Field estimates of scalar advection across a canopy edge

Measurements of the horizontal and vertical fluxes of energy and mass were taken at a crop canopy edge and downwind of it to examine the effects of inhomogeneity on surface-atmosphere exchange, for the ideal case of flat uniform terrain. Energy balance closure was also examined and the effects of the often-neglected advection terms on the energy budget were evaluated. The results show that neither vertical nor horizontal advection should be neglected for moderate distances downwind from heterogeneous boundaries, with the energy budget closure near the leading edge improved by more than 20% with the inclusion of the horizontal and vertical advection of latent and sensible heat. Significant mean advective horizontal and vertical flux divergences of water vapor and temperature were found even in typical daytime conditions. In stable conditions horizontal advection can be responsible for more than 15% of the scalar (water vapor) transport 136 canopy heights downwind of a change in water vapor source density and surface roughness.     

Tillage-induced environmental conditions in soil and substrate limitation determine biogenic gas production

Tillage changes soil environmental conditions and controls the distribution of residues in the soil, both actions that affect the production and emission of soil biogenic gases (CO₂, N₂O, and CH₄). The objective of this study was to determine how tillage-induced environmental conditions and substrate quality affect the mineralization rate of easily metabolizable compounds and the subsequent production of these gases. Carbon compounds, with and without nitrogen, were applied to soil cropped to maize under tilled and no-till systems. Following substrate application in the spring and summer, biogenic gases were measured periodically at the soil surface (flux) and within the profile (concentration) at 10-, 20-, and 30-cm depths (i.e., within, at the bottom of, and below the plough layer). Strong CO₂ and N₂O responses to sucrose and glycine in both the field and the laboratory indicate that the soil was C- and N-limited. Surface fluxes of CO₂ and N₂O were greater in soils amended with glycine than with sucrose and were greater in tilled than no-till soils. Transient emission of CH₄ following the addition of glycine was observed and could be attributed to inhibition of N mineralization and nitrification processes on CH₄ oxidation. Laboratory and field measurements indicated that the larger substrate-induced CO₂ emission from the tilled soils could not be attributed to differences in the total biomass or the basal respiratory activity of the soils. Thus, there appears to be no underlying difference in the functional capacity of the microbial communities under different tillage regimes. Comparison of gas profiles indicates relative accumulation of CO₂ at depth in soils under no-till, as well as greater decline in profile CO₂ content with time in the tilled compared to the no-till soil. These results support the conclusion that greater CO₂ efflux from the tilled soils resulted from more rapid gas diffusion through the profile. Hence, the observed differences in gas fluxes between tilled and no-till soils can be attributed to differences in physical environment.     

Effects of rhodium heterogeneous catalyst and isomerization conditions on linoleic acid conjugation of soybean oil

Rhodium heterogeneous catalyst was used to catalyze isomerization of linoleic acid in soybean oil to conjugated linoleic acid (CLA). A central composite rotatable design with five levels of three variables, namely, reaction temperature, stirring speed, and reaction time, was used to determine the maximum CLA yield. The formation of CLA during isomerization was greatly dependent on the reaction temperature and time. The CLA content of soybean oil increased from 0.63 to 202.42 mg/g oil when isomerization was done at 200 degrees C, with a stirring speed of 200 rpm for 49 min. Analysis of triacylglycerol positions showed that linoleic acid at any position in a triacylglyceride could possibly be isomerized to CLA.     

不同早稻品种灌浆期高温胁迫后根系生理差异研究

试验研究不同早稻品种灌浆期高温胁迫后根系生理差异结果表明,高温对不同水稻品种根系超氧化物歧化酶、过氧化物酶、过氧化氢酶活性均有影响,但对耐热型品种的影响显著小于热敏感品种,耐热型品种在高温胁迫后保护酶活性能较快恢复并接近对照水平;高温胁迫对耐热型水稻品种根系α-萘胺氧化力无影响,但热敏感品种根系氧化力明显下降,故根系α-萘胺氧化力可作为根系耐热指标之一。     

Ergosterol and microbial biomass relationship in soil

Ergosterol and microbial biomass C were measured in 26 arable, 16 grassland and 30 forest soils. The ergosterol content ranged from 0.75 to 12.94 g g^-1 soil. The geometric mean ergosterol content of grassland and forest soils was around 5.5 g g^-1, that of the arable soils 2.14 g g^-1. The ergosterol was significantly correlated with biomass C in the entire group of soils, but not in the subgroups of grassland and forest soils. The geometric mean of the ergosterol: microbial biomass C ratio was 6.0 mg g^-1, increasing in the order grassland (5.1), arable land (5.4) and woodland (7.2). The ergosterol:microbial biomass C ratio had a strong negative relationship with the decreasing cation exchange capacity and soil pH, indicating that the fungal part of the total microbial biomass in soils increased when the buffer capacity decreased. The average ergosterol concentration calculated from literature data was 5.1 mg g^-1 fungal dry weight. Assuming that fungi contain 46% C, the conversion factor from micrograms ergosterol to micrograms fungal biomass C is 90. For soil samples, neither saponification of the extract nor the more effective direct saponification during extraction seems to be really necessary.     

Penetration resistance and root growth of oats in tilled and untilled loess soil

Penetration resistance, bulk density, soil water content and root growth of oats were intensively studied in a tilled and an untilled grey brown podzolic loess soil. Bulk density and penetration resistance were higher in the top layer of the untilled soil compared with the tilled soil. In the latter, however, a traffic pan existed in the 25–30 cm soil layer which had higher bulk density and penetration resistance than any layer of the untilled soil. Above the traffic pan, rooting density (cm root length per cm³ of soil) was higher but below the pan it was lower than at the same depth in the untilled soil. Root growth was linearly related to penetration resistance. The limiting penetration resistance for root growth was 3.6 MPa in the tilled Ap-horizon but 4.6-5.1 MPa in the untilled Ap-horizon and in the subsoil of both tillage treatments. This difference in the soil strength-root growth relationship is explained by the build up of a continuous pore system in untilled soil, created by earthworms and the roots from preceding crops. These biopores, which occupy < 1% of the soil volume, can be utilized by roots of subsequent crops as passages of comparatively low soil strength. The channeling of bulk soil may counteract the possible root restricting effect of an increased soil strength which is frequently observed in the zero tillage system.     

Influence of lambda-carrageenan on the release of systematic series of volatile flavor compounds from viscous food model systems

The effect of lambda-carrageenan addition level (0.1, 0.25, 0.4, and 0.5% w/w) and viscosity on the release of systematic series of aroma compounds (aldehydes, esters, ketones, and alcohols) was studied in thickened viscous solutions containing lambda-carrageenan and 10 wt % of sucrose. Air-liquid partition coefficients K (37 degrees C) of a total of 43 aroma compounds were determined in pure water and in the lambda-carrageenan solutions by static headspace gas chromatography. Mass transfer of the aroma compounds in water and in the thickened lambda-carrageenan solutions which had a wide viscosity range was assessed by dynamic headspace gas chromatography. K (37 degrees C) increased as the carbon chain increased within each homologous series. Esters exhibited the highest volatility, followed by aldehydes, ketones, and alcohols. Under equilibrium, no overall effect of lambda-carrageenan was found, except with the most hydrophobic compounds. Analysis of flavor release under nonequilibrium conditions revealed a suppressing effect of lambda-carrageenan on the release rates of aroma compounds, and the extent of decrease in release rates was dependent on the physicochemical characteristics of the aroma compounds, with the largest effect for the most volatile compounds. However, none of the effects was of a magnitude similar to the obtained changes in the macroscopic viscosity, and the suppressing effects are therefore attributable to the thickener and not the physical properties of the increasingly viscous systems.     

Improved method for determination of pectin degree of esterification by diffuse reflectance Fourier transform infrared spectroscopy

An improved method for the determination of pectin degree of esterification (DE) by diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS) was developed. Pectin samples with a range of DE as determined by gas chromatography were used for developing a calibration curve by DRIFTS. A linear relationship between the DE of pectin standards and FTIR peak ratio for ester carboxyl peak area to total carboxyl peak area was found (R(2) = 0.97). Pectin DE of various samples was calculated from the linear fit equation developed by DRIFTS. Accuracy of the DRIFTS method was determined by comparing the DE values of four commercial pectins obtained by DRIFTS methods to the values obtained by the gas chromatography method. Greater precision was obtained for the FTIR measurement of test pectin samples when the ester peak ratio was used relative to the ester peak area.     

Current status and future strategy in breeding grasspea (Lathyrus sativus)

Efforts in grasspea (Lathyrus sativus) improvement have increased since the development of lines that are very low in the neurotoxin Beta-N-oxalyl-L-alpha-beta-diamino propionic acid (ODAP); also referred to as Beta-N oxalyl-amino-L-alanine (BOAA). Many programs now address several related aspects of improvement simultaneously. These include reduced ODAP concentrations, insect and disease resistance, nitrogen fixation, agronomic practices, fodder and forage production, and components for increased yielding ability. The coordinated, multidisciplinary approach now being applied to the genetic improvement of grasspea should allow the potential of this largely neglected grain legume to be fully realized.     

Soil phosphorus status and turnover in central-European beech forest ecosystems with differing tree species diversity

Problems in phosphorus (P) nutrition of forest trees raise questions concerning the soil P concentrations, pools and turnover in forests. In addition, it is not clear if, and to what extent, tree species diversity has an influence on the soil P status and turnover. The aim of this study was to investigate the P status and turnover in beech ( Fagus sylvatica L.) -dominated forest ecosystems on loess over limestone and to elucidate what role heterogeneities in tree species diversity would play. The soils of mixed species stands contained more organically bound P (710–772 kg ha⁻¹) than those of pure beech stands (378 kg ha⁻¹), whereas the inorganic P content differed little between the stand types. A large proportion (44–55%) of the total soil P was organically bound. This fraction was mainly dependent on the clay content of the soils and not on the tree diversity. The P input with leaf litter (1.4–2.1 kg ha⁻¹ year⁻¹) showed a tendency to increase with increasing diversity. The apparent P turnover times in the organic surface layers differed, with shorter turnover times in mixed species stands (2–3 years) than in pure beech stands (10 years). Possible explanations for the different turnover times were differences in the litter quality, interactions in mixed species litters and the soil pH and base saturation. Hence, the tree species mainly influence the apparent P turnover time in the organic surface layer, whereas the P concentrations and pools in the mineral soil are determined by the soil properties, particularly the clay content.