不同灌溉定额对膜下滴灌水稻耗水特征及水分生产效率的影响

【目的】研究膜下滴灌水稻不同水分处理对耗水特征和水分生产效率的影响。【方法】2017年设置5个灌溉定额,对比分析不同水分处理下水稻产量、各生育期耗水量。【结果】W₅处理(灌溉定额910.00 mm)的水稻产量比其他处理分别增加21.95%~458.43%。膜下滴灌水稻全生育期5个水分处理的耗水强度分别为3.75~7.14 mm/d。随着灌水量减少叶面积衰减指数逐渐增大,叶片表现出早衰特征,株高受到灌水量抑制。W₅处理与其他处理水分生产率相比分别提高7.61%~193.06%。生育阶段耗水强度变化规律为拔节孕穗期＞抽穗扬花期＞灌浆期＞分蘖期＞成熟期＞苗期。【结论】水稻全生育期适宜灌溉定额910.00 mm,在拔节孕穗期、分蘖期2个关键需水期,满足水稻水分需求。     

褐土区氮磷在土壤发生层中淋溶的差异性

农业氮磷淋溶已经成为地下水污染最普遍和突出的问题。为揭示氮磷在包气带不同土层的淋溶特征,以典型褐土的5个土壤发生层（耕层、淋溶层、钙积层、黏化层和母质层）为研究对象,采用室内土柱模拟淋溶试验,在施肥量相同的条件下分析不同形态氮磷淋溶量,研究氮磷在不同土壤发生层中的迁移特征及其影响因素。结果表明：1）进行5次淋溶,耕层、淋溶层、钙积层、黏化层和母质层淋溶液中可溶性总氮总量分别为2412.63 mg·L^-1、3028.94 mg·L^-1、244.16 mg·L^-1、3648.99 mg·L^-1和3356.51 mg·L^-1,淋溶层、黏化层和母质层可溶性总氮淋溶量显著高于耕层,而钙积层可溶性总氮淋溶量较耕层显著减少;耕层淋溶液中可溶性总磷总量为0.52 mg·L^-1,且显著高于其他4层。2）在试验初期,耕层、淋溶层的硝态氮、可溶性总氮和正磷酸盐淋溶量显著高于黏化层和母质层,进行到第4、5次淋溶,黏化层、母质层的硝态氮和可溶性总氮淋溶量显著高于其他3层,而各发生层间正磷酸盐淋溶量无显著差异;单次淋溶黏化层和母质层铵态氮淋溶量均显著高于其他3层,而耕层可溶性总磷淋溶量始终显著高于其他各层。3）耕层和钙积层的淋溶液中硝态氮是氮素淋溶的主要形态,占可溶性总氮比例分别为69.0%和85.4%,而在淋溶层、黏化层和母质层中分别为41.3%、5.1%和4.6%;在可溶性磷中,以无机态正磷酸盐为主,最高占可溶性总磷的75.9%。4）土壤有机质含量、阳离子交换量、黏粒含量对土壤氮磷的迁移转化有明显主导作用。有机质与氮磷淋溶量呈显著正相关关系,有机质含量高,会增加淋溶初期氮磷的淋溶风险;而阳离子交换量和黏粒含量则与氮磷淋溶呈显著负相关关系,阳离子交换量大和黏粒多能减少氮磷素的淋溶风险。该试验结果说明,由于5种发生层土壤理化性质不同,各发生层氮磷淋溶特征及其淋溶形态也有差异,并且氮磷的淋溶受土壤本身阳离子交换量、黏粒和有机质含量的影响。     

不同灌溉施肥方式的土壤硝态氮分布特性试验研究

通过大田测坑玉米种植试验研究,分析了常规畦灌和膜孔灌条件下农田土壤硝态氮的分布特性。结果表明:膜孔灌溉0~60 cm土层的硝态氮在作物的整个生育期变化较大,60 cm以下变化平缓,上下土层硝态氮含量差异相对较小。而常规畦灌在0~40 cm内变化较大,上下土层间硝态氮含量差异较大。两种灌溉方式,表层土壤的硝态氮含量在整个玉米生育期为双峰形式,以三叶期和抽穗期为最高。与常规畦灌相比,膜孔灌溉消除了硝态氮的表聚现象,土壤剖面硝态氮分布更趋合理,更加有利于作物的吸收利用。膜孔灌溉由于其覆膜作用,减轻了硝态氮的淋洗,提高了氮素的利用率。     

Reduced metribuzin pollution with phosphatidylcholine-clay formulations

BACKGROUND: Metribuzin is a widely used herbicide that has been identified as a groundwater contaminant. In this study, slow‐release formulations of metribuzin were designed by encapsulating the active ingredient in phosphatidylcholine (PC) vesicles and adsorbing the vesicles onto montmorillonite. RESULTS: The maximum active ingredient content in the slow‐release formulations was 246 g kg^?1. Infrared spectroscopy results revealed that the hydrophobic interactions between metribuzin and the alkyl chains on PC were necessary for encapsulation. In addition, water bridges connecting the herbicide and the PC headgroup enhanced the solubility of metribuzin in PC. Adsorption experiments in soils were performed to evaluate the relationship between sorption and leaching. Funnel experiments in a sandy soil revealed that the herbicide was not irreversibly retained in the formulation matrix. In soil column experiments, PC–clay formulations enhanced herbicide accumulation and biological activity in the top soil layer relative to a commercial formulation. PC–clay formulations also reduced the dissipation of metribuzin by a factor of 1.6–2.5. CONCLUSIONS: A reduction in the recommended dose of metribuzin can be achieved by employing PC–clay formulations, which reduces the environmental risk associated with herbicide applications. Moreover, PC and montmorillonite are non‐toxic and do not negatively affect the environment. Copyright © 2010 Society of Chemical Industry     

Effect of pesticide fate parameters and their uncertainty on the selection of 'worst-case' scenarios of pesticide leaching to groundwater

BACKGROUND: For the registration of pesticides in the European Union, model simulations for worst‐case scenarios are used to demonstrate that leaching concentrations to groundwater do not exceed a critical threshold. A worst‐case scenario is a combination of soil and climate properties for which predicted leaching concentrations are higher than a certain percentile of the spatial concentration distribution within a region. The derivation of scenarios is complicated by uncertainty about soil and pesticide fate parameters. As the ranking of climate and soil property combinations according to predicted leaching concentrations is different for different pesticides, the worst‐case scenario for one pesticide may misrepresent the worst case for another pesticide, which leads to ‘scenario uncertainty’. RESULTS: Pesticide fate parameter uncertainty led to higher concentrations in the higher percentiles of spatial concentration distributions, especially for distributions in smaller and more homogeneous regions. The effect of pesticide fate parameter uncertainty on the spatial concentration distribution was small when compared with the uncertainty of local concentration predictions and with the scenario uncertainty. CONCLUSION: Uncertainty in pesticide fate parameters and scenario uncertainty can be accounted for using higher percentiles of spatial concentration distributions and considering a range of pesticides for the scenario selection. Copyright © 2010 Society of Chemical Industry     

The environmental fate of diuron under a conventional production regime in a sugarcane farm during the plant cane phase

BACKGROUND: Field studies of diuron and its metabolites 3-(3,4-dichlorophenyl)-1-methylurea (DCPMU), 3,4-dichlorophenylurea (DCPU) and 3,4-dichloroaniline (DCA) were conducted in a farm soil and in stream sediments in coastal Queensland, Australia. RESULTS: During a 38 week period after a 1.6 kg ha(-1) diuron application, 70-100% of detected compounds were within 0-15 cm of the farm soil, and 3-10% reached the 30-45 cm depth. First-order t(1/2) degradation averaged 49+/-0.9 days for the 0-15, 0-30 and 0-45 cm soil depths. Farm runoff was collected in the first 13-50 min of episodes lasting 55-90 min. Average concentrations of diuron, DCPU and DCPMU in runoff were 93, 30 and 83-825 microg L(-1) respectively. Their total loading in all runoff was >0.6% of applied diuron. Diuron and DCPMU concentrations in stream sediments were between 3-22 and 4-31 microg kg(-1) soil respectively. The DCPMU/diuron sediment ratio was >1. CONCLUSION: Retention of diuron and its metabolites in farm topsoil indicated their negligible potential for groundwater contamination. Minimal amounts of diuron and DCMPU escaped in farm runoff. This may entail a significant loading into the wider environment at annual amounts of application. The concentrations and ratio of diuron and DCPMU in stream sediments indicated that they had prolonged residence times and potential for accumulation in sediments. The higher ecotoxicity of DCPMU compared with diuron and the combined presence of both compounds in stream sediments suggest that together they would have a greater impact on sensitive aquatic species than as currently apportioned by assessments that are based upon diuron alone.     

广州市酸雨对不同森林冠层淋溶规律的研究

１９９８年４月至１９９９年３月对广州市白云山马尾松林和常绿阔叶林、广州市龙眼洞马尾松林两试验点进行了酸雨的监测,并测定和分析了林内穿透雨物理量及化学量,旨在探讨酸雨对不同森林冠层养分淋溶规律的影响。结果表明：（１）广州市酸雨占次数的７９．７％或占降雨量的９５．１％。（２）酸雨通过林冠层后,ｐＨ值明显增加。（３）在马尾松林和常绿阔叶林中,某些单次降雨出现ＳＯ４＾２－、ＮＯ３＾－、ＮＨ４＾＋Ａｌ＾３＋、Ｎａ＾＋的负淋溶现象,说明森林对这些离子（特别是ＮＯ３＾－、Ａａ＾３＋）具有吸收作用;阔叶林全年的ＮＯ３＾－和Ａｌ＾３＋净淋溶为负值,说明阔叶林比马尾松林对这两种离子具有更强的吸收能力。（４）雨水酸度增加（即ｐＨ值减小）,明显提高阳离子Ｃａ＾２＋、Ｍｇ＾２＋、Ｋ＾＋和Ｎａ＾＋冠层淋溶面分率。（５）ＮＨ４＾＋、ＳＯ４＾     

垄作沟灌土壤水盐分布及作物产量试验研究

对垄作沟灌土壤水盐分布及作物产量进行了田间试验.结果表明,灌水定额为400 m³/hm²时,沟底土壤水分的垂直运动明显增大.当灌水定额增加100 m³/hm²时,土壤水分水平运动高于垂直运动.沟底土壤全盐量受灌水定额影响明显:在灌水阶段,沟底表层土壤发生脱盐现象.土壤蒸发阶段,土壤发生积盐现象.垄顶土壤含盐量相对稳定,基本不发生向下运移.重度水分亏缺(处理T1,灌溉定额为1 700 m³/hm²)垄、沟积盐量分别为1.49,1.35 kg/m²,中度水分亏缺(处理T2,灌溉定额为2 100 m³/hm²)垄沟积盐量分别为1.42,1.12 kg/m²,充分灌水(处理T3,灌溉定额为2 500 m³/hm²)垄、沟积盐量分别为1.32,0.83 kg/m²,畦灌措施使0~100 cm土壤发生脱盐现象,脱盐量为1.29 kg/m².垄作沟灌下,制种玉米产量为2 765.1~4 619.5 kg/hm²,WUE为0.755~0.969 kg/m³.穗长(L_s)、穗粗(d_s)、行粒数(N_R)与作物产量呈显著正相关关系.     

Control of nitrate leaching from a Nitrate Vulnerable Zone using paper mill waste

Abstract. The effects on nitrate leaching of incorporation of paper mill waste at three cultivation depths in fields previously cropped to iceberg lettuce and calabrese are reported. In the lettuce experiment, incorporation of 40 t DM paper mill waste/ha resulted in a decrease in N leaching (measured with suction cups) from 177 to 94 kg/ha (S.E._d= 23). Deep ploughing with and without paper waste increased N leaching from 105 kg/ha (normal ploughing or surface incorporation) to 172 kg/ha (S. E. _d= 27). Measurements of nitrate leaching using deep soil cores showed a less clear cut effect. Nitrous oxide (N₂O) emissions were very high immediately after paper waste was ploughed in to a depth of 35 cm. Non–significant increases in biomass N content were measured in the spring following paper waste application. There was no significant reduction in plant N uptake in subsequent crops. Removal of above–ground crop residues did not have a significant effect on nitrate leaching or N₂O losses. In the calabrese experiment, application of 40 t DM paper mill waste/ha followed by summer cropping with iceberg lettuce caused a decrease in N leaching (measured using deep soil cores) from 227 to 152 kg/ha (S. E._d= 22, mean of all cultivation treatments).