基于UHPLC–QTOF–MS技术的五倍子单宁成分分析

目的 基于超高效液相色谱–四极杆飞行时间–质谱（UHPLC–QTOF–MS）技术分析五倍子中单宁成分,建立一种有效的五倍子单宁成分测定方法,并解析单宁的裂解规律。 方法 使用高温和超声波辅助方法提取五倍子中的酚类化合物,基于二级质谱推定化合物的裂解途径。 结果 共鉴定到20种化合物,包含14种没食子单宁、3种酚酸、2种没食子酸酯和1种黄烷醇。以高温121℃为提取条件,均未鉴定到分子质量高于1 500 Da的没食子单宁,而在超声波辅助提取的五倍子水提取液中,成功地检测到1–O–没食子酰基葡萄糖至14–O–没食子酰基葡萄糖,其中,超声功率1 500 W,提取温度65℃条件下,鉴定到更多的没食子单宁异构体。MS/MS图谱显示,五倍子单宁主要通过没食子酸、没食子酰基、糖苷、水、羧基的损失进行裂解。 结论 本研究证明,超声波辅助提取条件下,应用UHPLC–QTOF–MS技术能够全面高效地分析五倍子中的单宁成分,本研究为富含单宁的植物的化学成分研究提供参考依据。     

城市公园游人行为与植物群落微气候调节效应适应性研究

以诸暨市体育公园为研究对象,通过测试夏、冬两个季节诸暨城市公园绿地不同样地的小气候要素数值,结合游人行为观测,探究了风、湿、热等小气候要素与人群行为间的复杂关系.结果发现:①高郁闭度对T HI有一定调节作用;②乔木、草本植物和水体蒸腾作用强,具有一定保湿作用;③灌木比高大乔木对风的阻碍更明显;④坐憩行为对小气候舒适度较...     

拉市海越冬末期斑头雁行为的初步研究

2004年2月18日～3月14对在拉市海越冬斑头雁的行为进行了研究，采用瞬时扫描方法进行行为取样，并对其在越冬地的行为进行观察记录。结果表明：斑头雁通常是早上7：30后飞离夜栖地，傍晚19：30以后从主要活动地飞回夜栖地。观察后期(3月7～13日)与观察前期(2月18～25日)相比，其飞离夜栖地的时间提前约20分钟，而从觅食地飞回夜栖地的时间则要晚10～25分钟。斑头雁无论取食还是夜栖，都喜集群，通常还有其他鸟类与斑头雁混群，如赤麻鸭等。3月初，有部分斑头雁开始北迁，大部分北迁是在3月中旬。越冬末期斑头雁行为时间的分配率为取食35．01％、静栖34．95％、警戒13．88％、运动8．35％、理羽6．77％、饮水0．63％、社群行为0．41％，所占比例依次减少。经对斑头雁在陆地和水域生境中的行为样本分别进行计算，表明斑头雁在这两种生境中有不同的行为时间分配模式。在陆地里，斑头雁的主要行为是取食(约占47％)，而在水域中，斑头雁的主要行为是静栖(约占46％)，表明斑头雁的食物主要是从陆地中获取。在一天中，斑头雁的不同行为出现的高峰时间不同，取食高峰时间和警戒高峰时间在早上9：00至10：00和傍晚17：30～19：15；静栖高峰时间在14：00～17：00；运动高峰时间在10：30～12：30；理羽高峰时间在14：30～17：00。     

2001年大火对扎龙自然保护区丹顶鹤栖息与繁殖的影响

2001年8月末至10月扎龙自然保护区发生重大火灾，大火虽对保护区丹项鹤(Grus japonensis)的栖息地有一些影响，但对整个保护区丹项鹤的迁徙数量影响不大；对丹项鹤的营巢环境、巢址选择、巢材等因子产生较大影响，巢周围剩余芦苇面积、高度成为丹项鹤巢址选择的主要因子，次要因子是植被类型；大火对丹项鹤的始营巢期产生了影响，其营巢期较正常年份延缓4～5天。     

基于SCP范式的山东省家具产业组织分析

家具产业是山东省的传统优势产业,但是随着全球金融危机爆发和其他省市家具产业的快速发展,山东家具产业的发展面临着巨大的挑战。本文应用产业经济学的SCP理论,从市场结构、市场行为和市场绩效三个方面分析了山东家具产业的现状,从政府、行业协会和企业组织三个层面提出了优化山东家具产业组织的对策建议。     

基于纳米压痕技术的木材胶合界面力学行为

【目的】研究木材胶合界面的静态和动态力学行为,探讨树脂渗透对木材管胞壁层力学性能的影响,为木质复合材料制造工艺优化和增强改性提供理论依据。【方法】采用纳米压痕静态和动态力学测试技术(Nano-DMA),对针叶材火炬松与酚醛树脂(PF)、脲醛树脂(UF)胶黏剂所形成胶合界面区域各相材料的静态弹性模量、硬度、蠕变性能以及储能模量和损耗模量等力学行为进行分析。【结果】静态力学行为方面,在界面区域,PF和UF渗透进入管胞壁层后,木材管胞壁的弹性模量( E r)和硬度( H )提高;经PF渗透后,木材管胞壁的 E r和 H 分别增加7%和26%;Burgers蠕变力学模型可有效描述胶合界面区域管胞壁的纳米压痕蠕变特性,经树脂渗透后,木材管胞壁的瞬时弹性模量增加,黏弹性模量和黏性系数减小;在保载初期,PF界面区域木材管胞壁的蠕变柔量约下降60%,UF界面区域木材管胞壁的蠕变柔量约下降58%。动态力学行为方面,随着加载频率增加,界面材料的储能模量( E ′ r)逐渐增大,而损耗模量( E ″ r)和损耗因子(tan δ)呈减小趋势;当加载频率为10 Hz时,PF和UF树脂渗透使得管胞壁层的储能模量分别增加16%和29%。【结论】胶合界面区域胶黏剂进入管胞壁层,对木材管胞的静态力学性能具有增强作用,同时胶黏剂可提高管胞壁的短期抗蠕变能力;木材管胞壁具有较高的储能模量和损耗模量,而树脂的储能模量和损耗模量较低,经树脂渗透后,木材管胞壁的储能模量增加,但损耗模量和损耗因子呈下降趋势,可能对界面传递和分散应力产生不利影响。     

Nutrition analysis of forage plants and foragnig behavior of Mongolian gazella

NutritionAnalysisofForagingPlantNutritionanalysisonwinterfoodconstitutionofMongoliangazella(PIOc~gutturosa)inHulunbeirgrasslandwasmadebyuseofthemicrohistologicalanalysistechniqueoff6ces.Theresultsshowedthat21plantspecies(genus)wereavailabletoMongpliangazellainwinter(Table1).FromTable1,wecouldconcludethattheGramipeaeisthestaplefoodforMongpliangazellainwinter.*T:meansoneforagingplant'spercentageofallforagingplants.AChnatherumSPI6nd6ns,whichdistributesinlakesideandsalinizedlowland,belongs…     

Germination pretreatment and storage behavior of Terminalia laxiflora seed

Terminalia laxiflora Engl.&Diels.is an important indigenous and multi-purpose species in Ethiopia.However threatened due to low germination and its storage behavior is unknown.In this study,we aimed to(1)test pretreatments for breaking the dormancy of T.laxiflora seed and(2)determine its storage behavior.Seeds were subjected to four pretreatments such as soaking,scarification,high-temperature,and control.Experiments were done before storage and after 2 years of dry storage at cold temperature(-10℃)based on randomized design with four replicates.The first round of experimental results showed that T.laxiflora seeds with high temperature treatments at 78℃for 10 min showed significantly higher germination percentage(80%).In the second round experiment,high-temperature treatment at 78℃for15 min,cold water soaking,high-temperature treatment at78℃for 10 min,hot water soaking,and high-temperature treatment at 78℃for 5 min showed significantly higher germination percentage from the remaining treatments(75,64,58,56,and 53%,respectively).To break the dormancy of T.laxiflora seed and attain good germination result,seeds should be pretreated with high-temperature at 78℃for 10 min to test the initial germination before storage and should be pretreated with high-temperature(at 78℃for15,10,or 5 min),soaked in cold,or hot water for 24 h to monitor the germination after storage.The two experiments show that T.laxiflora produces orthodox seed.     

竹-短木组合梁受弯性能试验研究

为解决木材利用率低、成本高的问题,提出了一种以零碎短木粘结竹集成而成的竹-短木组合梁。通过3根木梁、3根直拼的竹-短木组合梁(SBT)和3根搭接的竹-实木组合梁(OBT)的三分点加载受弯对比试验,研究了其破坏形态、极限承载力和位移延性等。结果表明:竹-短木组合梁破坏类型为脆性破坏;竹-短木组合梁跨中截面沿高度应变仍基本符合平截面假定;OBT试件受弯承载力平均提高1.6%,力学性能媲美木梁;最后提出了受弯承载力计算简式,与试验结果较为吻合。竹-短木组合梁替代木梁,在小跨度木结构工程中具有应用价值。     

Stand structure, fuel loads, and fire behavior in riparian and upland forests, Sierra Nevada Mountains, USA; a comparison of current and reconstructed conditions

Fire plays an important role in shaping many Sierran coniferous forests, but longer fire return intervals and reductions in area burned have altered forest conditions. Productive, mesic riparian forests can accumulate high stem densities and fuel loads, making them susceptible to high-severity fire. Fuels treatments applied to upland forests, however, are often excluded from riparian areas due to concerns about degrading streamside and aquatic habitat and water quality. Objectives of this study were to compare stand structure, fuel loads, and potential fire behavior between adjacent riparian and upland forests under current and reconstructed active-fire regime conditions. Current fuel loads, tree diameters, heights, and height to live crown were measured in 36 paired riparian and upland plots. Historic estimates of these metrics were reconstructed using equations derived from fuel accumulation rates, current tree data, and increment cores. Fire behavior variables were modeled using Forest Vegetation Simulator Fire/Fuels Extension.Riparian forests were significantly more fire prone under current than reconstructed conditions, with greater basal area (BA) (means are 87 vs. 29 m²/ha), stand density (635 vs. 208 stems/ha), snag volume (37 vs. 2 m³/ha), duff loads (69 vs. 3 Mg/ha), total fuel loads (93 vs. 28 Mg/ha), canopy bulk density (CBD) (0.12 vs. 0.04 kg/m³), surface flame length (0.6 vs. 0.4 m), crown flame length (0.9 vs. 0.4 m), probability of torching (0.45 vs. 0.03), predicted mortality (31% vs. 17% BA), and lower torching (20 vs. 176 km/h) and crowning indices (28 vs. 62 km/h). Upland forests were also significantly more fire prone under current than reconstructed conditions, yet changes in fuels and potential fire behavior were not as large. Under current conditions, riparian forests were significantly more fire prone than upland forests, with greater stand density (635 vs. 401 stems/ha), probability of torching (0.45 vs. 0.22), predicted mortality (31% vs. 16% BA), and lower quadratic mean diameter (46 vs. 55 cm), canopy base height (6.7 vs. 9.4 m), and frequency of fire tolerant species (13% vs. 36% BA). Reconstructed riparian and upland forests were not significantly different. Our reconstruction results suggest that historic fuels and forest structure may not have differed significantly between many riparian and upland forests, consistent with earlier research suggesting similar historic fire return intervals. Under current conditions, however, modeled severity is much greater in riparian forests, suggesting forest habitat and ecosystem function may be more severely impacted by wildfire than in upland forests.