Speciation and calcium competition effects on cadmium sorption by sandy soil at various pHs

The effects of Ca competition, ionic strength, inorganic complexation and pH on cadmium adsorption by a sandy soil were studied. Sorption of Cd was measured using four different electrolytes CaCl₂, Ca(NO₃)₂, NaNO₃ and NaCl at a constant ionic strength (I) of 0.003 M at three different pHs, at variable Ca/Na ratio with a constant ionic strength of 0.03 and at variable ionic strengths between 0.003 and 0.3 M for two different pHs for Ca(NO₃)₂ and NaNO₃. The measured Cd sorption isotherms were non-linear. In the case of Cl as electrolyte anion, 13% of the Cd in solution is complexed at I= 0.003 (0.002 M Cl) and 91% of Cd is complexed at I= 0.3 (0.2 M Cl). If NO₃ is the anion, none of Cd is complexed at I= 0.003 and 11% at I= 0.3. The Cd complexes do not adsorb significantly. Calcium competition, at an ionic strength of 0.03, reduced the Cd adsorption by 60–80% compared with the case that Na is the cation. Increasing the ionic strength from 0.003 to 0.3 decreased Cd sorption by 60% for Ca(NO₃)₂ and 25% for NaNO₃ due to a decrease of the activity coefficient, increase of inorganic complexation and increase of Ca competition. A decrease of one pH unit reduces Cd sorption of about 75%. Sorption of Cd by soil could be described adequately with the three-species Freundlich (3SF) equation in which pH, complexation, Ca competition and ionic strength effects were taken into account.     

Saturn's Magnetosphere, Rings, and Inner Satellites

Our 31 August to 5 September 1979 observations together with those of the other Pioneer 11 investigators provide the first credible discovery of the magnetosphere of Saturn and many detailed characteristics thereof. In physical dimensions and energetic charged particle population, Saturn's magnetosphere is intermediate between those of Earth and Jupiter. In terms of planetary radii, the scale of Saturn's magnetosphere more nearly resembles that of Earth and there is much less inflation by entrapped plasma than in the case at Jupiter. The orbit of Titan lies in the outer fringes of the magnetosphere. Particle angular distributions on the inbound leg of the trajectory (sunward side) have a complex pattern but are everywhere consistent with a dipolar magnetic field approximately perpendicular to the planet's equator. On the outbound leg (dawnside) there are marked departures from this situation outside of 7 Saturn radii (Rs), suggesting an equatorial current sheet having both longitudinal and radial components. The particulate rings and inner satellites have a profound effect on the distribution of energetic particles. We find (i) clear absorption signatures of Dione and Mimas; (ii) a broad absorption region encompassing the orbital radii of Tethys and Enceladus but probably attributable, at least in part, to plasma physical effects; (iii) no evidence for Janus (1966 S 1) (S 10) at or near 2.66 Rs; (iv) a satellite of diameter greater, similar 170 kilometers at 2.534 R(s) (1979 S 2), probably the same object as that detected optically by Pioneer 11 (1979 S 1) and previously by groundbased telescopes (1966 S 2) (S 11); (v) a satellite of comparable diameter at 2.343 Rs (1979 S 5); (vi) confirmation of the F ring between 2.336 and 2.371 Rs; (vii) confirmation of the Pioneer division between 2.292 and 2.336 Rs; (viii) a suspected satellite at 2.82 Rs (1979 S 3); (ix) no clear evidence for the E ring though its influence may be obscured by stronger effects; and (x) the outer radius of the A ring at 2.292 Rs. Inside of 2.292 Rs there is a virtually total absence of magnetospheric particles and a marked reduction in cosmic-ray intensity. All distances are in units of the adopted equatorial radius of Saturn, 60,000 kilometers.     

Mount st. Helens ash from the 18 may 1980 eruption: chemical, physical, mineralogical, and biological properties

Samples of ash from the 18 May 1980 eruption of Mount St. Helens were collected from several locations in eastern Washington and Montana. The ash was subjected to a variety of analyses to determine its chemical, physical, mineralogical, and biological characteristics. Chemically, the ash samples were of dacitic composition. Particle size data showed bimodal distributions and differed considerably with location. However, all samples contained comparable amounts of particles less than 3.5 micrometers in diameter (respirable fraction). Mineralogically, the samples ranged from almost totally glassy to almost totally crystalline. Crystalline samples were dominated by plagioclase feldspar (andesine) and orthopyroxene (hypersthene), with smaller amounts of titanomagnetite and hornblende. All but one of the samples contained from less than 1 percent to 3 percent free crystalline silica (quartz, trydimite, or cristobalite) in both the bulk samples and 1 to 2 percent in the fractions smaller than 3.5 micrometers. The long-lived natural radionuclide content of the ash was comparable to that of crustal material; however, relatively large concentrations of short-lived radon daughters were present and polonium-210 content was inversely correlated with particle size. In vitro biological tests showed the ash to be nontoxic to alveolar macrophages, which are an important part of the lungs' natural clearance mechanism. On the basis of a substantial body of data that has shown a correlation between macrophage cytotoxicity and fibrogenicity of minerals, the ash is not predicted to be highly fibrogenic.     

An Explanation of the Liesegang Phenomenon

Periodic band precipitation in porous media is explained by means of the Hirsch effect (specific semipermeability of the precipitate occurring only as long as both the precipitate-forming ions are present). The possibility of getting Liesegang bands in immunological precipitates is underlined, and a suggestion is made how to avoid them.     

一种测定土壤水分迁移率的方法研究

A new laboratory method was proposed to establish an easily performed standard for the determination of mobile soil water close to real conditions during the infiltration and redistribution of water in a soil. It consisted of applying a water volume with a tracer ion on top of an undisturbed ring sample on a pressure plate under a known suction or pressure head. Afterwards, soil water mobility was determined by analyzing the tracer-ion concentration in the soil sample. Soil water mobility showed to be a function of the applied water volume. No relation between soil water mobility and applied pressure head could be established with data from the present cxperiment. A simple one- or two-parameter equation can be fitted to the experimental data to parameterize soil water mobility as a function of applied solute volume. Sandy soils showed higher mobility than loamy＂ soils at low values of applied solute volumes, and both sandy and loamy soils showed an almost complete mobility at high applied solute volumes.