Toxicity reduction of Ontario hydro radioactive liquid waste

The radioactive liquid waste (RLW) system in Ontario Hydro's pressurised heavy water reactors collects drainage from a variety of sources ranging from floor drains to laundry waste. RLW effluent was intermittently toxic to rainbow trout andDaphnia magna during the first phase of Ontario's Municipal Industrial Strategy for Abatement (MISA) Program, apparently as a result of the interaction of a variety of known and unknown organic and inorganic compounds. Accordingly, we employed a tmatment-based approach to reducing its toxicity, supplemented by chemical analysis. Two series of toxicity reduction tests were conducted. The fast series explored the potential for sorption of the possible toxicants, while the accord series incorporated a wider variety of treatments. Of the 24 samples in the first test series, 17 were toxic (D. magna mortality ≥ 50%). Of the toxic samples, only 7 of 17 were still toxic after passage through an activated carbon column, but 5 of 6 samples tested remained toxic after passage through a metal chelating resin column. In the second series, at least one of the treatments was effective in reducing toxicity of all samples which were initially toxic (16 of 24 samples), but no one treatment was effective for all toxic samples. Three treatments (UV/H₂O₂ photo-oxidation with prior pH adjustment, or passage through a column of either a non-functioalized (N-F) resin or a mixture of N-F resin and a weak base (W-B) anion exchange rain), were effective in reducing the toxicity of more than 50% of the toxic samples; yet roughly 25% of these samples remained toxic after treatment O₂ sparging, UV/H₂O₂ photo-oxidation without prior pH adjustment, and passage through a column of the W-B Resin were less effective, as more than 50% of the samples remained toxic after treatment. Filtering was not effective, as all of the treated samples (9/9) retained their toxicity. There was no obvious correspondence between toxicity and the concentrations of metals (Cu, Zn, Fe, Al and Cd) nor were any simple relationships apparent between toxicity and Total Organic Carbon or NH₃ concentrations. At stations where radioactive liquid wastes are segregated, toxicity was also segregated, suggesting that we may be able to address the problem at source through a combination of Best Management Practices and smaller scale treatment facilities.     

Effects of acidity in precipitation on terrestrial vegetation

Over the last several decades rain in the Northeastern United States has become more acidic presumably as a result of anthropogenic inputs of SO_x and NO_x to the atmosphere and their conversion to H₂SO₄ and HNO₃. Present experimental results suggest that acidic precipitation would initially affect organisms on leaf surfaces and epidermal cells of leaves of higher plants. More internal cell layers would be affected with increasing duration or frequency of exposure. Differences in responses of plant foliage among plant species to acidic precipitation appear to be due to the degree of leaf wetting and differences in responses of leaf cells to low pH rain. Moreover, within the same plant, particular structures or cell types may be more sensitive than others. If the United States is to utilize coal reserves for electric power generation that might increase rainfall acidity in the future, an assessment of the impact that acidic rain might have on terrestrial vegetation is necessary. In one experiment, field-grown soybeans were exposed to short duration rainfalls of either pH 4.0, 3.1, 2.7, or 2.3 to provide inputs of 50, 397, 998, or 2506 μeq of H⁺, respectively, above ambient levels throughout the growing season. Control plots received only ambient rainfalls. These additional H⁺ decreased seed yield, 2.6, 6.5, 11.4, and 9.5%, respectively. A treatment response function determined between H⁺ treatments and seed yield wasy=21.06?1.01 logx had a correlation coefficient of ?0.90. Researchers must design additional experiments with adequate experimental controls to assess the impact that acidic rain, at the present pH levels of 3.0 to 4.0 or at anticipated worst-case levels, that could occur if the acidity of rain should increase. Only a holistic view of the impacts that acid precipitation may have on vegetation will enable optimal energy and environmental policy decisions to be made.     

Vegetation Type Affects the Relationship Between Soil Carbon to Nitrogen Ratio and Nitrogen Leaching

Nitrate leaching occurs when the soil's nitrogen immobilisation and plant uptake capacity has been saturated. Several widely-used models of nitrogen saturation incorporate a breakthrough function in which N begins to be leached at C/N values below an upper threshold, and is completely leached at C/N values below a lower threshold. In a survey of deciduous and coniferous woodland, acid grassland and heathland sites for which both C/N and nitrate flux measurements were available, deciduous woodland and acid grassland typically had lower C/N ratios, and began leaching nitrate at a lower C/N ratio, than coniferous woodland and heathland. Least-square fits of nitrate breakthrough functions gave upper thresholds (no nitrate leaching) of 27 mol C mol^?1 N for deciduous woodland and acid grassland and 50 mol C mol^?1 N for coniferous woodland and heathland. Upper thresholds were similar, at 24 and 51 mol C mol^?1 N, respectively, for total inorganic N (NH₄ + NO₃) leaching flux as a proportion of total inorganic N influx. In conifer plantations, stand maturity had a large effect, suggesting that a breakthrough function is unsuitable for modelling systems that are in disequilibrium. However, there was sufficient evidence to suggest that using different breakthrough C/N thresholds for different groups of vegetation would improve predictions of N saturation and leaching at both plot and catchment scales. The difference may be related to the reactivity of soil carbon; soils with a large proportion of recalcitrant carbon are likely to begin leaching nitrate at a higher C/N value than soils with more labile carbon.     

Heavy and light beer: a carbon isotope approach to detect C(4) carbon in beers of different origins,styles, and prices

The carbon isotope ratios (delta(13)C) of 160 beers from around the world ranged from -27.3 to -14.9 per thousand, primarily due to variation in the percentage of C(3) or C(4) plant carbon in the final product. Thirty-one percent of beers had a carbon signature of C(3) plants (barley, rice, etc.), whereas the remaining 69% contained some C(3)-C(4) mixture (mean of mixtures, 39 +/- 11% C(4) carbon). Use of C(4) carbon (corn, cane sugar, etc.) was not confined to beers from any particular region (Pacific Rim, Mexico, Brazil, Europe, Canada, and the United States). However, the delta(13)C of European beers indicated mostly C(3) plant carbon. In contrast, U.S. and Canadian beers contained either only C(3) or C(3)-C(4) mixtures; Brazilian, Mexican, and Pacific Rim beers were mostly C(3)-C(4) mixtures. Among different lagers, U.S.-style lagers generally contained more C(4) carbon than did imported pilsners. Among different ales, those brewed by large high-production breweries contained significant proportions of C(4) carbon, while C(4) carbon was not detected in microbrewery or home-brew ales. Furthermore, inexpensive beers generally contained more C(4) carbon than expensive beers.     

Field-based research on elemental mercury spills

Natural gas industry sites have been contaminated in the past by elemental mercury (Hg) from gas flowmeter manometers. Flowmeters (metering stations) are located throughout the natural gas distribution system at wellheads, at gas processing plants, along gas transmission lines, at underground gas storage facilities, and at points of end use. Field site instrumentation has occurred at six field research sites located in natural gas production areas of the United States. These field research sites, located in Louisiana, Pennsylvania, and New Mexico, are representative of diverse climatic, geologic, and hydrologic conditions.In situ hydraulic conductivity measurements on these sites represent a range of 10^?4 to an estimated 10^?10 m/s. Mean annual precipitation ranges from near desert (extremely negative annual water budget) to subtropical (extremely positive annual water budget). Geologic materials found on the six sites include stratified alluvial clays, weathered bedrock, and coarse sands and gravels. Each of these sites has had documented spills of elemental Hg and has been instrumented with stainless steel monitoring wells, each of which has a dedicated stainless steel and Teflon sampling pump. These monitoring points have been sampled quarterly in an effort to develop fundamental information on the transport and fate of Hg in the shallow subsurface, under a range of climatic, geologic, and hydrologic conditions. Both field-filtered and unfiltered groundwater samples have been collected as part of the quarterly sampling effort to determine the potential role of colloid-borne Hg transport in shallow groundwater systems. Data collected from five consecutive quarterly sampling efforts at the New Mexico and Pennsylvania sites suggest that there has been no apparent adverse impact to shallow groundwater in the immediate vicinity of the research sites. A quarterly monitoring program is currently under way at the two Louisiana sites.     

Curtailment of muddy floods in the Sompting catchment, South Downs, West Sussex, southern England

Abstract. Muddy floods due to runoff are a widespread problem on the South Downs of southern England and are associated with increased growing of autumn-sown cereals over the last two decades. The 10.6 km² Sompting catchment has been monitored over the 12-year period 1990/91–2001/02. A housing estate at the lower end of the catchment that was frequently inundated by muddy floods in the late 1980s and early 1990s has not been flooded since the winter of 1993/94, even during the heavy rainfall events of October and November 2000. This is a result of the ameliorative measures put in place in the early 1990s, primarily the reversion of some winter cereal fields to permanent grassland (set-aside). Other land management changes helped, for example, some parts of the catchment were put down to short-term grass leys and small dams were constructed to impound runoff. Flooding of the housing estate occurred when more than 30% of the catchment was covered by eroded fields, which contributed runoff to the valley floors leading down to the housing estate. The length of continuous down-valley flow was greater in the early 1990s compared with later years. The introduction of grassland reduced the risk of flooding not only by reducing the area contributing to runoff, but also by stopping valley floor flows linking up. Such measures to alleviate runoff, erosion and flooding fit well with policies proposed in the recent report by the UK Policy Commission on the Future of Farming and Food.     

Statistical inference for calibration points in nonlinear mixed effects models

Many disciplines conduct studies in which the primary objectives depend on inference based on a nonlinear relationship between the treatment and response. In particular, interest often focuses on calibration—that is, estimating the best treatment level to achieve a particular result. Often, data for such calibration come from experiments with split-plots or other features that result in multiple error terms or other nontrivial error structures. One such example is the time-of-weed-removal study in weed science, designed to estimate the critical period of weed control. Calibration, or inverse prediction, is not a trivial problem with simple linear regression, and the complexities of experiments such as the time-of-weed-removal study further complicate the procedure. In this article, we extend existing calibration techniques to nonlinear mixed effects models, and illustrate the procedure using data from a time-of-weed-removal study.     

Effect of soil treatment with cereal straw and method of crop establishment on field pea (Pisum sativum L.) N2 fixation

The effects of soil incorporation with cereal straw (nil, 2.5, 5 and 10 t straw ha^–1) and direct drilling on the proportion and amount of pea N derived from biological N fixation were investigated in three field experiments. Fixed N was determined by¹⁵N dilution using barley as a reference plant. The three sites were on acidic, red clay-loams in the cropping zone of southeastern Australia. Seasonal plant available soil N, as determined by the N accumulated in barley, was 31, 56 and 158 kg N ha^–1, for the three sites. Incorporated straw reduced soil nitrate at sowing by 10–50 kg N ha^–1 (0–30 cm), and 5 or 10 t straw ha^–1 reduced barley uptake of N by 10–38 kg N ha^–1. However, reducing plant available soil N was generally ineffective for increasing the N fixed by pea. Fixed N increased only at the site with the least plant-available N, and only one-third of the increase could be attributed to lower soil N uptake by pea. There was no evidence that direct drilling pea increased fixed N by decreasing crop uptake of soil N. It is proposed that a lower requirement for soil N by pea as compared to barley, and availability of mineral N beneath the soil layer treated with straw, minimise the effectiveness of straw incorporation for increasing the N fixed by pea.     

Accuracy of canopy temperature energy balance for determining daily evapotranspiration

The application of a single-layer canopy temperature energy balance (CTEB) model for determining integrated daily ET rates was tested, with possible applications towards determining irrigation requirements (“how much to irrigate”) as a complement to crop water stress index (CWSI) measurements (“when to irrigate”), an irrigation scheduling tool which uses much of the same data. Evapotranspiration (ET) rates estimated using the CTEB model were compared to Bowen ratio energy balance (BREB) measurements made over substantial portions of the growing seasons of corn and potato crops. Canopy temperature, net radiation and soil heat flux data were collected and analyzed at 20-minute intervals, and ET for each interval was summed to obtain daily and multi-day estimations. Only full canopy conditions were examined. Two methods for atmospheric stability correction were applied to the aerodynamic resistance required by the CTEB model; an iterative procedure proposed by Campbell, and a second procedure proposed by Monteith which uses an adjustment coefficient. To reduce instrumentation requirements for combined CTEB/CWSI data collection, estimates of ET were also determined using net radiation and soil heat flux values estimated from solar radiation measurements. Results showed that uncorrected CTEB ET estimates agreed reasonably well with BREB measurements over corn and potato canopies (RMSE = 0.5 to 0.7 mm day⁻ for observed average ET ranging from 4.8 to 5.5 mm day⁻, with a trend toward seasonal overprediction with corn. Stability corrections usually lowered the daily RMSE 0.1 to 0.2 mm day⁻, with seasonal ET more in agreement with BREB ET. The Monteith-based adjustment gave slightly better results. CTEB ET model with estimated net radiation and soil heat flux terms produced similar average and total ET, but somewhat larger daily errors (RMSE=0.5 to 0.9 mm day⁻). Seasonal total ET by the uncorrected CTEB model generally overestimated within 10% (ranging from 1% to 10%) of the observed BREB total ET, an acceptable error for most irrigation practices. Stability corrections generally caused seasonal ET to be underestimated within 1% to 9%.