土壤水溶性盐基离子的高光谱反演模型及验证

土壤水溶性盐基离子是诊断土壤盐渍化类型与盐渍化程度的重要依据,利用光谱技术快速获取土壤水溶性盐基离子含量数据,可为土壤盐渍化类型与盐渍化程度的诊断提供新的技术和手段。该研究通过采集新疆5个不同地区399个土样的反射率与水溶性盐基离子数据并进行31种光谱预处理方法,分析了不同水溶性盐基离子(HCO3-、Cl-、SO42-、K+、Na+、Ca2+、Mg2+)与高光谱反射率之间的相关性;采用K-S(Kennard-Stone)方法挑选出299个样品,针对每种离子使用偏最小二乘回归(partial least squares regression,PLSR)分别建立32个高光谱定量反演模型,优选最佳反演模型,并单独使用100个样品对估测模型进行检验。结果表明:不同离子的最佳反演模型所使用的预处理方法存在差异,其中仅有Cl-和Ca2+、SO42-和Mg2+所使用的预处理方法相同,其他离子则不同;不同离子的反演精度也不同,HCO3-和Ca2+构建的模型相对分析误差(relative percent deviation,RPD)分别为2.67、2.57,模型具有很好的预测能力。Cl-、SO42-和Mg2+所构建的模型RPD分别为2.05、2.10和2.14,表明这三者建立的模型具有较好的预测能力。K+建立的模型RPD仅为1.11,不能对样品进行预测。Na+构建的模型RPD为1.83,表明该离子所建模型只能对样品进行粗略估测。研究结果为探究水溶性盐基离子的高光谱反演增添了新的内容,为土壤盐渍化监测的深入和推进提供了新的思路和方法。     

黑土坡面不同粒级泥沙流失特征分析

不同粒级泥沙流失特征研究可揭示坡面侵蚀机理,表征土壤养分流失状况;而现有研究缺少对不同粒级泥沙流失速率及流失比例的过程性研究。为此,该研究基于连续汇流冲刷试验,研究汇流冲刷次数和坡度对黑土坡面不同粒级泥沙流失特征的影响。试验处理包括6次连续汇流冲刷（1 L/min,每次历时60 min）和2个黑土区典型坡度（5°和10°）。结果表明,汇流冲刷次数对不同粒级泥沙流失速率及比例的影响较坡度的影响明显。试验条件下,<0.25 mm泥沙流失比例最大,其次为1～2、2～5、0.5～1、0.25～0.5、>5 mm泥沙流失比例。随着汇流冲刷次数的增加,<0.25 mm泥沙的平均流失速率由1 965.7～6 698.4 g/(m2·h)显著减小为59.5～80.0 g/(m2·h),该粒级泥沙流失比例亦总体呈现减小的趋势,而1～2 mm泥沙流失比例总体呈现增加的趋势,二者作为侵蚀泥沙的主体,其变化具有明显规律性。因此,<0.25 mm和1～2 mm泥沙流失特征应作为黑土区土壤侵蚀研究的重要部分,进而指导防治措施的布设;同时,建议采用适宜的覆盖措施防治黑土坡面细小颗粒泥沙的流失。     

基于指示Kriging法的土壤盐渍化与地下水埋深关系研究

在北方干旱、半干旱的地下水浅埋区,土壤盐渍化是土地资源退化的主要原因,防治土壤盐渍化是农业和生态环境可持续发展的重要保障。该文以内蒙古河套灌区解放闸灌域为例,运用指示Kriging法绘制并比较了不同阈值下地下水位埋深和土壤表层含盐量的概率分布图,从概率空间分布的角度分析研究了土壤盐渍化与地下水位埋深之间的关系,从而将这方面的研究从通常的农田尺度扩大到灌域尺度。结果表明:1)土壤盐分和地下水位埋深空间变异强度均为中等,且具有中等的空间自相关性,球状模型拟合变异函数的效果较好;2)在灌域尺度上,解放闸灌域4月底土壤表层发生中度、轻度盐渍化时地下水位临界埋深分别为2.0、2.5m,西南及中东部地下水位埋深小于临界埋深的概率较大,是土壤返盐的高风险区;3)3月底地下水位埋深对土壤返盐的影响比4月底更大一些,这表明地下水位埋深对土壤返盐的影响具有一定滞后效应,只有地下水位埋深小于临界深度的状态维持一段时间,才会造成土壤中度或轻度盐渍化。     

季节性冻融土壤盐分离子组成与冻结层盐分运移规律研究

该文对冻融过程中土壤盐分离子组成及冻结层盐分运移规律进行研究,在内蒙古河套灌区永联试验站开展了冻融期土壤水盐及其离子成分监测试验,分析了冻融期地温、冻结层深度、地下水埋深与水质、土壤含水率、土壤盐分及离子组成的变化规律,通过离子相关性分析确定了土壤盐分运移的主控离子成分和盐分类型,进一步利用二元水盐体系相图探讨了冻融期主控盐分的运移规律。结果表明:冻融期地温梯度变化主要发生在0～1.0 m范围土层中,地下水埋深在冻融期变化趋势为快速增大-缓慢增大-减少,地下水矿化度均值在融化期显著降低;研究区地下水中变异性最大的离子为Na~+、Cl~–和SO_4~(2–),土壤盐分运移和扩散是地下水矿化度变化的主要原因;土壤中Na~+、Cl~–与SO_4~(2–)与含盐量相关系数高于0.9,冻融期土壤盐分浓度变化的主控盐分类型为氯化钠和硫酸钠;冻结层积盐或者脱盐取决于土壤盐分梯度和不同盐分的共饱和点,研究区最大氯化钠浓度(质量分数1.55%)和最大硫酸钠浓度(2.01%)均低于各自的共饱和点,当冻结前土壤溶液浓度梯度为正(从上到下浓度增大)时,冻结层易积盐,反之冻结层主要表现为脱盐。研究对阐明冻融期冻结层盐分累积规律的成因具有重要意义。     

安徽省典型城市周边土壤-蔬菜中PAHs的污染特征

研究了安徽省合肥、芜湖和亳州市周边蔬菜地土壤和蔬菜中PAHs的含量及其污染特征。结果表明：安徽省典型蔬菜地土壤中15种PAHs（除萘外）的残留总量在58.2～437.8μg·kg-1之间,三环和四环PAHs占PAHs残留总量的70%以上。胡萝卜、菠菜和茄子体内15种PAHs的含量在23.4～209.1μg·kg-1之间,均值为120.7μg·kg-1,三环和四环PAHs占蔬菜中PAHs富集总量的92.8%～94.4%。不同蔬菜体内8种可疑性致癌PAHs的含量在11.5～17.4μg·kg-1之间,分别占蔬菜中PAHs残留总量的9.80%～13.8%,其中BaP含量在1.69～2.03μg·kg-1之间,低于国家对食品中污染物（BaP）的限量标准（5μg·kg-1）。不同类型PAHs在蔬菜体内的富集系数在0.10～9.20之间,极差达10倍以上,低分子量PAHs在蔬菜体内的富集系数要大于高分子量PAHs。不同PAHs在蔬菜体内的富集系数表现为胡萝卜〉菠菜〉茄子,其中芴在蔬菜体内的富集系数最高。     

The rice soils of Cambodia. II. Statistical discrimination of soil properties by the Cambodian Agronomic Soil Classification system (CASC)

Abstract. A novel agronomic system of soil classification for managing rice soils in Cambodia (CASC) was developed recently. It integrates local knowledge about the soil with its conceptual and taxonomic understanding by soil scientists. Using quantitative soil survey data we evaluated the agronomic efficacy of the classification system. Although the CASC is based on simple field criteria it explained 25 to 44% of the variation in soil prop-erties relevant for agronomic decision making. It failed, however, to differentiate soil types based on pH (6% of variances explained). Despite its simplicity it performed as well or better than the most widely used soil map in Cambodia (Crocker, 1962), and unlike this small-scale soil map it allows classification on a field-specific basis. The average values of soil properties were often significantly different between groups. Organic carbon, clay content and plant available magnesium and calcium contributed most to the discrimination of CASC soil groups. The predictive accuracy when allocating new samples on the basis of quantitative survey data to soil groups of the CASC was 50% to 100%, except for soil groups Kein Svay (0%) and Kampong Siem (20%). The CASC is valuable for managing Cambodian rice soils and may also be used for up-scaling and mapping of soil information.     

Change Point in Phosphorus Release from Variously Managed Soils with Contrasting Properties

Abstract

Investigating the relation between concentration or release of phosphorus (P) into soil solution (CaCl₂‐P, determined by 0.01 M CaCl₂ extraction of soils) and soil test phosphorus (Olsen P, or 0.5 N NaHCO₃‐extractable soil phosphorus) for 10 widely ranging and variously managed soils from central Italy, a change point was evident where the slopes of two linear relationships meet. In other words, it was possible to distinguish two sections of the plots of CaCl₂‐P against Olsen P, for which increases of CaCl₂‐P per unit of soil test P increase were significantly (p<0.05) greater above than below these change points. Values of change point ranged from 14.8 to 253.1 mg kg^?1 Olsen P and were very closely correlated (p<0.001) to phosphorus sorption capacity of soils. Similar change points were also previously observed when Olsen P (and also Mehlich 3 P) of surface soils was related to the P concentration of surface runoff and subsurface drainage. Because insufficient data are available relating P in surface soils and amount of P loss by overland, subsurface, or drainage flow, using the CaCl₂ extraction of soil can be convenient to determine a change point in soil test P, which may be used in support of agricultural and environmental P management.     

Organic Matter and Mineralizable Nitrogen Relationships in Wetland Rice Soils

Abstract

Soil nitrogen (N) supply plays a dominant role in the N nutrition of wetland rice. Organic matter has been proposed as an index of soil N availability to wetland rice. This is based on the finding that mineralizable N produced under waterlogged conditions is related to soil organic carbon (C) and total N. The relationship between organic matter and mineralizable N is a prerequisite for determining the N requirement of wetland rice. However, no critical analysis of recent literature on organic matter–mineralizable N relationships has been made. This article evaluates current literature on the relationships of mineralizable N or ammonium N production with soil organic C in wetland rice soils. A number of studies with diverse wetland rice soils demonstrate a close relationship of N mineralized (ammonium‐N) under anaerobic conditions with organic C or total N. However, a few recent studies made on sites under long‐term intensive wetland rice cropping showed that strong positive relationships of mineralizable N with organic C or total N do not hold. Clearly, both quantity and quality of organic matter affect N mineralization in wetland rice soils. Future research is needed to clarify the role of quality of organic matter, especially its chemistry, as modified by the chemical environment of submerged soils, on the mineralization of organic N in wetland rice soils.     

Availability and plant uptake of nutrients following the application of paper pulp and lime to tropical acid soils

Availability and plant uptake of nutrients were evaluated in three tropical acid soils (Kandiudult) amended with paper pulp and lime under greenhouse conditions. Amendments were applied to attain target pH values of 5.5, 6.0, and 6.5. A control treatment (no paper pulp or lime added) was also included. Rye grass (Lolium perenne L.) as a test plant was grown for three successive cycles of 40 days each. Extractable nutrients and cumulative nutrient uptake were determined. The application of paper pulp or lime resulted in a significant increase in exchangeable Ca and K and a decrease in exchangeable Mg and extractable Fe, Mn, and Zn. Amendment of soils with paper pulp or lime increased plant uptake of Ca and Mg and decreased that of K, Mn, and Zn. Both amendments behaved similarly, but the effect of lime seemed generally greater than that of paper pulp. Paper pulp in tropical acid soils behaved as a liming agent rather than an organic amendment. Similar to lime, amendment of soils with paper pulp resulted in an increase in availability of Ca and Mg and in a decrease in availability of K, Mn, and Zn for plants. Soil extractions appeared to be appropriate for assessing the availability of Ca, Mn, and Zn. Soil pH and effective cation exchange capacity positively influenced the availability of Ca and negatively the availability of Mn and Zn. Thus, the precision of predicting nutrient availability in paper pulp amended tropical acid soils could be improved by including soil pH or effective cation exchange capacity in relevant regression equations.