Organic pesticides. XV. Synthesis and insecticidal activity of some compounds containing phosphorus and fluorine

Forty new organofluorine compounds, containing phosphorus, have been synthesised as potential pesticides. The compounds include esters of O,O-dialkyl phosphoramidic acids of the type (RO)₂P(O)NHAr; thioesters of O,O-dialkyl thiophosphoramidic acids of the type (RO)₂P(S)NHAr; esters of O,O-dialkyl phosphonic acid of the type (RO)₂P(O)Ar and esters of O,O-dialkyl thiophosphonic acid (RO)₂P(S)OAr. All the compounds have been screened for their insecticidal activity against adult cockroaches (Periplanata americana) and a few show appreciable activity.     

Node inoculation: A quick and easy technique to screen pigeonpea for resistance to Phytophthora blight

The petiole on pigeonpea was removed for easy, precise inoculation of node with Phytophthora drechsleri f. sp. cajani. After node inoculation, 96.0% plants were infected compared with 89.0% after stem-cut inoculation. Among various nodes inoculated on 30-day-old plants, the 5th node had the greatest relative susceptibility (90.0%), followed by the 3rd node (78.0%). This technique was validated on different cultivars (ICP 7119, Bahar, MA 6 and MAL 13), and 586 lines were successfully screened in the field, confirming the rapidity and effectiveness of the technique for resistance screening.     

Arbuscular Mycorrhizal (AM) Diversity in Prosopis cineraria (L.) Druce Under Arid Agroecosystems

Arbuscular mycorrhizal (AM) fungi associated with Prosopis cineraria (Khejri) were assessed for their qualitative and quantitative distribution from eight districts of Rajasthan. A total of three species of Acaulospora, one species of Entrophospora, two species of Gigaspora, twenty-one species of Glomus, seven species of Sclerocystis and three species of Scutellospora were recorded. A high diversity of AM fungi was observed and it varied at different study sites. Among these six genera, Glomus occurred most frequently. Glomus fasciculatum, Glomus aggregatum, and Glomus mosseae were found to be the most predominant AM fungi in infecting Prosopis cineraria. Acaulospora, G. fasciculatum, Sclerocystis was found in all the fields studied, while Scutellospora species were found only in few sites. A maximum of thirty-six AM fungal species were isolated and identified from Jodhpur, whereas only thirteen species were found from Jaisalmer. Spores of Glomus fasciculatum were found to be most abundant under Prosopis cineraria.     

Surgical Management of Enterocutaneous Fistula in a Mare

Enterocutaneous fistulas are reported to be sequelae of congenital umbilical hernia or penetrating trauma to the equine patient's abdomen. An enterocutaneous fistula is considered to be the least common clinical presentation in a horse with incarcinated umbilical hernia, and may be life-threatening if not managed timely. This case report describes an enterocutaneous fistula in a mare as a sequela to congenital umblical hernia. The mare had an uneventful recovery after surgical repair and delivered a healthy foal on subsequent follow-up. The report highlights the need to repair congenital umbilical hernias (regardless of the size), if they do not resolve by the age of 6 to 12 months.     

Effects of 41 Years of Application of Inorganic Fertilizers and Farm Yard Manure on Crop Yields,Soil Quality,and Sustainable Yield Index under a Rice-Wheat Cropping System on Mollisols of North India

The present investigation was carried out to evaluate the effect of integrated nutrient management (INM) on crop yield sustainability and soil quality in a long-term trial initiated during the wet season of 1971 under a humid subtropical climate. Over 41 years of study, 100% nitrogen, phosphorus, and potassium (NPK) + farm yard manure (FYM) at 15 t ha^?1 recorded the most sustainable grain yields. Optimal and superoptimal NPK fertilizers gave quite similar crop yields to that of 100% NPK + FYM at 15 t ha^–1 up to two decades but thereafter yields declined sharply due to emergence of zinc (Zn) deficiency. The sustainable yield index (SYI) values indicated that wheat yields were more sustainable than rice. Soil organic carbon and available N, P, K, and Zn in the control plot decreased the most, whereas 100% NPK + FYM at 15 t ha^–1 improved available N, P and K, maintained soil organic carbon, and decreased Zn over initial levels. Grain yield and SYI were more significantly correlated with Soil Organic Carbon (SOC). Continuous application of FYM contributed the maximum Soil Quality Index (SQI) (0.94), followed by Zn.     

Effect of beta-cyclodextrin on aroma release and flavor perception

Binding and release of volatile compounds to and from beta-cyclodextrin were measured in model aqueous systems using static equilibrium headspace and dynamic headspace dilution. Beta-cyclodextrin decreased the static equilibrium headspace for some volatiles (e.g., ethyl octanoate and decanone) due to binding, but dilution studies demonstrated that binding was readily reversible. Dynamic release of hydrophobic volatile compounds was similar to that observed from emulsions. When beta-cyclodextrin was added to fat free yogurt, the release of a commercial lemon flavoring was modified and was similar to release from a regular fat yogurt. Sensory difference testing confirmed the release results. The data demonstrate that beta-cyclodextrin can be used to modify flavor delivery in both model and real systems; the effects in the latter are sensorially significant.     

Metabolic and digestive enzyme activity of Pangasianodon hypophthalmus (Sauvage, 1878) fingerlings in response to alternate feeding of different protein levels in the diet

A feeding trial was conducted for 90 days to assess the metabolic and digestive enzyme activity in response to alternate or mixed feeding of different protein levels in the diet of Pangasianodon hypophthalmus fingerlings. One hundred and forty four fingerlings with an average weight of 5.0–5.5 g were distributed into four experimental groups each with triplicate. Four iso‐caloric diets with varying level of crude protein viz., 35%, 30%, 25% and 20% were made and designated as diet 35P, 30P, 25P and 20P respectively. Four treatments were maintained based on four different feeding schedules such as continuous feeding of diet 35P (35P/35P), alternate feeding of 1 day diet 35P next day diet 30P (35P/30P), alternate feeding of 1 day diet 35P next day diet 25P (35P/25P) and alternate feeding of 1 day diet 35P next day diet 20P (35P/20P). As a result, specific growth rate (SGR) and weight gain percentage were relatively higher in treatment (35P/25P) followed by (35P/35P) and (35P/30P). The metabolic enzymes such as lactate dehydrogenase (LDH), malate dehydrogenase (MDH), glucose‐6‐phosphate dehydrogenase (G6PDH), Glucose‐6‐phosphatase (G6Pase), alkaline phosphatase (ALP), acid phosphatase (ACP), alanine aminotransferase (ALT), aspartate aminotransferase (AST) were expressed better in (35P/35P) group followed by (35P/25P) and (35P/30P) groups. The digestive enzymes, protease and lipase activities were higher in (35P/35P) and (35P/25P) groups. The present study revealed that the better nutrient utilization and growth of 35P/25P group is because of their balanced digestive and metabolic enzyme activities through alternate level of higher and lower protein diet.     

Identification and pathogenicity of Alternaria alternata causing leaf spot and blight disease of Ailanthus excelsa in India

Alternaria leaf spot of Ailanthus excelsa is generally considered as minor disease in India. Recently, severe disease outbreaks were recorded in the nursery of the Forest Research Institute, Dehradun, progeny trial at Jhumpa, Haryana, and in a nearby farm field. Leaf symptoms included small circular, brown, necrotic spots with a chlorotic halo. With severe infections, leaf spots coalesced and resulted in leaf blight. A small‐spored Alternaria with concatenated conidia was isolated consistently from the leaf samples with spot symptoms. Sequence analyses of the internal transcribed spacer (ITS) region of ribosomal DNA (rDNA) and the translation elongation factor 1‐alpha (tef‐1α) gene region of two fungal isolates confirmed the species as A. alternata. In detached leaf assays, both isolates produced symptoms similar to those observed on the nursery/field‐grown plants. To validate the detached leaf assay result, pathogenicity was also demonstrated on whole plants in a glasshouse. Koch's postulates were fulfilled by re‐isolating A. alternata from the inoculated leaves. This work is the first to confirm that A. alternata is associated with leaf spot and blight disease of A. excelsa in India.     

Water Cover Technology for Reactive Tailings Management: A Case Study of Field Measurement and Model Predictions

Environmentally safe disposal of sulfide-rich reactive mine tailings is one of the major challenges facing the mining industry in Canada, Scandinavia, USA, and many other parts of the world. Placing tailings under a water cover is one of the effective methods to reduce the influx of oxygen to the tailings. Wind-induced turbulence and subsequent resuspension of the tailings, however, are major concerns with this approach. In this paper, a study of wind-induced resuspension at the Shebandowan tailings storage facility, northwestern Ontario, Canada, is discussed. The study compares computer modeling of required water cover depths and resuspended tailings concentrations to observed field data. The calculated minimum water cover depths required to eliminate resuspension were found to be higher than the existing implemented water cover depths in each cell. The predicted resuspended tailings concentrations for the west cell were 6?C22?mg/l with an average value of 15?mg/l and, for the east cell, 1?C10?mg/l, with an average of 6.0?mg/l. In comparison, optical backscatter sensors, deployed in situ, recorded average resuspended tailings concentration up to 25?mg/l, indicating that the model results were similar to the field-measured values. Results from sediment trap measurements did not show any correlation between the amount of resuspended tailings and water cover depth. Sediment traps collect not only sediments eroded and suspended at the location of deployment but also those that have been transported from elsewhere and redeposited at the trap location. The amount of resuspension occurring at Shebandowan does not raise a major concern because discharge from the tailings area is collected and managed before it reports to the final effluent.