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101.
Effect of cross-linking agent structure on the shape memory property of polyurethane block copolymer
Effect of cross-linking agent on the shape memory and mechanical property of polyurethane (PU) block copolymer is comprehensively
investigated. The selected chemical cross-linking agents are glycerol, 1,2,6-trihydroxyhexane, and 2,4,6-trihydroxybenzaldehyde
that are differentiated from each other in having remote hydroxyl group and aromatic ring. Significant increase in maximum
stress was observed for all of the cross-linked PUs, although the cross-linker structure was different. Structural change
of PU after cross-linking as evidenced by differential scanning calorimetry and infrared spectra was not detected, suggesting
that interaction between PU chains remained intact. Shape recovery went to as high as 95 % after cross-linking for all of
the cross-linking agents, and shape retention did not improve even if cross-linker was used. The remarkable increase in shape
recovery and maximum stress definitely originated from the employment of a cross-linking agent, and the effect of different
cross-linker structure on shape memory and mechanical property is discussed. 相似文献
102.
Yong Suk Chung Nicholas J. Goeser Xingkui Cai Shelley Jansky 《American Journal of Potato Research》2013,90(4):351-356
Bacterial soft rot is a serious disease in potato (Solanum tuberosum L.), causing rapid tuber tissue maceration and, consequently, marketable yield loss. Soft rot bacteria, including Pectobacterium carotovorum subsp. carotovorum (Pbc), are favored by moist conditions, which are prevalent in large potato storage facilities. However, although most potatoes in North America are stored before use, there are no published surveys of soft rot resistance in cultivars exposed to long-term storage conditions. Thus, we tested 65 cultivars and 13 breeding lines for soft rot resistance after 6 months of storage. There was a significant effect of cultivar and production environment on soft rot resistance score. During 6 months of storage, tuber soft rot resistance in resistant clones did not change, while it changed in susceptible clones. The three most resistant cultivars to soft rot were Freedom Russet, Anett, and Alaska Red Eye. 相似文献
103.
Yong-Chan Chung Jae Won Choi Young Jae Jung Samsook Han Byoung Chul Chun 《Fibers and Polymers》2013,14(12):2069-2076
Polyurethane (PU) copolymer is laterally linked with three kinds of metal ion indicator (calcein, calmagite, or eriochrome black T), with which free metal ion in aqueous solution is intended to be detected by PU color change. Metal ion detection by the indicator-PU fails due to the poor permeation of hydrophilic metal ion into hydrophobic PU layer. Instead, three surfactants with different ionic head groups, aerosol OT (AOT), cetyltrimethylammonium bromide (CTAB), and sodium dodecylsulfate (SDS), are tested for metal ion. Cationic CTAB exhibits an instant PU color change, but anionic AOT and SDS do not respond at all. Reason for the selective detection of cationic surfactant is the complex formation between cationic surfactant and indicator. Molecular interactions between PUs are affected by the laterally linked indicators based on the results by infrared spectra and differential thermal analysis. UV-vis spectra reveal that extra peak arising from the linked indicator appears compared to plain PU. The lateral linking of indicator to PU demonstrates, as well as the selective surfactant detection, a 454 % increase in tensile strength and reproducible shape recovery as high as 99 % compared to plain PU. 相似文献
104.
Chung Sarit Takeuchi Junichiro Fujihara Masayuki Oeurng Chantha 《Paddy and Water Environment》2019,17(2):255-263
Paddy and Water Environment - In Cambodia, rice production is important for the majority of rural populations as the main source of income. However, historical extreme flood events, especially the... 相似文献
105.
Electrospun web may possibly be widely applied to protective garments or specialty textiles due to its high level of protection
as well as comfort. Of particular interest in this study is to develop waterproof-breathable fabric by applying electrospun
web of polyurethane directly onto the substrate fabric. The optimal electrospinning condition was examined with regards to
the concentration, applied voltage and tip-to-collector distance. Solvent-electospinning of polyurethane was performed at
the optimum condition, using N,N-dimethylacetamide as solvent. The thickness of 0.02 mm of electrospun web was applied onto
the polyester/nylon blended fabric. For comparison, the polyester/nylon fabrics were coated with 0.02 mm thickness of polyurethane
resin membranes adopting four different conditions. The electrospun PU web/fabric was compared to resin coated fabrics in
terms of water-proof and breathable properties. The electrospun web applied fabric showed higher air permeability, vapor transmission,
and thermal insulation properties than resin coated fabrics, which can be translated as greater comfort sensation of electrospun
applied fabrics. However, water resistance value of electrospun web applied fabric did not reach that of resin coated fabrics. 相似文献
106.
Tae Keun Cho Mi Hwa Chong Byoung Chul Chun Hye Ran Kim Yong-Chan Chung 《Fibers and Polymers》2007,8(1):7-12
Polyurethane block copolymers chemically cross-linked by pentaerythritol, a four-way cross-linker, are tested for the shape
memory effect. One of the copolymers shows higher shape recovery than any other shape memory copolymer synthesized by us so
far. The copolymer maintains a surprising 94 % shape recovery after the third cyclic test. The four-way cross-linking by pentaerythritol
and interaction between hard segments are mainly responsible for the very high shape recovery. Tensile mechanical properties
also significantly improve by cross-linking. Glass transition temperature (T
g
) slightly increases with cross-linking content. Other characterization such molecular weight, IR, and X-ray diffraction is
also carried out to understand the arrangement of copolymer chains. 相似文献
107.
Lanza R Chung Y West MD Campbell KH 《Science (New York, N.Y.)》2003,301(5639):1482; author reply 1482
108.
Frank-Thorsten Krell Arthur Y.C. Chung Emma DeBoise Paul Eggleton Alessandro Giusti Kelly Inward Sylvia Krell-Westerwalbesloh 《Pedobiologia》2005,49(2):175-186
Winkler extractors, a simple device presumed to extract macro-invertebrates efficiently from soil and litter samples, is being used increasingly in ecological surveys and functional studies of soil macro-invertebrate communities. In this study the extraction efficiency and taxonomic bias of the Winkler extraction are evaluated for extraction periods of 3 h up to 7 weeks, calibrated by hand-sorting after 7 weeks. The method extracts most macro-invertebrates completely or to a proportion of over 90% except Isopoda, Diplopoda and Mollusca. However, for an exhaustive result, a long extraction period of several weeks is necessary. For the most speciose group (adult beetles) and for the commonly most abundant group (ants), a short extraction of 3 days was sufficient to get 70% of the individuals and nearly all species. Three days was also sufficient to recover the rank abundance order of beetle families, while for ‘higher taxa’ and for Chilopoda species, 4 and 3 weeks were necessary, respectively. Optimum extraction times for the abundant macro-invertebrate groups and possible adjustment factors for the soil macro-invertebrates of temperate woodlands are proposed to compensate the taxonomic bias caused by short extraction periods. However, for recording an accurate snapshot of the soil and litter fauna at a particular time, shorter extraction periods are advisable because of the short life cycle of many soil invertebrates causing emergence of later stages or a second generation during longer extraction periods. The problem of contamination of samples is also discussed. 相似文献
109.
Guidotti LG Rochford R Chung J Shapiro M Purcell R Chisari FV 《Science (New York, N.Y.)》1999,284(5415):825-829
Viral clearance during hepatitis B virus (HBV) infection has been thought to reflect the destruction of infected hepatocytes by CD8(+) T lymphocytes. However, in this study, HBV DNA was shown to largely disappear from the liver and the blood of acutely infected chimpanzees long before the peak of T cell infiltration and most of the liver disease. These results demonstrate that noncytopathic antiviral mechanisms contribute to viral clearance during acute viral hepatitis by purging HBV replicative intermediates from the cytoplasm and covalently closed circular viral DNA from the nucleus of infected cells. 相似文献
110.
Lopatto D Alvarez C Barnard D Chandrasekaran C Chung HM Du C Eckdahl T Goodman AL Hauser C Jones CJ Kopp OR Kuleck GA McNeil G Morris R Myka JL Nagengast A Overvoorde PJ Poet JL Reed K Regisford G Revie D Rosenwald A Saville K Shaw M Skuse GR Smith C Smith M Spratt M Stamm J Thompson JS Wilson BA Witkowski C Youngblom J Leung W Shaffer CD Buhler J Mardis E Elgin SC 《Science (New York, N.Y.)》2008,322(5902):684-685