土层性质对铜和铅在土壤中保持和迁移的影响

The mobility and bioavailability of heavy metals in soils is largely governed by sorption and desorption phenomena.Cu2+ and Pb2+ are among the most potentially toxic heavy metals and they are present,often concomitantly,in many polluting spills and in agrochemicals.The objective was to assess and compare the competitive sorption and desorption capacities and sorption hysteresis of Cu2+ and Pb2+,as well as their migration through the profiles of four natural soils:a Humic Umbrisol,an Umbric Cambisol,an Endoleptic Luvisol and a Humic Cambisol.In all horizons Pb2+ was invariably sorbed and retained to a greater extent than Cu2+.The sorption and retention of Cu2+ were most in?uenced by pH,e?ective cation exchange capacity(CECe) and Mn oxide content.On the other hand,the fixation capacity of Pb2+ was most in?uenced by pH,CECe,and Mn oxide and organic matter contents.pH and CECe were the individual soil properties most markedly in?uencing Cu2+ and Pb2+ sorption and retention.In all the horizons Pb2+ exhibited greater hysteresis than Cu2+.In each soil the hysteresis in the A horizon was greater than that in the B horizon,except in the Bt horizon of the Endoleptic Luvisol,due to its high pH and vermiculite content.Based on migration indices,Pb2+ was less mobile than Cu2+ in the studied soils.     

Behavior of phenolic substances in the decaying process of plants

The changes in amount of ether-extractable phenolic substances, individual phenolic adds, organic matter content, and pH value in the decaying process of rice straw were compared at 10, 30, and 50°C under moist and flooded conditions for 70 days.

1) The changes in pH value with time varied markedly according to temperature and water conditions.

2) Phenolic substances in the ether-extractable fraction obtained from the acidified solution of alkaline methanol extract contained undetected phenolic compounds in amounts larger than the phenolic adds detected by gas chromatography. pH value during incubation was hardly attributable to these phenolic substances because of their small quantity.

3) The changes in amount of the ether-extractable phenolic substances with time was mainly due to phenolic compounds other than phenolic acids, and influenced largely by the temperature and water conditions. Their formation and degradation took place rapidly at high temperatures under flooded conditions.

4) From the plots of individual phenolic acids vs. time, it was tentatively concluded that phenolic acids contalned in non-decayed straw were rapidly degraded in the earlier stage, and some of them were newly produced from ether-unextractable precursors in the later stage. These reactions occurred rapidly at high temperatures, especially under flooded conditions.

5) The content of p-hydroxybenzolc acid increased simultaneously with a rapid decrease in p-coumaric acid during the incubation ot straw. The relationship between vanillic acid and ferulic acid was the same.     

氯胺嘧草醚在土壤中的吸附行为研究

为评价氯胺嘧草醚的环境安全性,采用批量平衡法测定了氯胺嘧草醚在5种土壤中的吸附-解吸行为,并运用数学模型对其吸附-解吸特性及移动性能进行了分析。结果表明:氯胺嘧草醚在5种土壤中的等温吸附-解吸曲线符合Freundlich模型,吸附常数（Kf值）范围在6.991~18.49之间;不同土壤对其的吸附作用强弱依次为:黑土 > 水稻土 > 褐土 > 潮土 > 红土。氯胺嘧草醚在5种土壤中的有机碳吸附常数（KOC）范围在704.4~1 579之间,推测其在土壤中具有低移动性;薄层层析试验也表明,氯胺嘧草醚在土壤中的移动性较弱。氯胺嘧草醚在5种土壤中的吸附自由能绝对值均小于40 kJ/mol,表明其吸附机理主要是物理吸附。其Kf值与土壤有机质含量、黏粒含量呈正相关,而与土壤pH值呈负相关。解吸试验表明,氯胺醚在其中3种土壤中的解吸过程存在滞后现象。研究表明,在正常使用情况下,氯胺嘧草醚不易对地表水或地下水造成污染风险。     

金线鱼鱼皮抗冻蛋白酶法制备工艺优化

为了探讨金线鱼鱼皮抗冻蛋白的酶法高效制备工艺,该文首先探究不同蛋白酶酶解获得的酶解产物的热滞活性(thermal hysteresis activity,THA)以及不同分子区间的酶解产物的热滞活性。随后以抗冻蛋白得率为指标优化了底物与酶的比例、酶解时间、酶解温度以及p H值,并采用响应面法探究抗冻蛋白的最佳酶解工艺。最后使用差示扫描量热仪(differential scanning calorimeter,DSC)测定验证抗冻蛋白的热滞活性。结果表明:在碱性蛋白酶、中性蛋白酶、木瓜蛋白酶以及复合蛋白酶4种酶的最佳酶解条件下,碱性蛋白酶酶解所获得抗冻蛋白热滞活性最大,选择碱性蛋白酶作为制备金线鱼鱼皮抗冻蛋白的最佳蛋白酶;截留分子量为≥5~10 k Da鱼皮蛋白的抗冻效果最佳,热滞活性达1.20?0.07℃,确定≥5~10 k Da鱼皮蛋白得率作为酶解制备工艺的指标;得到金线鱼鱼皮抗冻蛋白最佳的酶解制备工艺条件为:底物与酶比例为32∶1、酶解时间为147 min、酶解温度为50℃和p H值为9,在此条件下,金线鱼鱼皮抗冻蛋白得率为49.25%±1.34%。相比于牛血清蛋白(bovine serum albumin,BSA),其降低了溶液起始结晶的温度;在最佳的保留温度条件下,其热滞活性为1.2℃。碱性蛋白酶酶解制备鱼皮抗冻蛋白是一种快速有效的方式,酶解获得的抗冻蛋白热滞活性高。该结果为综合发展和利用金线鱼鱼皮提供一定的理论依据。     

观光温室结构楔形箱型矩管柱梁连接节点抗震性能

为了满足温室结构的建设需要,提出了一种楔形箱型矩管柱与H形钢梁连接节点构造型式,并对该种节点的抗震性能进行研究。利用ANSYS对该节点进行了往复荷载作用下的有限元模拟分析,讨论了钢梁翼缘、腹板厚度及矩管柱壁厚对钢节点抗震性能的影响。结果表明,楔形箱型节点在往复荷载作用下梁端塑性铰位置向跨中偏移,保证了"强柱弱梁、强节点弱构件"设计理念的实现。累积耗能比传统的外联板式节点高出25.40%,比内隔板式节点减少20.46%,滞回曲线相对饱满,体现了良好的抗震性能。同时,梁翼缘和腹板的厚度及楔形箱形截面宽度变化率对于节点的抗震性能有较大的影响,建议实际工程中截面宽度变化率取1:4。计算结果表明该节点具有良好的抗震性能。     

Comparison of the Suspended Sediment Dynamics in Two Loess Plateau Catchments,China

Changes in runoff and sediment loads are of great importance for the management of river basins and the implementation of soil and water conservation measures. This study compared the suspended sediment dynamics in the Huangfuchuan and Yanhe catchments on the Loess Plateau. Both annual runoff and sediment load displayed significant reductions from 1955 to 2012. The decreasing rates were −0·88 mm a⁻¹ and −2·72 Mg ha⁻¹ a⁻¹ in the Huangfuchuan catchment, respectively, and ‐0.31 mm a⁻¹ and −1·20 Mg ha⁻¹ a⁻¹ in the Yanhe catchment. A total of 183 and 195 events, respectively, were selected to assess the suspended sediment dynamics in both catchments during the periods of 1971–1989 and 2006–2012. The results showed a good linear relationship between the sediment yield and runoff depth in both catchments from 1971 to 1989 and a relatively worse relationship in the Yanhe catchment from 2006 to 2012. The magnitude and frequency of the hyper‐concentrated sediment flow obviously decreased in the 2000s compared with that between 1971 and 1989. A hysteresis analysis suggested that complex and counter‐clockwise loops were the dominant patterns. Various soil and water conservation measures (e.g., afforestation, grassing, terraces, and check dams) played a critical role in runoff and sediment load changes in both catchments. The two catchments showed obvious heterogeneities in runoff and sediment yield because of different lithologies, soil types, and vegetation. The results of this study provide valuable information on suspended sediment dynamics and could be used to improve soil erosion control measures on the Loess Plateau. Copyright © 2016 John Wiley & Sons, Ltd.     

Experimental Analysis on the Deformation of Sandstone underPore Pressure and Constant Time

In order to discuss the deformation characteristics of rock mass under different water levels changing between 145 and 175 meter in the Three Gorges reservoir area, an experiment was carried out for the studying sandstone deformation under the conditions of three different axial stresses(σ1=55.54,34.18,12.82 MPa), two cyclic pore pressures(Pmin=2 MPa,Pmax=6 MPa) and two kinds of constant time(the upper limit time and the lower limit time(ΔT=120,240 s).With ε1-T curves and p-T curves, as well as p-ε1  hysteresis curves, it was found that the curves were continuous sine wave-shaped curves.At first, the strain decreased with loading pore pressure.And then, it decreased to valley value with pore pressure at stable upper limit.Next, it increased with unloading pore pressure and increased to peak value with pore pressure at stable lower limit.The p-ε1  hysteresis curves of the sandstone had two typical stages.And one was caused by the closure of some primary pores and crack under increasing compaction, in which the strain did not form obviously hysteresis curves, and the other was pore pressure coupling stage which showed obvious hysteresis curve in form of the anti-clockwise from the dispersed to the dense.In addition, Δε-n curves in four sections (loading, unloading, steady upper limit, steady lower limit) of p-ε1 curves were compared and respectively ananlyzed in the condition of various axial stress and different constant time .     

抗冻蛋白提高植物抗寒性研究进展

低温是影响植物生长发育及地域分布的主要生态因子,提高冷敏感植物的抗寒性具有重要的理论和现实意义。对抗冻蛋白基因的研究表明,将这些基因转入冷敏感植物可以明显提高植物抗寒性。本文就近几年关于抗冻蛋白作用机理进行了总结,并综述了抗冻蛋白基因提高植物抗寒性的研究进展,这为植物抗寒性分子育种提供了理论依据和新的技术思路。     

考虑附加涡流损失的Galfenol合金动态滞后建模与实验

在Galfenol合金能量平均静态滞后模型基础上,考虑铁磁材料在动态磁场作用下的涡流损耗和附加损耗,建立了Galfenol合金动态滞后磁化强度模型和应变模型。利用Galfenol合金磁特性测试系统进行了应变和磁场静态特性测试,测试结果与模型计算结果吻合较好。利用该测试系统测试了〈100〉取向多晶Fe83Ga17合金在动态磁场频率分别为1、10、20、40、60、100、200、300 Hz作用下的应变和磁场的关系。实验结果和模型计算结果对比表明,在磁场频率为200 Hz以下时,模型能准确反映应变与磁场的关系,频率为200 Hz以上时,计算结果与实验结果出现偏差。该模型能用于Galfenol合金的器件设计与应用。