Aging Behavior Analysis of Asphalt based on Nonlinear Differential Dynamic Model

In order to study aging behavior and anti aging performance of asphalt, aging tests were carried out with rolling thin film oven test(RTFOT) and oven aging test at 60℃, and aged asphalt was extracted from pavements of different service life. Viscosity of asphalt samples was fitted with nonlinear differential dynamic model. With parameter study, property changes, aging rate of asphalt and the difference of aging mechanism were analysed under different aging conditions. It was shown that the nonlinear differential dynamic model can simulate asphalt aging process in the laboratory or on site effectively. At the same time, model parameters(L and r) can quantify aging state and aging rate. Asphalt had its limited aging state corresponding with different aging temperature. Ultimate aging degree of RTFOT and field aging were about 4~5 times of that of oven aging test at 60 ℃. And aging effect of RTFOT for 6h was about equivalent with that of field aging for 6 years. Thus time delay RTFOT can simulate long term aging of pavement asphalt.     

Comparison on accuracy of different nonlinear models in predicting growth of Podolica bulls

Animal growth does not follow a linear pattern, being explained mathematically by functions that have parameters with biological meaning. These parameters are used to estimate the expected weight of animals at specific ages. Several nonlinear models have been used to describe growth. This study was carried out to estimate the parameters of logistic, Gompertz, Richards and von Bertalanffy growth curve models in a sample of Podolica young bulls to determine the goodness of fit. Animals were weighed every 3 months from birth to 810 days of age. The results indicate that all the growth models used were easily fitted to the observed data with Gompertz and logistic functions presenting less computational difficulty in terms of number of iterations to achieve convergence. Moreover, logistic and Richards equations provided the best overall fit being useful to describe the growth of Podolica bulls. Considering that the literature lacks information on growth curves in Podolica breed, the study of a mathematical model for growth describing the developmental pattern of a specific population within a peculiar environment is a useful tool to improve Podolica breed production.     

Practical Method of Form-finding of Semi-rigid Structures

Based on the discussion of the simulation for the cable prestress, the rigidity theory was used to identify the geometrical dimensions of semi-rigid structures in zero state. When the structural geometry in initial state is given, the geometrical dimension in zero state is determined by the initial prestress distribution. The contribution-matrix method is firstly applied to get the initial lack of fit. However, the influencing factor of initial lack of fit on the displacement of control point is linear superposition, that is, the structural response is linear, and it is irreconcilable with the geometry nonlinear of semi-rigid structure. In order to reduce the error of nonlinear structural response, the influencing factor in the contribution-matrix method is revised, and modified contribution-matrix method is put forward. Programs by ANSYS parameter design language APDL are worked out for the form-finding analysis of beam-string structure of a practical project. The numerical results show that the modified contribution-matrix method reduces the errors of the assumption of structural linear response. And it can be applied to the form-finding of semi-rigid structures with small stiffness.     

8-取代喹哪啶的合成与晶体结构

2-取代苯胺与巴豆醛反应合成了5种8-取代喹哪啶.讨论了反应因素对反应的影响,得到了较好的结果.8-取代喹哪啶的结构经1HNMR和MS分析确证,并用单晶X-射线衍射测定了化合物Ⅰa和Ⅰb的晶体结构.化合物Ⅰa晶体属正交晶系,空间群为Pca21,晶胞参数为:a=1.279 61(9)nm,b=0.506 60(4)nm,c=1.311 81(9)nm,Z=4,V=0.850 38(11)nm3,Dc=1.387 g/cm3,F(000)=368,R1=0.028 8,wR2=0.073 1,S=1.01;化合物Ⅰb晶体属单斜晶系,空间群为P21/c晶胞参数为:a=0.504 40(17)nm,b=1.346 7(4)nm,c=1.339 1(4)nm,β=97.678(4)°;Z=4,V=0.901 4(5)nm3,Dc=1.636 g/cm3,F(000)=440,R1=0.071 1,wR2=0.195 1,S=1.09.选择合适溶剂和添加剂,反应收率较文献值有较大提高.     

GPS网平差的多元响应模型及参数估计

本文针对CPS测量数据为多元响应数据的特点，建立了一个CPS网平差的多元响应模型，讨论了模型的性质，在几种情形下，给出了参数的极大似然估计与非线性最小二乘估计的非线性优化模型，讨论了参数估计的求解方法。     

Soil water-retention prediction from pedotransfer functions for some Indian soils

This paper discusses the development of pedotransfer functions (PTFs) and uses a multiple nonlinear regression technique to validate point and parametric PTFs for the estimation of a water-retention curve from basic soil properties such as particle-size distribution, bulk density and organic matter content. One hundred soil samples were collected at different depths from different locations in the Pavanje river basin that lies within the southern coastal region of Karnataka, India. Prediction accuracies were evaluated using the coefficient of determination (R ²), root mean square error (RMSE) and mean error (ME) between measured and predicted values. Overall, both point and parametric methods predicted water contents at selected water potentials with considerable accuracy. However, prediction of the soil water-retention curve using PTFs by point estimation method was relatively more successful (best case R ² = 0.983) for the sampled soils. F-tests were also conducted for all cases. For one regression equation, the p-value was zero and for other equation, values were close to zero. Critical comparative analysis was carried out on the performances of the point and parametric methods. Use of the developed PTFs is suggested for the prediction of a water-retention curve for loamy sand and sandy loam soils in this area of the coastal region of southern India.     

Photostabilization of quinalphos by crystal violet on the surface of kaolinite and palygorskite

Photochemical stability of the insecticide, quinalphos (O,O-diethyl O-quinoxalin-2-yl phosphorothioate), adsorbed on kaolinite and palygorskite was studied. In all cases considerable photostabilization was achieved in comparison with the sample of pesticide in its free form. Improvement of photostabilization was achieved when a cationic dye (crystal violet) was co-adsorbed with the quinalphos. The interactions between quinalphos and clays were studied by Fouriertransform infra-red spectroscopy. It is suggested that photostabilization is due to steric hindrance imposed by the clay surface to the isomerization step of photochemical reaction and pacification of clay surface by crystal violet.     

应用SPSS软件拟合Logistic曲线研究

介绍了SPSS软件中两种拟合Logistic曲线的方法和步骤,通过实例分析表明,用非线性回归(Nonlinear Regression)比曲线回归(Curve Estimation Regression)拟合Logistic曲线更简单实用。     

非线性动力特性的仿真分析

研究非线性动力特性可视化计算的仿真问题，建立了以时域微分方程描述的数学模型，探讨了该系统运动轨迹及其演变规律的可视化表示方式。     

焊接孔长度对钢框架梁-柱刚性节点性能的影响

对焊接孔长度扩大的钢框架梁－柱刚性节点进行了空间非线性有限分析。分析结果表明，焊接孔长工的扩大显著地降低了梁－柱连接面处的对接焊缝和焊接孔切角端开裂以及翼缘脆性破坏的可能性，但过长的焊接孔也会导致梁侧向稳定的丧失。