning, to assess whether any relationships exist between the wind profile, stand structure and seasalt distribution in the coastal pine forest. The vertical stand structure, i.e., optical stratification porosity (OSP), which is defined as vertical distribution of the proportion of sky hemisphere not obscured by tree elements inside a forest stand, was determined for each height by computer analysis of digital images taken with a hemispherical lens. The distribution of OSP in the coastal forest follows the Lambert-Beer's law with absorbency coefficient (). The relative windspeed within canopy can be described using the exponential form with the attenuation coefficient (). The sea-salt was collected using salt gauze (a surgical dressing of loosely woven cotton) both inside and outside the coastal forest, and the distribution of sea-salt within canopy was also in accordance with an exponential function. The relationships among windspeed, OSP and sea-salt indicate that the distributions of both sea-salt and windspeed within canopy were very closely correlated with the distribution of OSP. A linear relationship between OSP and sea-salt has been found. Additionally, linear regression between coefficients and has been obtained as well. Based on these relationships between OSP, wind and sea-salt in the coastal forest, the sea-salt distribution and wind profile within the canopy of the coastal forest can be predicted according to OSP. These results may therefore be useful in analyzing the effects of sea-salt on vegetation and evaluating the filter functions of coastal forests.This revised version was published online in November 2005 with corrections to the Cover Date.     

线切割与镂铣图形的CNC自动编程及虚拟加工技术研究

以AutoCAD R14为开发平台，综合运用ObjectARX SDK、Visual C^ 6.0及CNC技术，在研究了AutoCAD R14的数据结构、平面图形CNC自动编程及加工过程仿真和虚拟现实算法基础上，开发出一种适用于CNC木工镂铣、CNC线切割和CNC激光平面轨迹加工的、集CAD／CNC APT／虚拟加工功能于一体的集成技术。该技术可直接将二维AutoCAD图形快速自动转换成二维CNC加工程序，并可对所编程序进行虚拟加工实验，以检验加工的正确性和可靠性；解决了实际二维平面图形加工CAD／CAM集成及其一体化的瓶颈问题。