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Long-term microscale field experiments established at four sites in the Czech Republic (since 1996) were used for an assessment of the severity of the wide-scale contamination of treated soils by persistent organic pollutants (POPs) and pharmaceuticals and personal care products (PPCPs) as a result of the long-term regular pollutant load via sewage sludge and farmyard manure applications and for an estimation of the potential environmental risk caused by long-term pollutant inputs to agricultural soils.
Material and methodsThe experimental plots were treated as follows: (i) NPK mineral fertilization (NPK); (ii) sewage sludge (SS1); (iii) sewage sludge applied at three times the rate compared to SS1 (SS2); (iv) farmyard manure (FYM); and (v) untreated control. Except for antibiotics, which showed results for all analyses below the detection limit, all groups of the analyzed compounds showed measurable contents in the treated soils.
Results and discussionAmong the POPs, the levels of organochlorine pesticides (OCPs) were detected at two locations at levels exceeding the Czech preventive values for their contents in agricultural soils (7.5 μg/kg for dichlorodiphenyl trichloroethane family, 20 μg/kg for hexachlorbenzene, and 10 μg/kg for α-hexachlorocyclohexane), regardless of the treatment. Similarly, elevated contents of polycyclic aromatic hydrocarbons (PAHs) were occasionally observed without any substantial relationship to the fertilizer application scenario. Thus, these contaminants are connected with atmospheric deposition in the given areas (PAHs) and their long-term stability (OCPs) even several decades after their ban; the role of the fertilizer composition was negligible.
ConclusionsThe levels of per- and polyfluoroalkylated substances, brominated flame retardants, and synthetic musk compounds tended to increase in the sewage sludge–treated plots, indicating that sewage sludge can contribute to the abundance of these compounds in soil, although the contaminant levels determined do not represent a direct environmental risk. The levels of these contaminants in sewage sludge and sludge-treated soils should be regularly monitored in further research.
相似文献The majority of biochar studies use soils with only a narrow range of properties making generalizations about the effects of biochar on soils difficult. In this study, we aimed to identify soil properties that determine the performance of biochar produced at high temperature (700 °C) on soil pH, cation exchange capacity (CEC), and exchangeable base cation (Ca2+, K+, and Mg2+) content across a wide range of soil physicochemical properties.
Materials and methodsTen distinct soils with varying physicochemical properties were incubated for 12 weeks with four rates of biochar application (0.5, 2, 4, and 8% w/w). Soil pH, CEC, and exchangeable base cations (Ca2+, K+, and Mg2+) were determined on the 7th and 84th day of incubation.
Results and discussionOur results indicate that the highest biochar application rate (8%) was more effective at altering soil properties than lower biochar rates. Application of 8% biochar increased pH significantly in all incubated soils, with the increment ranging up to 1.17 pH unit. Biochar induced both an increment and a decline in soil CEC ranging up to 35.4 and 7.9%, respectively, at a biochar application rate of 8%. Similarly, biochar induced increments in exchangeable Ca2+ up to 38.6% and declines up to 11.4%, at an 8% biochar application rate. The increment in CEC and exchangeable Ca2+ content was found in soils with lower starting exchangeable Ca2+ contents than the biochar added, while decreases were observed in soils with higher exchangeable Ca2+ contents than the biochar. The original pH, CEC, exchangeable Ca2+, and texture of the soils represented the most crucial factors for determining the amount of change in soil pH, CEC, and exchangeable Ca2+ content.
ConclusionsOur findings clearly demonstrate that application of a uniform biochar to a range of soils under equivalent environmental conditions induced two contradicting effects on soil properties including soil CEC and exchangeable Ca2+ content. Therefore, knowledge of both biochar and soil properties will substantially improve prediction of biochar application efficiency to improve soil properties. Among important soil properties, soil exchangeable Ca2+ content is the primary factor controlling the direction of biochar-induced change in soil CEC and exchangeable Ca2+ content. Generally, biochar can induce changes in soil pH, CEC, and exchangeable Ca2+, K+, and Mg2+ with the effectiveness and magnitude of change closely related to the soil’s original properties.
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