Comparison of fractal dimensions of soils estimated from adsorption isotherms,mercury intrusion,and particle size distribution

The values of the surface fractal dimensions were determined for several samples of Cambisols and Luvisols from analysis of nitrogen and water vapor adsorption isotherms and from mercury intrusion data. Moreover, the values of fractal dimension characterizing the particle size distributions of soil samples were calculated by using a number‐based method. For almost all investigated soils the values of the surface fractal dimension, obtained from water vapor isotherms were lower than those obtained from nitrogen isotherms. Largest were the surface fractal dimensions evaluated form mercury intrusion data. No significant correlations between different kinds of surface fractal dimensions were found, and the reasons of this finding are discussed. However, the values of the surface fractal dimensions calculated from mercury intrusion data correlate with those characterizing the texture of soils. The paper also reports on correlations between of the values of surface area, fractal dimensions and some selected physico‐chemical characteristics of soils.     

Hydrochars derived from sewage sludge: effects of pre-treatment with water on char properties,phytotoxicity and chemical structure

Large amounts of labile compounds are adsorbed to the surface of chars produced by hydrothermal carbonization (HTC). The aim of this study was to characterize the core and adsorbed fractions of hydrochars and to gain knowledge about the possibility to remove phytotoxic compounds by washings with water. Chars were produced by HTC of sewage sludge at different temperatures (180 – 200 °C) and over different periods of time (4 – 8 h). For comparison one pyrolysis char produced by thermocatalytic low temperature conversion (LTC) at 400 °C for 1 h was included in the study. The chars and their feedstocks were treated varying the duration (1 x 15, 1 × 30 and 1 × 60 min) and number (2 x 60 and 3 × 60 min) of washings. Physicochemical properties, including the molecular structure of the test materials, and their effects on germination and plant growth were analysed. Element concentrations and phytotoxic effects were reduced and the number of washings had a stronger effect than their length of time. Intensive washings with water reduced the hydrochars’ portion of biodegradable compounds significantly. However, also plant available nutrients were lost by washing with water, decreasing the value of hydrochars as a soil amendment.     

Effects of Lime and Fertilizer Application on Soil Solution Composition in an Acid Sandy Forest Soil

In a 40 year old pine stand, soil solution was collected continuously with suction cups from 50 and 200 cm depth over a 42-month period following the surface application of lime and K/Mg-fertilizer. K and Mg showed a much higher mobility than Ca, which hardly increased in 200 cm depth even after 42 months. After an initial nitrate peak, concentrations decreased but remained elevated throughout the entire study period. In 200 cm, Al-, Mn, and Cd-concentrations increased due to exchange processes in the top-soil. Continuously elevated sulfate concentrations in 200 cm indicate S-mineralisation from humus decomposition.     

Effect of thermal treatment on the quality of cloudy apple juice

Apple juice from eight different varieties of apples was heated at high-temperature (60-90 degrees C) and short-time (20-100 s) (HTST) combinations. To determine the effect of heating conditions on enzymatic browning and cloud stability in apple juices, the activity of polyphenol oxidase and pectinesterase was analyzed and correlated with the thermal treatment conditions and the quality of the juice. Additional investigations included the measurement of pH value, soluble solid content, titratable acidity, color, and turbidity after 3 and 6 months. The results showed that HTST treatment at 80 degrees C already inactivated polyphenol oxidase, whereas pectinesterase activity was reduced to half and could even at 90 degrees C not be inactivated completely. In fact, highest residual pectinesterase activity was found at 60 degrees C. Heating at 70 degrees C caused stable pectinesterase activity and even a slight increase for 50 and 100 s heating times. Turbidity and lightness increased after HTST treatment. In particular, differences in cloud stability between the varieties were measured. HTST parameters did not correlate with the residual cloud stability after 6 months. The sensory evaluation revealed that only a few combinations were distinguishable. The best stability of cloud and color in relation to heat impact was achieved by HTST treatment between 70 degrees C/100 s and 80 degrees C/20 s.     

N-arylamidines and N-arylimidates of substituted acetic acids and their insecticidal and acaricidal properties

The synthesis of N-arylamidines and N-arylimidates of substituted acetic acids is described. Those amidines and imidates possessing a phosphorus ester as substituent showed insecticidal and high acaricidal properties. By contrast, their precursors were ineffective.     

Protein adsorption on and swelling of polyelectrolyte brushes: A simultaneous ellipsometry-quartz crystal microbalance study

With a coupled spectroscopic ellipsometry-quartz crystal microbalance with dissipation (QCM-D) experimental setup, quantitative information can be obtained about the amount of buffer components (water molecules and ions) coupled to a poly(acrylic acid) (PAA) brush surface in swelling and protein adsorption processes. PAA Guiselin brushes with more than one anchoring point per single polymer chain were prepared. For the swollen brushes a high amount of buffer was found to be coupled to the brush-solution interface in addition to the content of buffer inside the brush layer. Upon adsorption of bovine serum albumin the further incorporation of buffer molecules into the protein-brush layer was monitored at overall electrostatic attractive conditions [below the protein isolectric poimt (IEP)] and electrostatic repulsive conditions (above the protein IEP), and the shear viscosity of the combined polymer-protein layer was evaluated from QCM-D data. For adsorption at the "wrong side" of the IEP an incorporation of excess buffer molecules was observed, indicating an adjustment of charges in the combined polymer-protein layer. Desorption of protein at pH 7.6 led to a very high stretching of the polymer-protein layer with additional incorporation of high amounts of buffer, reflecting the increase of negative charges on the protein molecules at this elevated pH.