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十二烷基硫酸钠对大豆基木材胶黏剂的改性作用 总被引:3,自引:0,他引:3
采用10.0g·kg^-1的十二烷基硫酸钠(SDS)改性质量分数为250.0g·kg^-1的大豆粉浆液,制成SDS改性大豆基木材胶黏剂(SF),运用单因素和正交试验法考察了pH值、反应温度和反应时间对改性SF胶耐水胶合强度的影响。试验结果表明,SDS改性大豆基木材胶黏剂的最佳工艺:pH8,反应温度35℃,反应时间4h。改性后的SF胶Ⅱ类耐水胶合强度为0.70MPa。由红外光谱分析可知,SDS改性使大豆蛋白质分子大量的非极性基团外露,增加了蛋白质分子的疏水性,提高了改性SF胶的耐水胶合强度。图4表3参10 相似文献
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LIN Lanying FU Feng Research Institute of Wood Industry Chinese Academy of Forestry Beijing China 《中国林业科技(英文版)》2007,6(3):17-25
Resonance flexural vibration(Fast Fourier Transform, FFT), ultrasonic wave(Pundit) and stress wave(Metriguard) techniques were examined as means of evaluating the static modulus of elasticity (MOE) and predicting the modulus of rupture (MOR) of finger-jointed lumber specimens made with four kinds of Eucalyptus (Eucalyptus. citriodora, E. exserta, E. grandis x E. urophylla and E. grandis). Dynamic MOE was calculated from frequency and time obtained from forced vibrations and sounds induced in the four species of finger-jointed specimens. It was found that correlation coefficients between density and static MOE and dynamic MOE were statistically significant at the 0.01 level. And it was also found that the three nondestructive techniques can provide rapid and accurate means to determine the MOE, and the dynamic MOE was more accurate to predict static MOE than density. But the correlation coefficient between dynamic MOE, static MOE and MOR were lower than results reported by other researchers for solid wood, and were not statistically significant. It can be concluded that the three nondestructive techniques are useful for evaluating the MOE, but not suitable for predicting the MOR of finger-jointed. 相似文献
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ABSTRACTCertain important quality parameters of red maple (Acer rubrum) laminated veneer lumber (LVL) impregnated with three waterborne formulations: copper azole (CA-B), micronized copper azole (MicroCA or MCA) and alkaline copper quaternary (ACQ-D) bonded with phenol formaldehyde or cross-linked polyvinyl acetate (XPVAc) adhesives were evaluated. Pre-dipping of veneers before LVL production and two post-manufacturing procedures, viz., vacuum-pressure and post-dipping of LVL, were applied. Maximum copper retention in pre-dip-treated, vacuum-pressure and post-dip-treated LVL was 1.4, 9.7 and 1.7?kg/m3, respectively. Copper retention in MCA-treated LVL was relatively lower than soluble formulations. Various physical, mechanical and bonding properties of treated LVL such as density, water absorption, swelling, flexural properties, hardness, tensile shear strength, delamination and wood failure (%) were studied and compared with untreated LVL. Little to negligible deleterious effect was observed on properties of LVL due to these chemical treatments. Analysis of variance results showed that most of properties of red maple LVL were not significantly different compared with those of untreated LVL. Therefore, vacuum-pressure impregnation process can be used to treat the red maple LVL with novel micronized copper formulations for increasing the service life of such products against biodegradation without affecting techno-mechanical quality parameters. 相似文献
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Daniel Kohl C. von Boyneburgk M. Feldmann H.-P. Heim S. Böhm 《Wood material science & engineering》2020,15(3):130-139
ABSTRACTDue to its naturally grown properties, wood has played a rather subordinate role as a material for technical applications up to now. In this paper, multi-material systems based on veneers of beech (Fagus sylvatica) with different reinforcing variants were investigated. In addition to the influence of different adhesive systems (urea formaldehyde and polyurethane), the effect of reinforcing by aramid fiber fabric and stainless steel foil in different climates was examined. At the center of the investigations were dynamically sudden loads, in the form of impact bending and dart drop tests (penetration and impact mode). It has been shown that the use of the reinforcing materials leads to a significant improvement in material properties. The penetration energy of the composites reinforced with the aramid fiber fabric could be increased by 43%. The maximum force in the dart drop test (impact mode) could be increased by 29% with the stainless steel foil, the damping decreased by 48%. The aramid fiber reinforcement achieved an increase in impact resistance by 27% in impact bending test, the steel reinforced achieved an increase of 39%. A clear dependency on both, the climate and the adhesive within the composite, could be demonstrated. 相似文献
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Philipp Schlotzhauer Alexander Ehrmann Susanne Bollmus Holger Militz 《Wood material science & engineering》2020,15(5):278-288
ABSTRACT Knowledge about perpendicular to grain tension behavior of wood is essential, since in construction tension stresses perpendicular to grain cannot be avoided completely. Especially for hardwoods, the data basis is scarce. EN 338 design values are with 0.6 N/mm² characteristic strength set very low. The US-American National Design Specifications even set this value to zero and make local reinforcements mandatory. This paper compares strength and stiffness values attained with newly-designed, little, prismatic specimens and EN 408 structural timber specimens to evaluate the current European design values. Little specimen’s characteristic strength values range from 7.2 to 10.6?N/mm² and are assumed to be real material properties. EN 408 specimen values are with approximately 4.0?N/mm² lower. These lower values are mainly due to stress peaks introduced by the force introduction. Strength values attained for the medium-dense European hardwoods beech, ash and maple exceed EN 338 design values by a factor of six to seven. Adaptation of the EN 338 design value is not recommended, though. The abundance of influencing factors makes clear that the design value and the ensuing design code have to be synchronized carefully by tedious testing in order to make use of the perpendicular to grain tension strength potential of the selected hardwoods. 相似文献
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