Infusion of volatile flavor compounds into low-density polyethylene

Supercritical fluids can extract components from some matrixes (e.g., fat and flavors from food) as well as infusing additives into synthetic polymer matrixes. To study the feasibility of infusing flavors into matrixes as a potential flavoring mechanism, a wide range of volatile flavor compounds was infused into a well-defined synthetic polymer (low-density polyethylene) using supercritical carbon dioxide. The polymer was then extracted, and the amount of infused compound was determined. The effects of time, temperature, pressure, rate of depressurization, volatile concentration, and volatile properties on the degree of infusion were studied. Infusion with supercritical carbon dioxide achieved much higher loadings of the polymer (0.01 to 6.87 mg/g LDPE, depending on the volatile molecule being infused) compared to those achieved by static diffusion. Forty-five volatiles were infused, from which a model was developed to predict infusion as a function of certain physicochemical properties.     

An integrated hydro-economic modelling framework to evaluate water allocation strategies II: Scenario assessment

In this paper the results of an assessment of the hydrological and economic implications of reallocating water in the Musi sub-basin, a catchment within the Krishna Basin in India, are reported. Policy makers identified a number of different but plausible scenarios that could apply in the sub-basin, involving; supplying additional urban demand from agricultural allocations of water, implementing a number of demand management strategies, changing the timing of releases for hydropower generation, changing the crops grown under irrigation, reducing existing stream flows and allowing for more environmental flows. The framework chosen to undertake this assessment was a simulation model that measures and compares the economic values of water allocation scenarios determined from a water allocation model that accounts for supplies of groundwater and surface water across a number of regions and over a variety of uses. Policy makers are provided with the range of measures on the security of the supply of water and the social costs and benefits of reallocating water between sectors and across regions within the sub-basin. Taking water from agriculture to supply urban users has a greater impact on irrigation supplies during dry years. It was also found that changing the allocation of water between sectors, by taking it away from agriculture had a large positive economic impact on the urban sector. Yet the costs involved in undertaking such a strategy results in a significant loss in the net present value of the scheme. Stream flow reductions, if significantly large (at around 20%), were found to have a large physical and economic impact on the agricultural sector. Implementing water saving strategies in Hyderabad was found to be more cost effective than taking water from agriculture, if rainwater tanks are used to achieve this. Changing the timing of hydropower flows resulted in best meeting of irrigation demand in NSLC and NSRC. Under this scenario, the crops grown under irrigation were found to have a significant economic impact on the sub-basin, but not as large as farmers undertaking crop diversification strategies, ones which result in farmers growing less rice. The security of supplying water to different agricultural zones has significantly improved under this scenario. Finally, releasing water for environmental purposes was found to have only a minor impact on the agricultural sector.     

Rapid changes in throughput from single motor cortex neurons to muscle activity

Motor cortex output is capable of considerable reorganization, which involves modulation of excitability within the cortex. Does such reorganization also involve changes beyond the cortex, at the level of throughput from single motor cortex neurons to muscle activity? We examined such throughput during a paradigm that provided incentive for enhancing functional connectivity from motor cortex neurons to muscles. Short-latency throughput from a recorded neuron to muscle activity not present during some behavioral epochs often appeared during others. Such changes in throughput could not always be attributed to a higher neuron firing rate, to more ongoing muscle activity, or to neuronal synchronization, indicating that reorganization of motor cortex output may involve rapid changes in functional connectivity from single motor cortex neurons to alpha-motoneuron pools.     

Radioactivity of the lunar surface

Diffusion of radon and thoron from the Ilunar surface provides a mechanism for production of a radioactive surface layer on the moon. If the radon and thoron flux from the lunar surface is equal to that measured at the earth's surface, the equilibrium activity of this surface layet is estimated as approximately 1 microcurie per square meter, due to radon and its decay products. This activity consists of alpha particles and gamnmna rays at well-defined energies and of beta rays.     

Spectroscopic Observation of the Formyl Cation in a Condensed Phase

The formyl cation, HCO+, has long been believed to be an important intermediate in the chemistry of carbon monoxide (CO) in acidic environments, but its spectroscopic observation in solution has been elusive. This species was generated by the reaction of CO with the liquid superacid hydrofluoric acid-antimony pentafluoride (HF-SbF5) under pressure and was observed by nuclear magnetic resonance and infrared spectroscopy. Equilibria between CO in the gas phase, CO dissolved in HF-SbF5, the SbF5 adduct of formyl fluoride, and HCO+ associated with several equilibrating anions of the type [SbxF5x+1]- are proposed to describe the system.     

Triallelic inheritance in Bardet-Biedl syndrome, a Mendelian recessive disorder

Bardet-Biedl syndrome (BBS) is a genetically heterogeneous disorder characterized by multiple clinical features that include pigmentary retinal dystrophy, polydactyly, obesity, developmental delay, and renal defects. BBS is considered an autosomal recessive disorder, and recent positional cloning efforts have identified two BBS genes (BBS2 and BBS6). We screened our cohort of 163 BBS families for mutations in both BBS2 and BBS6 and report the presence of three mutant alleles in affected individuals in four pedigrees. In addition, we detected unaffected individuals in two pedigrees who carry two BBS2 mutations but not a BBS6 mutation. We therefore propose that BBS may not be a single-gene recessive disease but a complex trait requiring three mutant alleles to manifest the phenotype. This triallelic model of disease transmission may be important in the study of both Mendelian and multifactorial disorders.     

A theropod dinosaur embryo and the affinities of the flaming cliffs dinosaur eggs

An embryonic skeleton of a nonavian theropod dinosaur was found preserved in an egg from Upper Cretaceous rocks in the Gobi Desert of Mongolia. Cranial features identify the embryo as a member of Oviraptoridae. Two embryo-sized skulls of dromaeosaurids, similar to that of Velociraptor, were also recovered in the nest. The eggshell microstructure is similar to that of ratite birds and is of a type common in the Djadokhta Formation at the Flaming Cliffs (Bayn Dzak). Discovery of a nest of such eggs at the Flaming Cliffs in 1923, beneath the Oviraptor philoceratops holotype, suggests that this dinosaur may have been a brooding adult.