Surface-active properties of particle size fractions in two humic acids

The relationships between surface active properties and humic acid (HA) particle sizes were investigated. Two HAs from an Ando soil and a Brown forest soil were separated into 6 particle size fractions by gel permeation chromatography. Surface-active properties characterized by surface excess value (\gT mol cm^-2), cross-sectional surface area per molecule (A nm²), critical micelle concentration (CMC g L^-1), efficiency and effectiveness of water surface tension reduction were obtained by the measurement of the surface tension of HA solutions from different particle size fractions. For the HA from the Ando soil, except for the smallest particle size fraction, increasing particle size enhanced the efficiency of reduction of the water surface tension and decreased the CMC, while the effectiveness of reduction of the water surface tension was about the same. The surface activity of the HA from the Ando soil increased with increasing particle size. This phenomenon was similar to the surface activity of a homologous series of surfactants, which increased with increasing alkyl chain length. For the HA from the Brown forest soil, the smallest particle size fraction and three large fractions showed a high efficiency, namely a high surface activity. The smallest fraction from the Brown forest soil showed the highest efficiency and the lowest CMC value. In both HAs, the smallest particle size fraction showed exceptional surface-active properties compared with the other fractions and three fractions with large particle size showed a higher surface activity than other smaller fractions.     

Soil Redistribution investigations by combined use of soil 137Cs and selected chemical properties

Abstract

To improve the methods of application of phosphorus or supply of soil P to Azolla (A. microphylld), basal application, split application, inoculation of P-enriched Azolla, and soil disturbance were compared. Soil disturbance did not increase the floodwater P content. Phosphorus was applied to inoculum production plots to enrich Azolla with P. Thus, phosphorus-enriched Azolla could multiply 5–7 times after inoculation until it became P deficient. Trials on the methods of enrichment of Azolla with P showed that the best method was to broadcast twice 4.33 kg P (10 kg P₂O₅/ha) at 2-day intervals and to harvest Azolla 3 days after P application. Addition of P once or twice 2 weeks after the inoculation of P-enriched Azolla further increased the biomass production. Efficiency of P application was analyzed in terms of N gain in relation to the amount of P applied. This ratio in the P-enriched Azolla treatment was higher than the economically sound ratio -5-, and higher than or equal to that in the standard split application.     

协助自然修复微量元素污染酸性土壤研究：8年田间试验

There are many remediation techniques for organic contaminated soils,but relatively few of them are applicable to trace elementcontaminated soils.A field experiment was carried out to investigate assisted natural remediation（ANR） of an acid soil contaminated by As,Cd,Cu,Zn and Pb using one inorganic amendment,sugar beet lime（SL）,and two organic amendments,biosolid compost（BC）and leonardeite（LE）.The experiment was arranged in a completely randomized block design with four treatments in three replicates:1) a non-amended control（NA）;2) SL amended at 30 Mg ha^-1 year^-1;3) BC amended at 30 Mg ha^-1 year^-1 and 4) LE amended at 20 Mg ha^-1 year^-1 plus SL amended at 10 Mg ha^-1 year^-1（LESL）.The amended plots received two doses of each amendment（DO2）:one in October 2002 and another in October 2003.The plots were then divided in half into two subpolts and one subplot received another two doses of the same amendments（DO4） in October 2005 and October 2006.In 2011,the pH values of the amended soils were greater than that of the NA soil,with the SL-amended soil showing the highest pH.Total organic carbon（TOC） was also greater in the amended soil,and greater with DO4 than with DO2.Amendments reduced the concentrations of 0.01 mol L^-1 CaCl₂-extractable Cd,Cu and Zn,especially in the SL-amended soil.Plant cover of colonizing vegetation was enhanced by amendments,but was independent of amendment doses.Changes in soil properties from 2003 to 2011 showed that the first amendment application of DO2 caused a high differentiation between all the amendment treatments and the NA treatment.After the second application of DO2,soil pH and TOC continued increasing slowly.Further two applications of amendments（DO4） caused differences only in the organic treatments.Plant cover increased over time in all the treatments including NA.It could be concluded that the slow and steady natural remediation of this soil could be enhanced by amendment application（ANR）.     

不同母质发育土壤的中红外吸收光谱特征

选取湘东丘陵区四种典型母质发育土壤(酸性紫色土、花岗岩红壤、板岩红壤和第四纪红土红壤),采集剖面(深至母岩/母质层)样品,应用傅里叶变换红外光谱仪研究灼烧去除有机质处理、土层深度和母质类型对土壤中红外吸收光谱特征的影响,分析吸收光谱与土壤理化性质的关系。结果表明,去除有机质后,特征区的中红外吸收值升高,反映矿物质对红外吸收谱线的强烈影响。在剖面上,底土(60~80 cm或100~120 cm)的中红外吸收值高于表土(0~20 cm),与土壤有机质含量的剖面分布相反。四种土壤的中红外光谱均属典型的高岭石图谱。砂粒、粘粒含量与红外吸收值的相关性最好,砂粒含量的最大相关系数(0.51)出现在3700、913和720~540 cm~(-1)附近,粘粒含量的最大相关系数(0.54)出现在1100~694 cm~(-1);本研究表明,原土的中红外吸收光谱特征主要受矿物质的支配,可以很好地反映土壤质地的状况,指示土壤质量变化。     

不同品种小麦籽粒中戊聚糖含量分析

从全国小麦主产区收集弱筋小麦品种19份、强筋品种24份,对小麦籽粒中的戊聚糖含量以及籽粒基本品质特性进行了测定与统计分析。结果显示,不同类型与品种的小麦籽粒中总戊聚糖(TP)和水溶性戊聚糖(WSP)含量存在极显著差异（P<0.01）;强筋小麦的TP和水不溶性戊聚糖（WUP）平均值较弱筋小麦的偏高,但二者的WSP平均值基本一致。对籽粒的戊聚糖含量与其品质特性进行相关性分析发现,强筋小麦籽粒的WSP含量与籽粒蛋白质含量、湿面筋含量、zel沉降值、面团稳定时间存在正相关关系;弱筋小麦籽粒WSP含量与籽粒蛋白质含量、湿面筋含量、硬度、zel沉降值、形成时间存在负相关关系。通径分析结果显示,蛋白质与湿面筋含量对戊聚糖含量的影响更为显著。由本研究得出结论,强筋与弱筋类型小麦的品质指标对戊聚糖含量的影响有明显不同,建议未来戊聚糖的研究按小麦类型区别对待。     

运用模糊隶属度进行土壤属性制图的研究——以黑龙江鹤山农场研究区为例

通过传统土壤类型图所得的土壤属性图已不能满足精准农业和生态环境模型所需土壤属性的精度,而目前应用较多的统计方法和地统计方法均存在一定的局限性。鉴于此,本文探索了一种采用模糊聚类获取模糊隶属度进行土壤属性制图的方法。首先,采用模糊c均值聚类(Fuzzyc-means clustering,FCM)方法对环境因子进行聚类,通过野外采样(称为建模点)建立土壤-环境关系知识;然后,计算区域内各像元点对土壤类型的模糊隶属度;最后,对模糊隶属度采用加权平均的方法获取土壤属性值。将该方法应用于黑龙江鹤山农场老莱河流域的研究小区,以土体厚度和表层有机质为例进行土壤属性制图。为了评价该方法的有效性,将其与采用环境因子所建立的多元线性回归模型进行比较,通过野外验证点集评价两种模型所得的土壤属性,评价指标为观测值和预测值的相关系数、平均绝对误差(MAE)、均方根误差(RMSE)和准确度(AC)。结果表明,尽管通过建模点建立的多元线性回归方程R2较大,但该方程并不适用于研究区内的其他样本点,这表明多元线性回归方法在该区具有一定的局限性。与之相比,模糊隶属度加权平均的方法则可以通过较少的建模点得到更好的预测效果。     

植物单宁酸交联明胶的条件优化及性质分析

该文用单宁酸作交联剂对明胶进行交联改性,通过响应面法优化反应条件并建立回归模型,并对交联前后的明胶进行十二烷基磺酸钠-聚丙烯酰胺凝胶电泳(SDS-PAGE)、紫外光谱和黏度等3方面的分析测定,确认单宁酸交联对明胶所产生的交联作用,开发新食品配料交联明胶。结果显示:适宜的交联反应条件为反应温度47.5℃,时间50h,单宁酸添加量80mg/g明胶。性质分析表明,与原料明胶相比交联明胶一些性质发生变化,紫外光谱分析发现交联明胶在276nm出现新吸收峰,表明交联明胶分子中存在苯环;电泳后交联明胶的蛋白质条带色泽明显变浅,且交联度越大条带色泽越浅,此外,交联明胶溶液的黏度明显增大,说明单宁酸交联处理使交联明胶中有更多的大分子物质生成。     

Characterizing Spatial Variability of Soil Textural Fractions and Fractal Parameters Derived from Particle Size Distributions

Soil particle size distribution (PSD) is a fundamental physical property affecting other soil properties. Characterizing spatial variability of soil texture is very important in environmental research. The objectives of this work were: 1) to partition PSD of 75 soil samples, collected from a flat field in the University of Guilan, Iran, into two scaling domains using a piecewise fractal model to evaluate the relationships between fractal dimensions of scaling domains and soil clay, silt, and sand fractions and 2) to assess the potential of fractal parameters as an index used in a geostatistical approach reflecting the spatial variability of soil texture. Features of PSD of soil samples were studied using fractal geometry, and geostatistical techniques were used to characterize the spatial variability of fractal and soil textural parameters. There were two scaling domains for the PSD of soil samples. The fractal dimensions of these two scaling domains (D₁ and D₂) were then used to characterize different ranges of soil particle sizes and their relationships to the soil textural parameters. There was a positive correlation between D₁ and clay content (R² = 0.924), a negative correlation between D₁ and silt content (R² = 0.801), and a negative correlation between D₂ and sand content (R² = 0.913). The geometric mean diameter of soil particles had a negative correlation with D₁ (R² = 0.569) and D₂ (R² = 0.682). Semivariograms of fractal dimensions and soil textural parameters were calculated and the maps of spatial variation of D₁ and D₂ and soil PSD parameters were provided using ordinary kriging. The results showed that there were also spatial correlations between D₁ and D₂ and particle size fractions. According to the semivariogram models and validation parameters, the fractal parameters had powerful spatial structure and could better describe the spatial variability of soil texture.     

方便米饭加工工艺及生产原料适应性研究

选择12种我国不同产地的大米,通过相关性分析,研究方便米饭感官品质与大米主要化学成分及蒸煮性质之间的关系。结果表明,原料大米的主要化学成分与米饭的蒸煮性质对方便米饭感官品质有明显影响,特别是大米的直链淀粉含量与感官评定呈极显著负相关,硬度,胶稠度也都与感官评定有不同显著程度的相关性;直链淀粉含量低,胶稠度较低,含水量适中的大米生产的方便米饭有较好的感官品质。     

山东禹城地区土壤入渗特性的空间变异研究

在中科院禹城综合试验站102 m×52 m面积内选择样点,采用经典统计学和地质统计学方法,对土壤稳渗率和入渗经验指数的空间变异性进行研究.结果表明,土壤稳渗率和入渗经验指数均服从对数正态分布,表现出空间变异结构,但不是完全的随机变异,在一定范围内存在着空间相关现象.利用克立格最优内插估值法,绘制了土壤稳渗率和入渗经验指数的等值线图,可准确、直观地了解该地区农田土壤垂向透水性的空间分布规律.