Chemical synthesis of polypyrrole film and its adsorption capacity for aromatic polycarboxylic acids

Polypyrrole (PPy) film was prepared via in-situ chemical polymerization of pyrrole monomer on the surface of red-clay-brick (RCB) substrate. The deposited PPy film was characterized and used as an adsorbent for removal of benzene polycarboxylic acids from aqueous solutions. The effects of solution pH, contact time, initial concentration, and temperature on the adsorption process were systematically investigated to find the optimum operating conditions. Adsorption kinetic data were best fitted by pseudo-second order kinetic model. The adsorption equilibrium data were most represented by the Freundlich isotherm model. The maximum adsorption amounts of Trimellitic, Hemimellitic, and Pyromellitic acids were 189.27, 177.26, and 203.31 mg/g, respectively. The thermodynamic studies indicate that the adsorption was an endothermic and spontaneous process. Also, the PPy-RCB film was successfully regenerated using sodium hydroxide solution. The regenerated PPy-RCB can be reused for more than four successive cycles with a low reduction in adsorption efficiency.     

Edge effect and matrix influence on the nest survival of an old forest specialist,the Brown Creeper (<Emphasis Type="Italic">Certhia americana</Emphasis>)

Conservation strategies should be based on a solid understanding of processes underlying species response to landscape change. In forests fragmented by agriculture, elevated nest predation rates have been reported in many forest bird species, especially near edges. In intensively-managed forest landscapes, timber harvesting might also be associated with negative edge effects or broader “context” effects on some species when the matrix provides additional resources to their major nest predators. In this study, we hypothesized that proximity to a forest edge and proportion of cone-producing plantations will increase nest predation risk in fragments of relatively undisturbed forest. We focused on the Brown Creeper (Certhia americana), an indicator species of late-seral forests. We compared habitat configuration and composition at four spatial scales (0.14, 0.5, 1 and 2 km) around 54 nests and related daily nest survival rate to the distance to the nearest forest edge, mean patch size of late-seral forest (r = 141 m), proportion of non-forested lands (r = 141 m), density of maintained roads (r = 1 km), proportion of cone-producing spruce plantations (r = 2 km), and year. The best model included distance to the nearest edge and proportion of cone-producing plantations. Distance of nests to the nearest edge was the best individual predictor of daily nest survival. A larger sample of nests showed a significant threshold in distance to the nearest forest edge; nests located at least 100 m away were more likely to fledge young. These results suggest that even in managed forest landscapes, matrix effects can be important and some bird species may exhibit negative edge effects.     

Identification of genetic sources with attenuated <Emphasis Type="Italic">Tomato chlorosis virus</Emphasis>-induced symptoms in <Emphasis Type="Italic">Solanum</Emphasis> (section <Emphasis Type="Italic">Lycopersicon</Emphasis>) germplasm

The whitefly-transmitted Tomato chlorosis virus (ToCV) (genus Crinivirus) is associated with yield and quality losses in field and greenhouse-grown tomatoes (Solanum lycopersicum) in South America. Therefore, the search for sources of ToCV resistance/tolerance is a major breeding priority for this region. A germplasm of 33 Solanum (Lycopersicon) accessions (comprising cultivated and wild species) was evaluated for ToCV reaction in multi-year assays conducted under natural and experimental whitefly vector exposure in Uruguay and Brazil. Reaction to ToCV was assessed employing a symptom severity scale and systemic virus infection was evaluated via RT-PCR and/or molecular hybridization assays. A subgroup of accessions was also evaluated for whitefly reaction in two free-choice bioassays carried out in Uruguay (with Trialeurodes vaporariorum) and Brazil (with Bemisia tabaci Middle-East-Asia-Minor1—MEAM1?=?biotype B). The most stable sources of ToCV tolerance were identified in Solanum habrochaites PI 127827 (mild symptoms and low viral titers) and S. lycopersicum ‘LT05’ (mild symptoms but with high viral titers). These two accessions were efficiently colonized by both whitefly species, thus excluding the potential involvement of vector-resistance mechanisms. Other promising breeding sources were Solanum peruvianum (sensu lato) ‘CGO 6711’ (mild symptoms and low virus titers), Solanum chilense LA1967 (mild symptoms, but with high levels of B. tabaci MEAM1 oviposition) and Solanum pennellii LA0716 (intermediate symptoms and low level of B. tabaci MEAM1 oviposition). Additional studies are necessary to elucidate the genetic basis of the tolerance/resistance identified in this set of Solanum (Lycopersicon) accessions.     

First report of sclerotinia rot of mango caused by <Emphasis Type="Italic">Sclerotinia sclerotiorum</Emphasis> in Japan

A panicle blight with sclerotia was found on mango (Mangifera indica L.) in Okinawa Prefecture, Japan, in March 2016. Water-soaked lesions with white mycelia developed on panicles in the flowering stage; softening and decay of panicles was followed by formation of sclerotia. The fungus isolated from these sclerotia was identified as Sclerotinia sclerotiorum based on morphology and analysis of rDNA-ITS sequences. The isolate reproduced the symptoms on mango panicles in an inoculation test and was reisolated from flower stalks. This is the first report of sclerotinia rot (kinkaku-byo in Japanese) on mango caused by S. sclerotiorum in Japan.     

An improved shear lag model for predicting stress distribution in hybrid fiber reinforced rubber composites

An improved micromechanical shear lag model, which considers the interphase and bonded fiber end, is developed to investigate the load-carrying characteristics and stress profiles in hybrid aramid/sepiolite fiber reinforced rubber composites. The properties of the equivalent matrix, which is combination of sepiolite fiber and rubber matrix, are determined by Mori-Tanaka method. The axial and shear stresses at the fiber end are resolved by the imaginary fiber technique. The results obtained from the improved model show the tensile stress has a maximal at the real fiber center and the interfacial shear stress has a maximal at the end of the real fiber. Comparing with the results from Tsai’s model, the improved model has a better agreement with the numerical simualtion results. The effects of the imaginary fiber length on the stress transfer are analyzed and the results show that the effects can be ignored when the imaginary fiber length is greater than twice of the fiber radius. The effects of interphase modulus and thickness on the maximal axial and shear stresses are discussed. The results show that the interphase modulus and thickness of about 106.3 MPa and 0.2 μm are optimal to prevent interfacial debonding and improve the strength of hybrid fiber reinforced rubber composites.     

Nitrogen loading levels affect abundance and composition of soil ammonia oxidizing prokaryotes in semiarid temperate grassland

Purpose  

Global nitrogen deposition has profound impact on the terrestrial ecosystem including the semiarid temperate grassland, causing vegetation community shifts and soil acidification. Little is known regarding the effect of nitrogen (N) deposition on the belowground microbial communities. This study aimed to examine the response of ammonia-oxidizing bacteria (AOB) and archaea (AOA) to added N in semiarid temperate grassland.     

Major nutrients,heavy metals and PBDEs in soils after long-term sewage sludge application

Purpose

Two contrasting soils receiving long-term application of commercial sewage sludge fertilizers in China were investigated to determine the concentrations of selected nutrients, heavy metals (HMs) and polybrominated diphenyl ethers (PBDEs) present to evaluate the impact of sewage sludge fertilizer on soil fertility and environmental risk.

Materials and methods

Soil samples were collected from Tangshan City, Hebei province and Ningbo City, Zhejiang province and divided into two portions, one of which was air-dried and sieved through 2-, 0.25- and 0.149-mm nylon mesh for determination of nutrients and heavy metals. The other portion was frozen at ?20°C, freeze-dried and sieved through 2-mm nylon mesh for PBDE analysis. The concentrations of nutrients, heavy metals and PBDEs were determined in all samples.

Results and discussion

Concentrations of nutrients and heavy metals in soils amended with low rates of sewage sludge fertilizer (SSF) and conventional fertilizer were compared. After long-term excessive amendment with SSF from Ningbo City (SSF-N), the concentrations of soil total N, P, aqua regia-extractable HMs and DTPA extractable HMs were higher than the control, especially in the arable layer. Moreover, the concentration of aqua regia-extractable Zn (457 mg kg^?1) exceeded the recommended China Environmental Quality Standard for soils (GB15618-1995). All 8 target PBDE congeners were found in fertilizer SSF-N and soil with excessive amendment with SSF-N for 12 years, but the concentrations of 8 different PBDEs in SSF-N-amended soil were not significantly different from control soil.

Conclusions

Both economic and environmental benefits can be obtained by careful application of sewage sludge fertilizer to recycle plant nutrients. Repeated and excessive application rates of sewage sludge fertilizer may pose environmental risk, especially in respect of soil heavy metal and PBDE contamination, and high concentrations of phosphorus may also be environmentally detrimental.

     

Xylem traits in European beech (Fagus sylvatica L.) display a large plasticity in response to canopy release

Key message

The position of trees in the canopy impacts xylem structure and its inter-annual variation. After canopy release, the increase in the hydraulic conductivity of growth rings was driven by an increase in radial growth in large trees, and by both an increase in radial growth and changes in xylem structure in saplings.

Context

Forest canopies are frequently subjected to disturbances that allow understory trees to access the upper canopy. The effect of canopy release on xylem anatomy has been assessed in juvenile trees and saplings, while the potential acclimation of larger trees remains poorly documented.

Aims

We estimated the potential hydraulic conductivity of growth rings in large understory trees compared to overstory trees, and evaluated the responses to canopy release in large trees and in saplings.

Methods

We recorded radial growth, wood density, and vessel structure in beech trees according to their position within the canopy and their size. Xylem traits were followed during 6 years after canopy release for large trees, and during 2 years for saplings. Vessel diameter and frequency as well as ring area were used to compute the potential annual ring hydraulic conductivity.

Results

Large understory trees displayed lower radial growth increments and lower potential annual ring hydraulic conductivity than overstory trees. After canopy release, potential annual ring hydraulic conductivity increased in large trees, due exclusively to increased radial growth without any change in specific hydraulic conductivity. It increased in saplings due to both increased radial growth and increased specific conductivity.

Conclusion

Tree size impacted xylem structure and resulted in plasticity of the potential hydraulic conductivity of the annual tree ring following canopy release.

     

Culture of juvenile European lobster (<Emphasis Type="Italic">Homarus gammarus</Emphasis> L.) in submerged cages

A bottleneck for re-establishment or enhancement of lobster (Homarus gammarus L.) populations through release of hatchery-produced juveniles is ineffective and expensive juvenile production. In this study, we cultured lobster juveniles from stage V to a size being suitable for re-establishment or enhancement purposes (40–50 mm total length) in cages submerged under existing facilities for culture of bivalves. The lobsters were not feed or tended during the culture period (6–14 months). The survival and growth rates were similar or higher compared to what has been achieved with other methods used for culture of lobster juveniles in the past. The highest survival (82–89%) and fastest growth (4–5 cm total length over 190–250 days) were achieved using commercial oyster baskets. It is believed that the juveniles fed on naturally occurring plankton and organisms growing inside the cages. Thus, the current study shows that it is possible to culture lobster juveniles for reestablishment or enhancement purposes in a way that would involve less investments and operational costs than earlier used methods as there would be no need for artificial heating of water, for large buildings or for continuous feeding and tending of large numbers of juveniles.     

Post-fire attractiveness of maritime pines (<Emphasis Type="Italic">Pinus pinaster</Emphasis> Ait.) to xylophagous insects

The spectrum and dynamics of xylophagous insects infesting Pinus pinaster after a fire event were studied from November 2007 to December 2008 at Sierra de Outes (Galicia, NW Spain). Insects were collected within and outside the fire area. Relationships among species status, species abundance, tree parameters and tree injury were assessed. Mortality of injured trees was also recorded. Insect colonization built up consistently during the first year after the fire, although the pests did not colonize unburned trees in nearby areas. Thirteen insect species from six xylophagous families were collected. Tomicus spp., Buprestis novenmaculata, Anobium punctatum and Pissodes castaneus were the first species detected. Tomicus spp. (29%) and Ips sexdentatus (23%) were the dominant taxa. Bole char height and soil burn severity were positively correlated with insect presence. Trees with short stem diameter and thinner bark were also preferred. B. novenmaculata presence was positively correlated with crown scorch. Loss of cambium hydration was negatively related to the occurrence of pests, likely because sapwood desiccation and loss of nutrient impede brood development. About 33.3% of the fire-scorched pines died. The results recommend the removal of injured and dying pines after fire, to avoid the rise of pest population threatening recovering trees in the burned areas.