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101.
《Communications in Soil Science and Plant Analysis》2012,43(15-16):2033-2045
Abstract Soils under the main mangrove (Rhizophora racemosa and Avicennia germinans) forest in the Niger Delta, Nigeria, were characterized, and their capacities to retain heavy metals were examined by using soil column leaching experiments, using 20 mg L?1 Cu, 50 mg L?1 Zn, 20 mg L?1 Cd, and 100 mg L?1 Mn solutions. At the end of the leaching experiments, soil samples from each column were divided into two layers (0–5 cm and 5–10 cm) and analyzed for total metal retained. The fractionation of heavy metals in the surface soil samples (0–5 cm) was investigated by the sequential extraction technique. The study showed that the soils were influenced by tidal flow and characterized by the presence of very fine textured, thin (0–5 cm) to moderately thick (10–15 cm) layer of alluvium (mud) on the surface. The fibric soil material beneath the surface mud varies in thickness from about 70 to 100 cm, and beyond the histic layer is the plastic, very sticky, massive clay. In situ, the soils were neutral in reaction (pH 7.0–7.2), but became strongly acid (pH 3.3–4.8) upon drying. They are saline, high in soluble salts, highly reduced, with CEC that is low in the fibric layer, but high in the mineral, clayey subsoil horizon. The soils are saturated with water for much more than 30 days in a year and have fiber content that is more than 40 cm thick, with the fibric sphagnum constituting more than three‐fourths by volume to a depth greater than 90 cm. The soils, classified as Typic Sphagnofibrists, sequestered considerable amounts of copper (Cu), zinc (Zn), cadmium (Cd), and manganese (Mn) with most of the metals retained in the surface soils. The anthropogenic heavy metals were mostly adsorbed probably to the negatively charged sites of organics and clay. These loosely bound metals may be desorbed and reenter the aqueous phase, thus becoming a secondary source of metal pollution. 相似文献
102.
Abstract In a lysimeter study it was found that moderate rates of ammonium nitrate increased utilization percentages in spring wheat, and the leaching was 10% or less of added N. Over-optimal rates reduced utilization percentages and increased leaching to almost 50% of the highest doses. Late split application of calcium nitrate increased the percentage of N in grain. Furthermore, leaching of N was not reduced, but occurred somewhat later in the fall and winter seasons. Leaching of Cl? was more rapid and that of SO4 2- was delayed relative to the leaching of NO3 ?. Rather large negative N balances were obtained, also after over-optimal application rates, and total N content of the soil was reduced. Compared with the N0 treatment, differences in soil N residues amounted to 15–25% of added N in seven years. Gaseous losses had apparently taken place both from the added N and from soil N according to the total-N analysis. 相似文献
103.
C. R. Rahn G. D. Bending R. D. Lillywhite & M. K. Turner 《Soil Use and Management》2009,25(2):113-123
Return of high nitrogen (N) content crop residues to soil, particularly in autumn, can result in environmental pollution resulting from gaseous and leaching losses of N. The EU Landfill Directive will require significant reductions in the amounts of biodegradable materials going to landfill. A field experiment was set up to examine the potential of using biodegradable waste materials to manipulate losses of N from high N crop residues in the soil. Leafy residues of sugar beet were co‐incorporated into soil with materials of varying C:N ratios, including molasses, compactor waste, paper waste, green waste compost and cereal straw. The amendment materials were each incorporated to provide approximately 3.7 t C per hectare. The most effective material for reducing nitrous oxide (N2O) production and leaching loss of NO3? was compactor waste, which is the final product from the recycling of cardboard. Adding molasses increased N2O and NO3? leaching losses. Six months following incorporation of residues, the double rate application of compactor waste decreased soil mineral N by 36 kg N per hectare, and the molasses increased soil mineral N by 47 kg N per hectare. Compactor waste reduced spring barley grain yield by 73% in the first of years following incorporation, with smaller losses at the second harvest. At the first harvest, molasses and paper waste increased yields of spring barley by 20 and 10% compared with sugar beet residues alone, and the enhanced yield persisted to the second harvest. The amounts of soil mineral N in the spring and subsequent yields of a first cereal crop were significantly correlated to the lignin and cellulose contents of the amendment materials. Yield was reduced by 0.3–0.4 t/ha for every 100 mg/g increase in cellulose or lignin content. In a second year, cereal yield was still reduced and related to the cellulose content of the amendment materials but with one quarter of the effect. Additional fertilizer applied to this second crop did not relieve this effect. Although amendment materials were promising as tools to reduce N losses, further work is needed to reduce the negative effects on subsequent crops which was not removed by applying 60 kg/ha of fertilizer N. 相似文献
104.
Organoclays were assayed as matrices in which to associate herbicides, with the aim of decreasing product losses that could give rise to water contamination from agricultural activities. Fenuron was selected as model of a very mobile and highly water-soluble herbicide. Two different organoclays of high (A-HDT) and low (H-C18) reversible fenuron sorption were selected. Herbicide-organoclay complexes were prepared from the two organoclays and with two different fenuron contents (20 and 40 g AI kg-1) and two different mixing times, so as to form a series of weak and strong complexes. The release of fenuron from those complexes into water and water/soil suspensions gave values of T50 (time to release 50% of the fenuron content) ranging from 0.3 min to 2400 h. The total fenuron released in these closed systems ranged from 48 to 80% of the fenuron in the complex. The organoclay type (high or low sorptivity) had the greatest influence on fenuron release, followed by the strong or weak complex, suggesting that herbicide-organoclay interactions are the main factors controlling release. Soil column leaching experiments showed fenuron-organoclay complexes to be effective in reducing the peak herbicide concentration in the leachate to a half (6 microns) or a quarter (3 microns) of that obtained from the free technical compound (12 microns). Herbicide lost through leaching was reduced from 78% for the free technical fenuron to 50-30%, depending on the organoclay used as carrier and the strength of the complex. Bioassay with ryegrass showed that the weak fenuron/H-C18 complex (40 g AI kg-1) gave the same herbicidal activity as technical fenuron. The potential suitability of low-sorptive organoclays for conferring slow-release properties on the fenuron complex has been demonstrated. 相似文献
105.
Sensitivity analyses using a one-at-a-time approach were carried out for leaching models which have been widely used for pesticide registration in Europe (PELMO, PRZM, PESTLA and MACRO). Four scenarios were considered for simulation of the leaching of two theoretical pesticides in a sandy loam and a clay loam soil, each with a broad distribution across Europe. Input parameters were varied within bounds reflecting their uncertainty and the influence of these variations on model predictions was investigated for accumulated percolation at 1-m depth and pesticide loading in leachate. Predictions for the base-case scenarios differed between chromatographic models and the preferential flow model MACRO for which large but transient pesticide losses were predicted in the clay loam. Volumes of percolated water predicted by the four models were affected by a small number of input parameters and to a small extent only, suggesting that meteorological variables will be the main drivers of water balance predictions. In contrast to percolation, predictions for pesticide loss were found to be sensitive to a large number of input parameters and to a much greater extent. Parameters which had the largest influence on the prediction of pesticide loss were generally those related to chemical sorption (Freundlich exponent nf and distribution coefficient Kf) and degradation (either degradation rates or DT50, QTEN value). Nevertheless, a significant influence of soil properties (field capacity, bulk density or parameters defining the boundary between flow domains in MACRO) was also noted in at least one scenario for all models. Large sensitivities were reported for all models, especially PELMO and PRZM, and sensitivity was greater where only limited leaching was simulated. Uncertainty should be addressed in risk assessment procedures for crop-protection products. 相似文献
106.
为明确Aquacrop模型在北疆棉田膜下滴灌和地下滴灌方式下生长和生产模拟的适用性,并探究棉田生育期最优灌溉洗盐制度,该研究以2020和2021年的田间试验数据对模型参数进行校正和验证,并用校正好的模型揭示3种灌溉水平(100%ETc、80%ETc、60%ETc,其中ETc为作物需水量)、3种淋洗总定额(0、120和240 mm)、3种灌水频率(5、7和10 d/次)和3种降水年型(湿润年、平水年、干旱年)对棉花产量和灌溉水生产力的影响。结果表明,2021年所有处理的冠层覆盖度、地上生物量归一化均方根误差(normalized root mean square error, NRMSE)不大于20.998%,一致性指数d≥0.967,决定系数R2≥0.914,产量均方根误差(root mean square error, RMSE)、NRMSE、d和R2分别为0.389 t/hm2、6.797%、0.836和0.754,模型整体模拟效果良好。基于58 a气象数据的模型模拟表明:灌溉水平、淋洗定额、降水年型对棉花产量和灌溉水生产力的影响显著,灌水频率的影响不显著;在平均土壤含盐量范围为12~18 g/kg的植棉区域,综合考虑产量、灌溉水生产力及实际生产情况,湿润年推荐80%ETc+120 mm的灌溉淋洗总定额,平水年和干旱年推荐100%ETc+120 mm的灌溉淋洗总定额;推荐延长灌水频率至10 d/次以减少灌水次数,节约成本。研究可以为Aquacrop模型在棉田中的应用积累经验,为农业水资源高效利用提供理论指导与技术支撑。 相似文献
107.
Abstract. The effect of drought between summer 1995 and 1997 on stream and river nitrate concentrations was investigated using sites close to the long-running meteorological station in Oxford, UK. Nitrate concentrations in the River Windrush were relatively low during the drought, but after it had ended reached the highest level since records began in 1973. The low concentrations during the drought probably reflect a reduced contribution from agricultural runoff. High nitrate concentrations were found in a field drain at Wytham Environmental Change Network site during and after the drought, but discharge was greatly reduced. A woodland stream at Wytham had much lower nitrate concentrations than the field drain but these similarly increased during and after the drought. There was evidence that both a concentrating effect of low water volumes and enhanced soil nitrogen mineralization and nitrification rates were causing concentrations to rise. The effects of mineralization and nitrification were more important in woodland than agricultural land. Nitrate load over the course of a year was determined largely by discharge, but steeper gradients for the relationship between cumulative load and cumulative discharge were seen during and after the drought than before, reflecting the higher concentrations. 相似文献
108.
林地是森林资源的重要组成部分,如何有效地对林地进行管理,对于实现胡锦涛总书记提出的到2020年我国森林面积和蓄积量比2005年分别增加4 000万hm2和13亿m3的林业双增目标具有重要意义。而林地定额管理是林地管理的一个重要组成部分。目前的林地定额管理主要依靠各省人工逐笔核算和月末上报的方式,不仅存在一定的时滞性,而且还可能出现超额使用林地定额情况。针对以上弊端,深入分析和研究林地定额的细分规则,提出一种基于面向服务的体系结构(SOA)架构的林地定额管理系统。不仅解决了时滞性,实现对林地定额的实时管理与监控,而且还能灵活地解决林地定额管理中出现的一些特殊情况。 相似文献
109.
选取三峡库区万州段具有代表性母岩和土壤作为研究样点,测定了土壤和母岩中Si、Al、Fe、K、Mg、Ca、Na等几种风化成土元素的含量,探讨了土壤元素分布特征及其发生学意义。研究表明:母岩元素平均含量顺序为:Si>Al>Fe>K>Mg>Ca>Na,其中Fe、Ca、Mg、Na、K高于中国和世界元素背景值,而Al介于中国和世界元素背景值之间,Si的平均含量则低于背景值;灰岩区上的土壤中,Ca、Mg、K元素最高,砂岩母质区的土壤风化素含量较低;而碎屑岩类中,泥岩区土壤风化元素相对较高,粉砂岩区土壤风化元素含量介于泥岩与砂岩区之间;母岩的淋失强度为Ca>Mg>Al>Si>K>Fe>Na,Na元素的迁移程度小,是由于母岩中Na元素对土壤的不断补充。因此以土壤中风化元素含量为基础计算的风化指标,难以反映亚热带温暖潮湿地区的成土风化过程,常用的土壤分子硅铝率和硅铁铝率也不能指示所有土壤的风化成土作用程度,只适用于判断风化初期或成土作用早期。 相似文献
110.
《Communications in Soil Science and Plant Analysis》2012,43(17-18):2673-2687
Mandated processing of waste by‐products in the United States has inspired national interest in addressing the effectiveness of using composted biosolids and yard trimmings to grow containerized plants. Diamond bay Chinese evergreen (Aglaonema ‘Diamond Bay’) was transplanted in containers filled with one of eight formulated media (components added by volume). Medium 1 was a standard mix commonly used in Aglaonema production (5:2:3 peat–vermiculite–perlite); medium 2 was formulated on site to contain peat–bark–stalite–rice hulls–coir (2:2:3:1:2); media 3 and 4 contained 40% biosolid–yard waste compost instead of peat and with or without 20% stalite, respectively; and media 5, 6, 7, and 8 were commercially formulated to contain peat–bark–perlite–rice hulls–coir (4:1.5:2.5:1:1, 4:1.5:2.5:1:1, 4:2:2:1:1, and 3.0:2.5:2:1:1.5, respectively). Physical and chemical properties of the eight media were in ranges 50–65% container water‐holding capacity, 2.9–7.8% air‐filled porosity, 55–80% moisture (w/w), 0.11–0.37 g·cm3 bulk density, 0.34–0.96 g·cm3 particle density, 4.2–7.2 pH, 0.12–4.4 dS·m?1 electrical conductivity (EC), 27.3–54.5 meg/100 g cation exchange capacity (CEC), 17.9–39.0% carbon (C), and 0.22–1.7% nitrogen (N). Medium 4 (40% compost) had 5.5 times more ammoniacal N (NH4‐N) and 1.7 times more nitrate N (NO3‐N) than that of the standard commercial mix. At week 8, plants grown in media 2 and 5 were 8.9% to 9.5% taller than plants grown in medium 1 (commercial standard). At week 16, there were no significant differences in plant heights or growth indices among media. At week 24, there were no significant differences in plant height, growth index, visual quality, shoot dry weight, and root dry weight among media. However, cumulative phosphorus (P) leaching from media 1, 4, and 5 was significantly more than leaching from media 2 and 8. This study suggests that compost may serve as a horticulturally suitable and cost‐effective alternative to peat‐based media for Aglaonema production. 相似文献