Influence of CaCl(2) on the foliar biomass and quality of tobacco leaves

The aim of the present work was to determine the influence of different CaCl(2) dosages on foliar biomass and quality of tobacco plants (Nicotiana tabacum L. var. Tennesse 86). Plants were grown under controlled conditions and submitted to regular fertilization with macro- and micronutrients. The CaCl(2) was applied to the nutrient solution at 1.25 mM (T1), 2.5 mM (T2), and 5 mM (T3). The results indicated that, under the experimental conditions of this work, the application of 1.25 mM of CaCl(2) favored the growth and development of the leaves, this leading to improved biomass production in tobacco leaves. The increase in foliar biomass in treatment T1 could largely be a result of the stimulation of NO(3)(-) assimilation. However, this situation has negative consequences for tobacco quality, given that the T1 treatment augmented the NO(3)(-) concentration and the foliar concentration of nicotine (both effects being harmful for human consumption) and decreased the concentration of reducing sugars in leaves of tobacco plants compared with those of T2 and T3. Finally, a close and directly proportional relationship was found in our experiment between the parameters of foliar-biomass production, total N concentration, chlorophyll concentration, and decline in quality.     

Are landscapes over-irrigated in Southwest Florida? A spatial�Ctemporal analysis of observed data

Monthly water billing records for eleven cities in Hillsborough County Florida were available from 2001 through 2007. Irrigation was estimated from total water use based on two different methods to estimate basic indoor water use and assumed impervious areas. Estimated irrigation use was compared with a calculated irrigation requirement by a water balance to test if homeowners were over-irrigating. Results showed that on average, the mean estimated irrigation was lower than the calculated irrigation requirements in most of the cities and years given the uncertainties in this analysis. The calculated irrigation ranged from 612 to 744 mm year⁻¹, whereas the average estimated irrigation ranged from 264 to 684 mm year⁻¹. However, there were some homeowners that greatly exceeded the calculated irrigation requirement. The estimated irrigation increased temporarily in areas under urban development, which was evidenced by built landscape expansion. Good correlation was found between the annual estimated irrigation and the annual calculated irrigation requirements, when the per capita method was used, but not between the annual estimated irrigation and the annual rainfall. Future conservation programs can use this methodology to identify users where substantial opportunity for water savings exists.     

Spatial Variability of Turbulent Mixing in the Abyssal Ocean

Ocean microstructure data show that turbulent mixing in the deep Brazil Basin of the South Atlantic Ocean is weak at all depths above smooth abyssal plains and the South American Continental Rise. The diapycnal diffusivity there was estimated to be less than or approximately equal to 0.1 x 10(-4) meters squared per second. In contrast, mixing rates are large throughout the water column above the rough Mid-Atlantic Ridge, and the diffusivity deduced for the bottom-most 150 meters exceeds 5 x 10(-4) meters squared per second. Such patterns in vertical mixing imply that abyssal circulations have complex spatial structures that are linked to the underlying bathymetry.     

Atom collision-induced resistivity of carbon nanotubes

We report the observation of unusually strong and systematic changes in the electron transport in metallic single-walled carbon nanotubes that are undergoing collisions with inert gas atoms or small molecules. At fixed gas temperature and pressure, changes in the resistance and thermopower of thin films are observed that scale as roughly M(1/3), where M is the mass of the colliding gas species (He, Ar, Ne, Kr, Xe, CH4, and N2). Results of molecular dynamics simulations are also presented that show that the maximum deformation of the tube wall upon collision and the total energy transfer between the colliding atom and the nanotube also exhibit a roughly M(1/3) dependence. It appears that the transient deformation (or dent) in the tube wall may provide a previously unknown scattering mechanism needed to explain the atom collision-induced changes in the electrical transport.     

Performance of peach and plum based rootstocks of different vigour on a late peach cultivar in replant and calcareous conditions

The field performance of fifteen peach and plum based rootstocks of different vigour (Adesoto, Evrica, Garnem, GF 677, HM-2, Krymsk^® 1, PAC 9801-02, PAC 960, PAC 9907-02, PAC 9917-26, PAC-MUT, PADAC 9907-23, ROOTPAC^® 40, ROOTPAC^® 70 and Tetra) grafted with ‘Calrico’ cultivar was compared after 7 years of establishment on an Armillaria infested replant site. ‘Calrico’ is a selected clone of “Calanda” late peach cultivar. Differences in parameters such as tree survival, leaf chlorophyll content, vigour, yield, cumulative yield, yield efficiency and fruit size were analyzed among rootstocks. All PAC 9801-02 and Tetra trees survived and the mortality rate was low in Evrica, PADAC 9907-23 and ROOTPAC^® 40. The rest of genotypes showed higher mortality rates. Leaf chlorophyll concentration was higher when grafted on Adesoto and Evrica and lower when grafted on PAC 9907-02 and PAC 9917-26. Garnem and PADAC 9907-23 were the most vigorous rootstocks. The highest yield efficiency was induced by Krymsk^® 1 and PAC 9801-02 due to their lower vigour. The highest fruit weight was also induced by Krymsk^® 1 but its cumulative yield was low. Other rootstocks that showed high fruit weight and cumulative yields were ROOTPAC^® 70 and Tetra. Overall, Evrica, PAC 9801-02, ROOTPAC^® 40 and Tetra were among the best adapted to soil sickness and calcareous soil showing a good agronomic performance. The first three rootstocks (Evrica, PAC 9801-02, ROOTPAC^® 40) also exhibited a high capacity to control tree vigour associated with high yield efficiency.     

Hydroxytyrosol 4-beta-D-glucoside,an important phenolic compound in olive fruits and derived products

There is increasing interest in olive polyphenols because of their biological properties as well as their contribution to the color, taste, and shelf life of olive products. However, some of these compounds remain unidentified. It has been shown that hydroxytyrosol 4-beta-D-glucoside (4-beta-D-glucosyl-3-hydroxyphenylethanol) coeluted with hydroxytyrosol [(3,4-dihydroxyphenyl)ethanol] under reversed phase conditions in the phenolic chromatograms of olive pulp, vegetation water, and pomace of olive oil processing. A method to separate this compound from hydroxytyrosol by HPLC has been developed. The concentration of this glucoside increased in olive pulp with maturation and could be the main phenolic compound in mature olives. In contrast, the presence of this compound was not detected in olive oil by using HPLC-MS. The compound must be considered both in table olives and olive oil processing because of its glucose and hydroxytyrosol contribution to these products.     

Polyphenol changes during fermentation of naturally black olives

The individual evolution of phenolic compounds has been studied during the natural fermentation of black olives for the first time. Cyanidin 3-rutinoside and cyanidin 3-glucoside were the main anthocyanins identified in fresh olives, and they were not detected after 1 month of storage either in brine or in olive. The fruit colors were different when aerobic or anaerobic conditions were used and as a consequence of the different anthocyanin polymerizations that took place. At time zero, the polyphenols observed in the olive juice were hydroxytyrosol-4-beta-glucoside, oleuropein, hydroxytyrosol, tyrosol, salidroside, and verbascoside and, after 12 months, the main phenol was hydroxytyrosol. The polyphenol content in the oil phase of olives was also analyzed. The dialdehydic form of elenolic acid linked to hydroxytyrosol and tyrosol, oleuropein aglycon, and ligstroside aglycon were the main compounds found at the beginning of fermentation but were not detected after 3 months. In contrast, hydroxytyrosol, hydroxytyrosol acetate, tyrosol, and tyrosol acetate were the main polyphenols detected in the oil phase of the final product. The acid hydrolysis of the initial glucosides (in olive juice) and the aglycons (in oil phase) was, therefore, the main reaction that took place during fermentation.     

The causes of piping in a set of abandoned agricultural terraces in southeast Spain

This study aims to identify some of the factors contributing to the piping process in abandoned terraces in seven sites located in the Murcia Region (southeast Spain). The local landscape has the appearance of badland geomorphology, possessing deep valleys which until the 1970s were terraced and cultivated. The terraces have now been abandoned to the piping process. The research focuses on the relationship between the size and position of pipes and the physical and geochemistry properties of the local highly dispersive marl lithology; and the extent to which the reworking of the materials for terrace cultivation has exacerbated piping erosion.Morphologically, the terracing in the stream beds has resulted in a series of gentle benches separated by steeper risers with variable ‘drop’, (riser height). A series of flat infiltration surfaces result, and because the resculpting produces a reduced bulk density infill with enhanced throughflow, infiltrating water is forced along steep hydraulic gradients to a low outfall at the base of the riser.Paralleling studies of land levelling and terrace abandonment in similar materials elsewhere, piping in the study area is shown to be closely related to the physical and chemical characteristics of the materials its sodicity and dispersive character. Considerable differences in structure, texture, mineralogical composition and material's surface crust and subsoil geochemical properties emerged from ‘site signature’ plots, and these results suggest that agricultural processes affect the dispersive character of the crust materials, presumably because agricultural activity increases the buffering effect of organic acids on the dispersed clay. This is supported by the observation that on the one site that was levelled but not used for agriculture, a stable organically-distinct crust like the abandoned agricultural sites has not formed. The changes to the material's aggregate stability and bulk density properties when terracing occurs is examined, but insufficient evidence is available from the data collected to unpick the causes of aggregate stability changes in the study plots. The way in which differences between crust and subsoil enhance infiltration is discussed, and the role of the terrace ‘drop’ in influencing hydraulic gradients and pipe development is illustrated. A possible index to describe the relationship between evacuated material volumes and the controlling parameters discussed above is tested.It is concluded that terracing which is intended as a conservation practice has, in dispersive materials, actually enhanced piping, leading to the abandonment of farming.     

Changes in the phenolic composition of virgin olive oil from young trees (Olea europaea L. cv. Arbequina) grown under linear irrigation strategies.

This study reports the HPLC profiles of phenolic compounds of virgin olive oils obtained from young olive trees (Olea europaea L. cv. Arbequina) and how the application of a linear irrigation strategy affected these. Hydroxytyrosol, tyrosol, vanillic acid, vanillin, 4-(acetoxyethyl)-1,2-dihydroxybenzene, p-coumaric acid, the dialdehydic form of elenolic acid linked to hydroxytyrosol and to tyrosol, lignans, and the oleuropein aglycon were found in all the oils. Hydroxytyrosol, tyrosol, vanillic acid, and p-coumaric acid contents in the oils were unaffected by linear irrigation. The concentration of lignans was lower in the oils from the least irrigated treatment and the concentration of vanillin increased as the amount of irrigation water applied to olive trees increased. However, 4-(acetoxyethyl)-1,2-dihydroxybenzene, the dialdehydic form of elenolic acid linked to hydroxytyrosol and to tyrosol, and the oleuropein aglycon, all of them hydroxyphenyl derivatives, decreased as the level of irrigation water increased. The latter three compounds represented the most considerable part of the phenolic fraction of the oils and they were shown to be correlated to the oxidative stability, the bitter index (K(225)), and the bitter, pungent, and sweet sensory attributes. Linear irrigation strategy changed the profile of the oil phenolic compounds and, therefore, changed both the organoleptic properties and the antioxidant capacity of the product.