全球气候变化对我国干旱区影响分析

<正> 全球变暖问题已经是全世界关注的焦点,不仅各国科学家们进行了大量的研究,各国政府也耗费巨资组成了政府间专家组(IPCC,Intergovernmental panel on ClimateChange研究气候变化的影响。IPCC包括3个工作组,Ⅰ.科学分析工作组(Working     

Long-term impacts of an organophosphate-based regime of pesticides on field and field-edge Collembola communities

During a 6-year study, effects of two contrasting regimes of pesticide use on pitfall and suction catches of Collembola were monitored in an arable field under a rotation of grass and winter wheat. Current farm practice (CFP) represented conventional fungicide and herbicide use plus applications of organophosphorus (OP) insecticides, whereas reduced input approach (RIA) utilised minimum inputs of fungicides and herbicides and excluded any use of insecticides. Compared with RIA, the CFP regime caused a substantial decline in the abundance and diversity of Collembola in the field, including the local disappearance of one species, without recovery during the study. At the field edge, which was protected during OP applications by a 6-m unsprayed buffer zone, effects of the CFP regime were less severe, and were not persistent in the long term. Some Collembola species occurred only in field-edge samples. Pitfall and suction sampling yielded remarkably similar patterns of catches, indicating that pitfall trapping may be appropriate for detecting long-term changes in collembolan abundance caused by intensive agricultural management practices.     

Computational chemistry study of the environmentally important acid-catalyzed hydrolysis of atrazine and related 2-chloro-s-triazines

Many chlorine-containing pesticides, for example 2-chloro-s-triazines, are of great concern both environmentally and toxicologically. As a result, ascertaining or predicting the fate and transport of these compounds in soils and water is of current interest. Transformation pathways for 2-chloro-s-triazines in the environment include dealkylation, dechlorination (hydrolysis), and ring cleavage. This study explored the feasibility of using computational chemistry, specifically the hybrid density functional theory method, B3LYP, to predict hydrolysis trends of atrazine (2-chloro-N4-ethyl-N6-isopropyl-1,3,5-triazine-2,4-diamine) and related 2-chloro-s-triazines to the corresponding 2-hydroxy-s-triazines. Gas-phase energetics are described on the basis of calculations performed at the B3LYP/6-311++G(d,p)//B3LYP/6-31G* level of theory. Calculated free energies of hydrolysis (delta h G298) are nearly the same for simazine (2-chloro-N4,N6-diethyl-1,3,5-triazine-2,4-diamine), atrazine, and propazine (2-chloro-N4,N6-di-isopropyl-1,3,5-triazine-2,4-diamine), suggesting that hydrolysis is not significantly affected by the side-chain amine-nitrogen alkyl substituents. High-energy barriers also suggest that the reactions are not likely to be observed in the gas phase. Aqueous solvation effects were examined by means of self-consistent reaction field methods (SCRF). Molecular structures were optimized at the B3LYP/6-31G* level using the Onsager model, and solvation energies were calculated at the B3LYP/6-311++G(d,p) level using the isodensity surface polarizable continuum model (IPCM). Although the extent of solvent stabilization was greater for cationic species than neutral ones, the full extent of solvation is underestimated, especially for the transition state structures. As a consequence, the calculated hydrolysis barrier for protonated atrazine is exaggerated compared with the experimentally determined one. Overall, the hydrolysis reactions follow a concerted nucleophilic aromatic substitution (SNAr) pathway.     

ANSYS/FLOTRAN在温室内气流场稳态模拟的应用研究

以Navier-Stokes方程为模型基础,运用ANSYS/FLOTRAN软件对华北型机械通风式连栋塑料温室在不同山墙门打开度情况下室内的气流场进行三维稳态模拟.同时通过试验测得温室内各测点的气流流速,并分析试验数据得到温室内的气流流速的平均值.结果表明:在试验条件下山墙门打开度为2.3×2 m2,造成室内局部风速过大,流场分布紊乱;山墙门打开度为2.3×3m2,使室内风速平均值太小,达不到温室通风的要求;山墙门打开度为2.3×2.4m2时在同等条件下温室内的气流场分布均匀,平均风速最大,通风效果较理想.     

农田黑线姬鼠发生规律与防治技术

１９８５￣１９９５年１０年监测结果表明,黑线姬鼠为浙江农田优势种,每年４￣５月和９￣１０月为繁殖高峰期,６月和１０￣１１月为数量高峰。冬前冬后密度基数,种群年龄结构,繁殖力,温度,降水,天敌和药剂防治是影响种群数量变动的主要因子及预测的依据。根据害鼠密度与稻麦为类损失率及经济允许水平,提出主害期控制的鼠密度指标为：大小麦２．７％￣４．４％,早稻４．６％￣６．７％,晚稻６．９％￣８．４％,防治指标为     

桑苗圃和桑园的化学除草

用氟乐灵和精稳杀得或高效盖草能进行桑苗圃除草，用草甘磷和乙草胺混合进行桑园除草，可有效地防除杂草。     

Factors affecting the development of disease symptoms in potatoes infected by <Emphasis Type="Italic">Tobacco rattle virus</Emphasis>

Infection of potato plants with Tobacco rattle virus by its nematode vector can have different outcomes, including the development of spraing symptoms in progeny tubers. A novel syndrome described here comprises a generalized mottle in leaves on all stems, together with virtually total failure to produce daughter tubers. The outcome of infection depends partly on the potato genotype, but field trials with 15 varieties showed that the incidence and severity of spraing symptoms at three sites differed. There was no evidence that this was due to differences in virulence among the virus isolates at the sites, but it was probably the result of environmental differences that influenced the numbers and activity of the vector nematodes. At the most severely affected site, spraing symptoms were found in all varieties tested, except Record, including several that were not affected at the other two sites. Taking both severity and incidence of symptoms into account, the ranking of varieties was similar at each site. The incidence of spraing symptoms was greater in larger than in smaller tubers, and increased with later harvest dates, but did not increase when early harvested tubers were stored. Tobacco rattle viruswas detected in the roots of many of the weeds growing at one of the sites and in the roots of a few plants of the subsequent barley crop.     

5种杀虫剂超低容量液剂对玉米田草地贪夜蛾的防治效果

草地贪夜蛾是新入侵我国的迁飞性重大害虫,为害玉米的心叶、生长点及雄穗等,能引起严重的损伤、烂心、授粉不良等,导致玉米减产甚至绝产。本文评价了5种杀虫剂超低容量液剂通过低容量喷雾对玉米田草地贪夜蛾的防治效果。结果表明,在相同的原药成本下,6%甲维·茚虫威超低容量液剂和1%甲氨基阿维菌素苯甲酸盐超低容量液剂具有优异的保叶效果和杀虫效果,5%氯虫苯甲酰胺超低容量液剂在较低的用量下(有效用量1 g/667m~2)具有良好的保叶和杀虫效果,3%呋虫胺超低容量液剂对草地贪夜蛾幼虫基本无效,但有一定的保叶效果。     

紫肉火龙果保护地栽培技术

紫肉火龙果为热带植物、亚热带植物,喜光耐阴、耐热耐旱。北方栽培要利用温室、塑料大棚等保护地生产。在栽培管理中利用水泥杆做支架,选向阳地段建园,栽培管理要薄肥勤施,及时浇水和排水,进行摘心、绑缚、修剪等植株管理,授粉、疏花疏果等花果管理,加强保护地温度、光照、空气湿度管理。     

三唑磷在竹笋中的残留分析与消解动态

运用气相色谱法分析了竹笋中三唑磷的残留量和消解动态,建立了三唑磷的消解动态方程。竹笋样品经乙腈匀浆、净化后,在DB-1701色谱柱中分离并采用GC-FPD分析,当添加水平为0.01~0.1 mg/kg时,竹笋中三唑磷的平均添加回收率为94.0% ~101.5%,相对标准偏差在1.6% ~18.2%之间,以3倍基线噪音作为最小检出限,得到最小检出量为5×10-12 g,最低检测浓度为 0.01 mg/kg。田间残留消解试验表明: 竹笋对三唑磷的吸收在施药后1 d达到高峰,之后缓慢下降,药后30 d接近最低检测浓度0.01 mg/kg,半衰期为3.7 d,消解到0.01 mg/kg的时间为药后30.2 d,其消解方程ct=2.738 5e-0.186 t。建议三唑磷在竹笋上的安全间隔期应大于21 d。