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61.
The formation of a complex with aluminum by low molecular weight compounds and saponified ozone-treated kraft lignins was
evaluated based on the decrease in pH of their solutions on the addition of 0.1 M AlCl3. Decreases in pH were observed with the solutions containing compounds having adjacent carboxyl groups (oxalic acid), carboxyl/alcoholic
hydroxyl groups (glycolic acid), carboxyl/formyl groups (glyoxylic acid), and phenolic hydroxyl groups (protocatechuic acid)
on the addition of 0.1 M AlCl3. The malonic and phthalic acids, having two carboxyl groups, were also effective. These results show that the compounds were
effective in forming complexes with aluminum. This finding corresponds to the fact that aluminum toxicity is reduced by formation
of a complex with aluminum, except in phthalic acid. The chemical structures stated above in ozone-treated kraft lignins contribute,
at least partly, to the complex with aluminum. The pH of solutions containing saponified ozone-treated kraft lignins and alkaline-treated
kraft lignin decreased more than that without modified kraft lignins on the addition of 0.1 M AlCl3, showing that they were effective in forming a complex with aluminum. The high molecular weight part of saponified ozone-treated
kraft lignin was effective in forming a complex with aluminum and in reducing its toxicity. 相似文献
62.
Philip Y. Lam Po Yee Chiu Hoi Yan Leung Na Chen Pou Kuan Leong Kam Ming Ko 《Fitoterapia》2010,81(8):1239-1245
The effect of schisandrin B (Sch B) on long-term ethanol-induced oxidative stress in various rat tissues was investigated. Long-term ethanol treatment increased reactive oxygen metabolites (ROM) level in plasma. The ethanol-induced oxidative stress was assessed by mitochondrial glutathione and α-tocopherol levels, antioxidant enzyme activities, malondialdehyde (mtMDA) production and heat shock protein (Hsp) 25/70 levels. Liver was most susceptible to oxidative stress with a significant increase in mtMDA production. Long-term Sch B treatment enhanced mitochondrial antioxidant status in a tissue non-specific manner. Sch B co-treatment ameliorated the alterations in plasma ROM levels, mtMDA production and Hsp 25/70 expression in rat tissues. 相似文献
63.
Han XQ Chung Lap Chan B Dong CX Yang YH Ko CH Gar-Lee Yue G Chen D Wong CK Bik-San Lau C Tu PF Shaw PC Fung KP Leung PC Hsiao WL Han QB 《Journal of agricultural and food chemistry》2012,60(17):4276-4281
A polysaccharide (GSP-6B) with a molecular mass of 1.86 × 10? Da was isolated from the fruiting bodies of Ganoderma sinense . Chemical composition analysis, methylation analysis, infrared spectroscopy, and nuclear magnetic resonance spectroscopy were conducted to elucidate its structure. GSP-6B contains a backbone of (1→6)-linked-β-D-glucopyranosyl residues, bearing branches at the O-3 position of every two sugar residues along the backbone. The side chains contain (1→4)-linked-β-D-glucopyranosyl residues, (1→3)-linked-β-D-glucopyranosyl residues, and nonreducing end β-D-glucopyranosyl residues. An in vitro immunomodulating activity assay revealed that GSP-6B could significantly induce the release of IL-1β and TNF-α in human peripheral blood mononuclear cell (PBMC) and showed no toxicity to either PBMC or a human macrophage cell line THP-1. GSP-6B could also activate dendritic cells (DC) by stimulating the secretion of IL-12 and IL-10 from DC. 相似文献
64.
Ko JA Kim YM Ryu YB Jeong HJ Park TS Park SJ Wee YJ Kim JS Kim D Lee WS 《Journal of agricultural and food chemistry》2012,60(24):6210-6216
Rubusoside (R) is a natural sweetener and a solubilizing agent with antiangiogenic and antiallergic properties. However, currently, its production is quite expensive, and therefore, we have investigated nine commercially available glycosidases to optimize an economically viable R-production method. A stevioside (ST)-specific β-glucosidase (SSGase) was selected and purified 7-fold from Aspergillus aculeatus Viscozyme L by a two-step column chromatography procedure. The 79 kDa protein was stable from pH 3.0 to pH 7.0 at 50-60 °C. Hydrolysis of ST by SSGase produced R and steviol monoglucosyl ester as determined by (1)H and (13)C nuclear magnetic resonance (NMR). Importantly, SSGase showed higher activity toward ST than other β-linked glucobioses. The optimal conditions for R production were 280 mM ST and 16.6 μL of SSGase at pH 5.1 and 63 °C. This is the first discussion detailing the production of R by enzymatic hydrolysis of ST and is useful for the food additive and pharmaceutical industries. 相似文献
65.
The self-assembly of asymmetric ABC triblock copolymers in the ordered structure is investigated using an isothermal-isobaric
molecular dynamics simulation. Unlike symmetric ABC triblock copolymers, more fascinating morphologies are observed in asymmetric
ones because of a larger difference of incompatibility between the components. Various modes of self-assembly in assymmetric
ABC triblock copolymers are also observed depending on the block composition. When the composition of block A is changed from
0.125 to 0.25 at the samef
B
=0.25, the morphological transition from the “cylinder in cylinder” to “cylinders at cylinder” structure is observed in the
simulation. In the case of ABC triblocks withf
B
=0.5, a lamellar-type structure is changed to a cylinder-type structure with increasing the length of block A. When the mid-block
length increases further tof
B
=0.625, the “spheres on cylinder” structure is observed in both the A10B50C20 and A20B50C10 triblocks. From these results, the phase diagram of ABC triblock copolymers can be constructed.
Dedicated to Professor Won-Jei Cho on the occasion of his retirement. 相似文献
66.
67.
68.
Kavita Sharma Leonid Asnin Eun Young Ko Eul Tai Lee 《Acta Agriculturae Scandinavica, Section B - Plant Soil Science》2013,63(2):150-160
Onion cultivar “Sunpower” has growing popularity in Korea due to high storability. The present study considers changes in flavonols, sugars, and two amino acids in onion bulbs during a long-term storage in the ambient dark storage room and in glasshouse equipped with a climate control system. Flavonol and sugar contents were found to fluctuate noticeably during the storage period. Amino acid content remained relatively unchanged till the onset of inner sprouting, increasing afterward. Visible sprouts appeared at week 22 in the dark storage room and for four weeks later in the glasshouse. The bulbs lost 20–30% of their weight depending on storage conditions at the end of the storage trials. At the same time, the content of nutraceutics in study expressed on the dry weight basis remained of the same order of magnitude. The nature of observed variations in chemical composition of onions as well as relation of this phenomenon to physiological development of stored onion bulbs is discussed. A conclusion is made that the “Sunpower” onion cannot sustain overwinter storage. 相似文献
69.
70.
Continuous photografting/crosslinking of polyethyleneglycol dimethacrylate oligomers onto cotton using a water-soluble benzophenone
photoinitiator was investigated. Photografting increased with increasing irradiation dose, oligomer concentration and photoinitiator
concentration. Maximum grafting efficiency of DM 400 and 600 were 83% and 79%, respectively. The photografting increased the
wrinkle resistance of cotton implying surface crosslinking of cotton. Both surface crosslinking and bulk crosslinking of cotton
were accomplished via dual curing of a mixed formulation containing both a thermally curable component (BTCA/SHP) and a UV-curable
component. The wrinkle resistance of the crosslinked cotton was found to be higher when cured by thermal curing after UV curing
rather than by UV curing after thermal curing due to the facile post-polymerization of the UV active component. The presence
of crosslinks in the dually crosslinked cotton was verified with FT-IR and thermogravimetric analysis. 相似文献