牡丹江山区地形逆温对污染物扩散的影响

利用牡丹江2006~2007年较详细每日环保大气监测资料以及探空资料,来分析牡丹江山区出现逆温的属性特征,重点分析并对逆温的生消规律、大气污染物的日变化及出现逆温和没有逆温情况下的浓度变化规律进行研究,来分析逆温对大气主要污染物扩散的影响。结果表明,牡丹江出现逆温主要以地形辐射逆温为主,逆温在08：00和20：00有逆温强度中心峰值,并对大气污染物浓度产生较大影响。当出现逆温时,在05：00～08：00、20：00～23：00时间段,污染物浓度增大,其他时间段浓度较小或变化不十分明显：没有逆温时,大气处于不稳定层结状态,有利于污染物扩散,浓度较小。     

大辽河河口地区污染边界层特征试验研究

利用2007年1～2月份大辽河河口地区沿海和陆地2个地面观测点观测得到的污染边界层的气象资料,探讨了该地区冬季污染边界层日变化特征。结果表明,大辽河河口地区污染边界层受到海陆的影响,在一定的天气条件下,海岸区域200m以下的低空可能出现海陆风。海岸区域不同高度的稳定度变化较陆地区域稳定;该地区风场变化主要在300m左右低空。夜间地区常出现逆温,逆温层厚度稳定在200～300m。热内边界层深入陆地10km,且高度可达800m。海岸区域大气扩散能力较弱,陆地区域较强。     

基质固相分散-离子色谱法测定卷烟样品中的糖和多元醇

[目的]研究用基质固相分散法提取净化,离子色谱法测定卷烟中的糖和多元醇。[方法]将样品与石墨化碳黑球（w／w,1：4）充分研磨后装柱,用热水洗脱,洗脱液中的糖用离子色谱测定。以CarboPacMAl（4×250mm,5μm）阴离子交换柱为固定相,0．5mol／LNaOH溶液为流动相分离,脉冲安培检测器检测。[结果]一次进样可实现卷烟样品中甘油、丙二醇、木糖醇、山梨醇、葡萄糖、果糖、蔗糖、麦芽糖和半乳糖9种成分的同时测定。方法加标回收率在94．6％～105．7％,相对标准偏差小于3．0％,检测限均小于50μg/L.[结论]该方法重现性好,准确可靠,回收率较好,可用于实际烟草样品中糖和多元醇的测定。     

具有功能反应的时滞扩散食饵-捕食者数学模型

研究了具有HollingⅡ类型功能反应的一捕食者有两种食饵的时滞扩散系统,得到了与时滞有关的系统永久持续生存的充分条件,通过构造Lyapunov函数得到了与时滞有关的系统全局渐近稳定的充分条件.     

Clay dispersion and its relation to surface charge in a paddy soil of the Red River Delta,Vietnam

Dispersion is an important issue for clay leaching in soils. In paddy soils of the Red River Delta (RRD), flooding with fresh water and relatively high leaching rates can accelerate dispersion and the translocation of clay. For the clay fraction of the puddled horizon of a typical paddy soil of the RRD, the effect of various cations and anions as well as humic acid (HA) at different pH values on the surface charge (SC) were quantified and the dispersion properties were determined in test tubes and described by the C₅₀ value. In the <2 µm fraction, dominated by illite, the proportion of 2:1 vs. 1:1 clay minerals is 5:1. The organic‐C content of the clay fraction is 2.2%. Surface charge was found to be highly pH‐dependent. At pH 8 values of –32 and at pH 1 of –8 mmol_c kg^–1 were obtained. Complete dispersion was observed at pH > 4, where SC is > –18 mmol_c kg^–1. The flocculation efficiency of Ca strongly depends on the pH. At pH 4, the C₅₀ value is 0.33, 0.66 at pH 5, and 0.90 mmol L^–1 at pH 6. At pH 6, close to realistic conditions of paddy soils, the effect of divalent cations on the SC and flocculation decreases in the order: Pb > Cu > Cd > Fe^II > Zn > Ca > Mn^II > Mg; Fe^II was found to have a slightly stronger effect on flocculation than Ca. An increase in concentrations of Ca, Mn^II, and Mg from 0 to 1 mmol L^–1 resulted in a change in SC from –25 to approx. –15 mmol_c kg^–1. In comparison, the divalent heavy‐metal cations Pb, Cu, Cd, and Zn were found to neutralize the SC more effectively. At a Pb concentration of 1 mmol L^–1, the SC is –2 mmol_c kg^–1. From pH 3 to 5, the dispersion of the clay fraction is facilitated rather by SO than by Cl^–, which can be explained by the higher affinity of SO to the positively charged sites. With an increase of the amount of HA added, the SC continuously shifts to more negative values, and higher concentrations of cations are needed for flocculation. At pH 3, where flocculation is usually observed, the presence of HA at a concentration of 40 mg L^–1 resulted in a dispersion of the clay fraction. While high anion concentrations and the presence of HA counteract flocculation by making the SC more negative, Fe^II and Ca (C₅₀ at pH 6 = 0.8 and 0.9 mmol L^–1, respectively) are the main factors for the flocculation of the clay fraction. For Fe^II and Ca, the most common cations in soil solution, the C₅₀ values were found to be relatively close together at pH 4, 5, and 6, respectively. Depending on the specific mineralogical composition of the clay fraction, SC is a suitable measure for the determination of dispersion properties and for the development of methods to keep clay particles in the soil in the flocculated state.     

Soil Water Retention at Varying Matric Potentials following Repeated Wetting with Modestly Saline‐Sodic Water and Subsequent Air Drying

Abstract

Coal bed natural gas (CBNG) development in the Powder River (PR) Basin produces modestly saline, highly sodic wastewater. This study assessed impacts of wetting four textural groups [0–11%, 12–22%, 23–33%, and >33% clay [(g clay/100 g soil)×100%)] with simulated PR or CBNG water on water retention. Soils received the following treatments with each water quality: a single wetting event, five wetting and drying events, or five wetting and drying events followed by leaching with salt‐free water. Treated samples were then resaturated with the final treatment water and equilibrated to ?10, ?33, ?100, ?500, or ?1,500 kPa. At all potentials, soil water retention increased significantly with increasing clay content. Drought‐prone soils lost water‐holding capacity between saturation and field capacity with repeated wetting and drying, whereas finer textured soils withstood this treatment better and had increased water‐retention capacity at lower matric potentials.     

Dynamics of calcium‐sodium exchange under unsaturated plow conditions

Abstract

An experiment was conducted in soil columns of 84 cm length and 5.7 cm inner diameter to determine the effect of degree of water saturation on the extent of replacement of sodium by calcium from the exchange sites. The experiment was performed by running 0.20 N calcium chloride solution through a saline‐sodic soil into a water table at the lower end at different rates less than the infiltration rate of the soil, thus obtaining unsaturated flow conditions. The effective or the apparent calcium exchange capacity of the soil was reduced significantly and nearly proportionally with a decrease in the degree of water saturation during the flow process. It is suggested that part of exchange sites become inaccessible during the unsaturated flow and that there must be some isolated locations away from the main water stream in which mixing or molecular exchange by diffusion is negligible.     

元谋干热河谷坡面表层土壤力学特性对其抗冲性的影响

为了研究元谋干热河谷区坡面表层土壤的抗侵蚀性能,通过对燥红土机械组成、团聚体组成、基质吸力、黏聚力c和内摩擦角φ等参数的分析,并用原状土进行冲刷试验测定土壤的抗冲指数ANS,探讨了这些参数对土壤抗冲性的影响。结果表明,土壤分散率和ANS(soilanti-scourability)呈一元三次多项式变化,随着分散率的逐渐增加,ANS逐渐下降,ANS随着平均重量直径MWD的增大呈幂函数增长,随着基质吸力、黏聚力c和内摩擦角φ的逐渐增加,ANS也呈对数函数增长;ANS与各力学参数的相关程度依次为:抗剪强度τf>φ>MWD>分散率>基质吸力>c,逐步回归表明,黏聚力c、平均重量直径MWD和抗剪强度τf与ANS呈较好的线性关系(R2复=0.983),偏相关系数(RMWD(0.915)>Rc(0.829)>Rτf(0.776))表明水稳性团聚体的稳定性、颗粒及团聚体之间的胶结凝聚力和土壤抵抗水流的剪切破坏力对ANS影响较大。     

牛舍冷风机-风管上置置换通风系统设计及降温效果

为了探索一种高效且运行成本低的牛舍降温方式,该试验通过设计合理的风管布置和开口,采取上置置换通风的模式对肉牛舍降温。该设计方案用计算流体力学(computational fluid dynamics,CFD)的方法验证其可行性,并通过实际测试设定风机开启和关闭的适宜时间,试验表明:处理舍系统产生的冷风大量流向牛活动区域,温湿度梯度比对照舍明显,达到了局部降温的节能目的。该系统开启后,10:00-18:00期间,处理舍牛的平均热负荷指数(heat load index,HLI)比对照舍降低7.4(P0.01),平均呼吸频率降低12次/min(P0.01),平均日增质量提高0.37 kg/d(P0.01),缓解了肉牛的热应激,提高了肉牛的养殖效益。处理舍由于相对封闭,故牛活动区域平均相对湿度、CO2和NH3浓度分别比对照舍高26.8%、252 mg/m3、0.54 mg/m3(P0.01),但牛舍环境空气质量符合相关行业标准的要求。该试验为冷风机-风管通风降温系统设计提供了一些参考参数,有利于该系统的优化,并发挥更好的降温效果。     

Methodological aspects of determining soil particle‐size distribution using the laser diffraction method

This paper presents the influence of selected methodological aspects on the results of particle‐size distribution (PSD) as measured by the laser diffraction method (LDM). The investigations were carried out using the Mastersizer 2000 with Hydro MU attachment (Malvern Ltd., UK). It was found that for the investigated soils: (1) optimal speed of pump and stirrer was 2500 rpm, (2) optimal measurement time was ≈ 1 min, (3) there are two, practically equivalent methods for soil‐sample dispersion: chemical (with the use of a solution of sodium hexametaphosphate) or physical (by means of ultrasound application for 4 min at a maximum power of 35W), (4) one must not use the chemical and physical dispersing methods simultaneously, because this can lead to aggregation (not dispersion) of soil particles, (5) the Fraunhofer theory (physical models) can be used to convert scattered‐light data to PSD. In the case of the Mie theory, the best results were obtained for a refractive index (RI) in the range of 1.5–1.6 and an absorption index (AI) of 1.0. It was also found that most of the discussed parameters depend on design of the measuring device and on the type and volume of the investigated suspensions. It is necessary, therefore, to explain how the data was obtained every time and to specify the details in the methodological part of the paper.