不同配比施肥对华北花岗片麻岩山地土壤促成的作用

华北花岗片麻岩山区土壤严重退化,恶劣的土壤环境是该地区植被恢复的限制性因子.利用不同配比的化肥对试验区内土壤进行促成技术研究,结果表明:各种配比的肥料间,对土壤有机质和营养元素的影响(以全P释放量为例),以NPK1和NPK2处理效果最好,其分别提高风化速率29.68%和31.21%;对土壤粒径的影响(以<1 mm粒径土壤重量百分比为例),同样以NPK1和NPK2处理效果最好,其分别提高风化速率30.50%和24.81%.综上分析可以说明,各种配比的化肥对土壤促成起到了一定的作用,试验区内土壤正朝成熟土壤方向演化.     

Evaluation of elemental depletion weathering rate estimation methods on acid-sensitive soils of north-eastern Alberta, Canada

Immobile element-based weathering estimation methods assume that Zr (or Ti) is an immobile element, and that weathering rates of other elements can be estimated according to the enrichment of Zr in weathered horizons relative to an unweathered parent material. This approach was used to estimate base cation weathering rates for 33 soil profiles on acid-sensitive terrain in north-eastern Alberta. Zirconium generally showed enrichment within the rooting zone, but the deepest (subsoil) samples were not always associated with the lowest Zr concentrations. Weathering rates estimated with the Zr depletion and Pedological Mass Balance (PMB) methods were generally low (ranges: 0-51 and 0-58 mmol_c m^− 2 yr^− 1, respectively); however, low base cation oxide concentrations and heterogeneity within soil profiles complicated weathering rate calculations and net base cation gains were calculated for several (six) sites. Evaluation of the Zr depletion and PMB weathering estimates against those calculated with the process-oriented PROFILE model at a subset (n = 9) of the sites indicated the estimates were poorly related, with PROFILE rates typically being higher. The effects-based emissions management strategy for acid precursors in this region requires spatial coverage of soil properties (including weathering rates) across a large area, but the apparent limitations associated with the immobile element based methods in this region: identifying representative parent soils and deriving weathering rate estimates comparable to more robust methods are arguments against their candidacy for future use.     

花岗岩风化产物中高岭石和埃洛石的粒径分布及其对土壤发生的意义

The kaolins collected from a profile of weathered granite at Yichun County, Jiangxi Province have been subjected to particle size fractionation by the conventional sedimentation method and examined by XRD, SEM and TEM. All of them exhibit a mixture phase of poorly crystallized kaolinites and halloysites (0.7 nm) occurring as the main clay minerals. Electron micrographs reveal that plate kaolinites are the principal constitution in the coarse fraction, and more tubular and curled halloysite (0.7 nm) in the fine fraction. Both of them show normal probability curves in particle size distributions. The ratios of kaolinite and halloysite (0.7 nm) in different size fractions are examined by X-ray diffraction with a series of X-ray patterns characterized by three main peaks at d(001), d(002) and d(020),varying in intensity. Therefore, an index Q_hm expressed as (I_d(001) + I_d(002))/(2×I_d(002)), is designed to indicate relative ratios of the two clay minerals in a number of mixture phases. Because kaolinite and halloysite (0.7 nm) commonly occurred, respectively, in low and medium leaching microenvironment, the index Q_hm, can be used to indicate weathering and pedogenic conditions of a weathering crust.     

Contribution of Parker and Product indexes to evaluate weathering condition of Yellow Brown Forest soils in Japan

Soil weathering is recognizable through study on physico-chemical characteristics of soil. In this study, Parker, ([(Na)_a / 0.35] + [(Mg)_a / 0.9] + [(K)_a / 0.25] + [(Ca)_a / 0.7]) × 100, and Product, [SiO₂ / (TiO₂ + Fe₂O₃ + SiO₂ + Al₂O₃)] × 100, weathering indexes, originally developed for study on rocks, were tested on Yellow Brown Forest soils from two different regions in Japan. The results showed that the contribution of the mentioned indexes can be used for study on soils weathering. In other word, in a two-dimensional coordination system where the axes are Parker and Product indexes, regarding to the chemical bases of the indexes, initial and lateral products of weathering can be tracked at the same time.

Additionally, the indexes relations with soil color were studied after exposing the samples at a high temperature. Remarkable relationships between a* / b* ratio–parameters of psychometric chromaticness of color in CIE color standard system–and these two weathering indexes demonstrated that a* / b* ratio can be applied reliably to estimate the quantities of Parker and Product indexes in Yellow Brown Forest soils.     

喀斯特山区不同土地利用方式下石灰土化学风化特性

研究喀斯特山区不同土地利用方式（耕地、荒草地、退耕还草地和林草间作地）石灰土剖面化学风化特征，探讨矿质元素在石灰土剖面的分布、迁移和富集特征，从不同土地利用方式下土壤风化度，元素淋溶度、迁移度和残积度的角度分析土壤化学风化特征。结果表明：喀斯特山区石灰土剖面氧化物含量以SiO₂、Al₂O₃、Fe₂O₃为主，其他氧化物含量相对较低，均属于中等变异元素，SiO₂、Al₂O₃、MgO含量以荒草地较高，CaO、Na₂O含量以林草间作地较高，Fe₂O₃、MnO、P₂O₅、K₂O以耕地较高；研究区土壤处于中等化学风化阶段，富铝化程度弱，不同土地利用方式下荒草地土壤化学蚀变系数较强，林草间作地土壤富铝化程度较高；研究区土壤K、Na、Ca淋失严重，荒草地盐基离子淋失明显，林草间作地盐基离子淋失程度相对较低；土壤Fe、Al相对富集明显，残积程度高，林草间作地Al含量积累明显，退耕还草地Fe含量富集显著；实施“退耕—还草”等增加植被覆盖度的治理模式对土壤的保护作用显著。     

A model for simulating rock–water interactions in a weathering profile subjected to frequent alternations of wetting and drying

Physically based equations for unsaturated groundwater flow and solute transport have been coupled with kinetic rate laws for mineral dissolution–precipitation, and mass balance/mass action equations for aqueous species, in a numerical model that is capable of simulating rock–water interactions in a weathering profile subjected to fluctuating boundary conditions. A numerical experiment was conducted to demonstrate how incipient soil development may proceed in a warm subhumid environment. The simulation involved a hypothetical coarse-textured parent material that was subjected to frequent wetting and drying during an annual water cycle. The hypothetical weathering profile evolved rapidly; dissolution of primary minerals (enstatite, forsterite, and diopside) and precipitation of secondary clay–minerals (kaolinite and Ca-montmorillonite) occurred monotonically despite the abrupt fluctuations in soil-moisture content. In contrast, the activities of aqueous species and dissolution–precipitation rates of calcite were very sensitive to the changing moisture conditions in the upper part of the profile. Although the simulation involved numerous simplifying assumptions, reasonable results were achieved and the calculated (from the model) rate of chemical denudation fell within the range of contemporary denudation rates determined from the dissolved loads of rivers.     

青藏高原爬坡沙丘地表沉积物特征分析——以柴达木盆地托拉海河为例

为了阐明青藏高原爬坡沙丘的物源及沉积学意义并揭示其形成机理,对托拉海河爬坡沙丘进行断面采样,分析爬坡沙丘不同地形部位的粒度与地球化学元素特征。结果表明,托拉海河爬坡沙丘地表沉积物的粒度组成总体以极细砂、细砂、中砂为主,粒度特征表现出明显的风成特点;不同地形部位,粒度特征呈现不同的递变规律,自河床到迎风坡顶粒径变粗,分选变好,迎风坡顶到背风坡,粒径粗细混杂,分选变差。沉积物地球化学元素组成以Si、Al、Ca为主,和上陆壳(UCC)相比,除Co、As、CaO、SiO2以外,其余元素都有一定的亏损,不同部位化学元素分布具有一定相似性,且常量氧化物之间有较好的相关性,表明其具有相似的沉积环境。A-CN-K图解及CIA值揭示了托拉海河爬坡沙丘地表沉积物化学风化处于较低程度,大部分化学元素没有显著的风化或迁移,整体属于早期去Na、Ca的阶段;A-CNK-FM图则表明整个断面Fe、Mg元素在空间分布上存在一定的差异,Fe、Mg流失主要是差异风力风选的结果。从化学风化指标来看,不同地形部位风化程度不同,河床风化程度最弱,山地迎风坡的风化程度最强;河床与河流阶地的物源呈现多样性,而迎风坡和背风坡物源较为单一,可能是古沙翻新和就地起沙。因此,初步认为托拉海河爬坡沙丘的形成经历了两个阶段:一是古沙丘形成阶段;二是现代爬坡沙丘形成阶段。在不同空间尺度上,托拉海河爬坡沙丘地表沉积物的理化特征差异与风动力和水动力的差异有关,反映出沉积物对风、水交互作用的响应。     

自然降水条件下煤矸石坡土壤含水量及径流变化

为了防止矸石山水土流失,促进煤矿废弃地植被恢复,对自然降水条件下煤矸石坡面含水量及径流变化进行观测,研究降水量及风化年限对煤矸石坡面各层含水量及产流量的影响.结果表明:1)在小雨(＜10 mm/d)条件下,煤矸石坡地表、地下径流量接近;在中雨(≥10 mm/d,＜25 mm/d)及大雨(≥25 mm/d)条件下,降雨主要以地下径流的形式流失.在小雨情况下,煤矸石坡产生的地表径流、地下径流量均较少;中雨的发生频率和累计降水量最高,累计产生的地表径流量最高;大雨发生频率最低,累计产生的地下径流量和总径流量最高.2)地表径流量与降水量显著正相关,地下径流量与最大降雨强度、平均降雨强度显著正相关.3)由于风化程度增加,与2013年相比,2014年次小雨产生的地表径流、地下径流和总径流分别降低50％、100％、80％,次中雨产生的地表径流、地下径流和总径流分别降低88％、82％、97％.4)煤矸石具有一定的蓄水能力,20 ～ 30 cm含水量最高.随着风化程度增加,10 ～ 30 cm含水量增加.尽管10 cm风化程度高,但是由于表层蒸发,含水量较低.5)由于煤矸石颗粒粗大、渗透性强,在小雨、中雨、大雨条件下,矸石坡产生的地表径流量均小于土坡,分别为土坡的4％、26％、19％.     

Interactions between mycorrhizal fungi and mycorrhizosphere bacteria during mineral weathering: Budget analysis and bacterial quantification

The impact of ectomycorrhizal fungi or rhizosphere bacteria on tree seedling growth and nutrient uptake is well known. However, few studies have combined those microorganisms in one experiment to clarify their relative contribution and interactions in nutrient acquisition. Here, we monitored the respective contributions of pine roots, two ubiquitous forest ectomycorrhizal fungi Scleroderma citrinum and Laccaria bicolor, and two S. citrinum-mycorrhizosphere bacterial strains of Burkholderia glathei and Collimonas sp., on mineral weathering, nutrient uptake, and plant growth. Pinus sylvestris plants were grown on quartz–biotite substrate and inoculated or not with combinations of mycorrhizal fungi and/or bacterial strains. Magnesium and potassium fluxes were measured and nutrient budgets were calculated. Both ectomycorrhizal fungi significantly increased Mg plant uptake. No significant effects of the two bacterial strains were detected on the K and Mg budgets, but co-inoculating the mycorrhizal fungus S. citrinum and the efficient mineral-weathering B. glathei bacterial strain significantly improved the Mg budget. Similarly, co-inoculating S. citrinum with the Collimonas sp. bacterial strain significantly improved the pine biomass compared to non-inoculated pine plants. In order to better understand this process, we monitored the survival of the inoculated bacterial strains in the quartz–biotite substrate, the pine rhizosphere, and the mycorrhizal niche. The results showed that the two bacterial strains harboured different colonization behaviours both of which depended on the presence of the ectomycorrhizal partner. The populations of the Burkholderia strain were maintained in all these environments with a significantly higher density in the mycorrhizal niche, especially of S. citrinum. In contrast the population of the Collimonas strain reached the detection level except in the treatment inoculated with S. citrinum. These results highlight the need for taking into account the ecology of the microorganisms, and more specifically the fungal–bacterial interactions, when studying mineral weathering and plant nutrition.     

紫色土壤风化发育程度与“钛值”关系的研究

在重庆地区按紫色土壤习惯命名采集各主要紫色地层母岩发育的54个土壤剖面样品,并进行全钛和无定形钛含量测定。结果表明:供试紫色土全钛含量范围为TiO22.70~23.9 g kg-1,平均值7.52±3.90 g kg-1;土壤全钛含量高低主要与成土紫色母岩有关,而受土壤风化发育程度的影响不大,在剖面中分布规律不明显;用土壤"钛值"(全钛/无定形钛)比较,各紫色地层母岩初期风化发育的土壤(如石骨子土)钛值大小与母岩基本保持一致,表现为:三叠系飞仙关组(T1f)>侏罗系蓬莱镇(J3p)>侏罗系自流井组(J1—2z)>侏罗系沙溪庙组(J2s)>侏罗系遂宁组(J3s)>白垩系夹关组(K2j);但随土壤风化发育程度加深,钛值显著降低,且钛值大小顺序与土壤硅铝铁率所描述的土壤风化发育程度结果基本吻合,二者达极显著相关(r=-0.809 1**),如果将紫色土壤钛值大小划分为Ⅰ~Ⅶ级,则可将不同风化发育度的紫色土壤归入相应的级别中,据此,可按级别对紫色土壤的风化发育程度做出描述。