Experimental Study on the Deformation Characteristics of Fine-Sandstone Under the Loading and Unloading Conditions

The deformation characteristics of the fine-sandstone is studied under the loading and unloading conditions at the three different deformation-rates and the two different stress-levels. The experimental results show that there is really the plastic-loop in the deformation curve for the loading deformation curve is different from the unloading deformation curve. But the plastic-loop is nearly unchangeable since the second circulate loading. The residual-deformation is be almost zero since the second circulate loading, and that the slope of the deformation curve increases as the deformation-rate increases, and that the residual-deformation increases as the stress-levels increases.     

DETERMINATION OF METALLIC IRON IN HIGH TITANIUM SLAG BY HEADSPACE GAS CHROMATNGRALHY

The following details are discussed in the present paper, after high titanium slag and H3PO4 is put in the closed system,the .reaction takes place under controlled temperature conditions, and the gas produced is collected. The two phases of gas liquid attain kinetic equilibrium, ihe gas above the liquid is used to make GC analysis with the aid of chromatographic column of 5A molecular sieve, TCD and N2 30ml/min. Satisfactory quantitative results can be achieved with simple instruments and uncomplicated operation technique.     

The Feasible Control for the Day-operation of the Three-Gorge Cascade Hydropower Station

The feasible control problem is presented for the day-operation of the Three-Gorge Caseade Hydropower Station. The significance of the problem is explained. Basic propetties ofthe problem and the approaches to study it are discussed. Two methfods are given for solving theproblem. which are calculus of variation and linear programming. In the former. the Euler equationwith time-lag and the generalised two-point boundary conditions are obtained and the correspondingpractical implication is interpreted. In the latter. the rationality for the discrete model is exptainedand the computalional details are given for the implement software. some questions which should bepaid much attentfon and the corresponding propeels are prasented based on the numerical results andtheoretical analysis     

Evolvement of Plastic-loop of Fine-sandstone Under the Loading and Unloading Conditions

The deformation characteristics and the plastic-loop of the fine-sandstone is studied under the loading and(unloading) condition at the three different deformation-rates and the two different stress-levels,the results show: 1) There is really the plastic-loop in the deformation curve for the loading deformation curve is different form the unloading deformation curve.But the plastic-loop is nearly unchangeable since the second circulate loading.2) There is different for every imitational parameter between the first deformation curve and the second deformation curve at the different stress-levels and the different deformation-rates,but every imitational parameters become more and more invariable gradually since the second circulate curve.3) With the change of the deformation-rates and stress-levels,the imitational(parameters) will change with it.4) The imitational parameters are different for loading section and unloading section of the fine-sandstone deformation curve at the same circulate curve under the same deformation-rate and stress-level.     

Determination of Molecular Weight and Distribution of Hyroxyethl Starch (HES) by Means of GPC- RI- MALLS Technique

The author introduces a method and experimental procedures that determine dn/dc,molecular weight and its distribution of the hyroxyethyl starch(HES) by means of Gel Permeation Chromatography-Refractive index-Multi-angle laser light scattering detection(GPC-RI-MALLS)techniques.The key experimental technique and results are discussed.The method takes CH3COOH/CH3COONa as mobile phase and solvent.The experiment gets satisfactory results.It can be used as a routine method to determine the hyroxyethyl starch(HES) molecular weight and its distribution.     

高效液相色谱法测定复方非泼罗尼滴剂中抗氧剂的含量

建立高效液相色谱法(HPLC)测定复方非泼罗尼滴剂中抗氧剂叔丁基对羟基茴香醚(BHA)与二丁基羟基甲苯(BHT)含量。采用高效液相色谱法,色谱柱为Agilent Zorbax SB-C18(250×4.6 mm, 5μm),流动相A为乙腈-甲醇-水(47∶21∶32),混合前在水中加入1%冰醋酸,流动相B为乙腈,线性梯度洗脱;检测波长为285 nm;流速为0.9 mL/min;柱温为30℃;进样量为20μL;采用外标法计算BHA、BHT含量。在建立的色谱条件下,空白溶液、阴性样品对BHA、BHT的测定均无干扰;BHA、BHT的检测限分别为0.08μg/mL和0.19μg/mL,定量限分别为0.31μg/mL和0.77μg/mL,分别在5.13～15.39μg/mL与2.56～7.66μg/mL范围内线性关系良好;平均回收率分别为98.5%和99.9%(n=9)。所建立的方法简单易行、专属性强、准确度高、灵敏度好,可用于复方非泼罗尼滴剂中抗氧剂的含量测定。     

土壤铅和镉溶出伏安法检测中影响因素及其削弱方法研究进展

溶出伏安法具有分析速度快、成本低、灵敏度高等优点被广泛应用于检测土壤重金属含量,但在检测土壤重金属时,溶出伏安检测精度会受到多方面因素的影响。该文在介绍溶出伏安法工作原理的基础上,从伏安参数、试验条件和土壤物质成分三方面阐述溶出伏安法检测土壤Pb2+和Cd2+为的影响因素,解析各因素的影响机理,归纳影响削弱方法的研究进展。研究结论为：方波脉冲阳极溶出伏安法最常用于检测土壤Pb2+和Cd2+,伏安参数包括脉冲幅值、电压增量和脉冲频率,试验条件包括沉积时间、沉积电压和支持电解质种类及其pH值,土壤成分主要干扰因素包括非目标重金属和有机质。针对伏安参数和试验条件的影响可以设计优化试验有效削弱。针对非目标重金属和有机质的干扰影响,目前研究还没有提出有效的削弱方法。最后,展望了溶出伏安法检测土壤重金属的未来发展方向。     

水稻赖氨酸含量测定方法改进及其最优动态分类研究

赖氨酸是水稻营养成分中第一限制性氨基酸.为优化赖氨酸的测定方法,设置了本试验,通过超声振荡器取代普通振荡器,进行300W超声功率下酰化用时及染料结合反应用时的研究.结果 表明,最佳酰化用时为15min,染料结合用时为90 min.与国标法相比,优化后的方法酰化用时变长、染料结合用时变短,测定总用时明显缩短,但测定结果和...     

一种利用气相色谱快速检测瘤胃体外发酵液中三甲胺浓度的方法

本试验旨在建立一种利用气相色谱快速检测瘤胃体外发酵液中三甲胺浓度的方法.瘤胃体外发酵试验设置2个组,对照组(n=4)和试验组(n=4),试验组每个发酵瓶中添加0.0414 g三甲胺盐酸盐,发酵24 h.采用10 mol/L氢氧化钾溶液对发酵液样品进行预处理,使用WEL-PEG20M色谱柱和氢火焰离子检测器对三甲胺进行分...     

贵州省黎平县地表覆被变化引起的生态系统碳储量变化

[目的]对贵州省黎平县地表覆被变化引起的生态系统碳储量变化进行评估,为区域碳源和碳汇管理及"大生态"发展目标提供科学依据。[方法]基于黎平县2005,2010和2015年3期土地利用数据,结合CA-Markov模型和InVEST模型碳储量模块,在对土地利用变化趋势进行分析的基础上定量评估了研究区2005—2025年生态系统固碳能力。[结果]①2005—2015年,黎平县耕地、林地、未利用地呈减少趋势,草地、建设用地、水域呈增加趋势。②2015—2025年土地利用整体变化趋势与2005—2015年一致但幅度增大。耕地由2005—2015年的降幅2.37%到2015—2025年的增幅4.21%,整体趋势发生转变;③2015年黎平县生态系统总碳储量和平均碳密度分别为9.12×10~7 t和206.61 t/hm~2。自2005年以来分别下降2.00×10~5 t和0.45 t/hm~2。2025年黎平县碳储量和平均碳密度分别为8.98×10~7 t和203.44 t/hm~2。[结论]黎平县生态系统固碳能力呈减弱趋势,林地的大面积转出和建设用地的扩张是碳储量下降的直接原因,未来应加强对土地利用结构的优化。