Opportunities for chiral agrochemicals

Chiral compounds account for 25% of all agrochemical compounds used commercially and for 26% of the total value of the world agrochemical market. However, those sold in single isomer form contribute only 7% to the market value despite many potential advantages in terms of regulatory, intellectual property and marketing benefits. Limited access to chiral raw materials and economic synthesis routes are key reasons why single isomers are less common than they might be. The development of more chiral routes will encourage the development of single isomer compounds to capitalise on their advantages.     

Hybridisation in kiwi (Apteryx; Apterygidae) requires taxonomic revision for the Great Spotted Kiwi

Background: Kiwi (Apteryx spp.) are flightless ratites from New Zealand whose numbers and distributions have declined following human arrival. Some of the kiwi ...     

INTEGRATED CROP-LIVESTOCK SYSTEMS: LESSONS FROM NEW YORK,BRITISH COLUMBIA,AND THE SOUTH-EASTERN UNITED STATES

• Livestock production in North America has moved to fewer farms with greater inventories • Land application of livestock manures is a preferred nutrient recycling strategy • Confined animal feeding operations have challenges to utilize livestock manure sustainably • Integration of livestock and cropping systems is possible on a farm or among farms • Nutrient balance is needed for environmental sustainability Livestock production in the United States (US) and Canada is diverse, but shows a common trend in most livestock sectors toward fewer farms producing the majority of animal products despite a large number of farms still small in production scale. The migration to larger and more concentrated animal feeding operations in beef finishing and poultry, swine, and dairy production allows processors to streamline supplies to meet market demand for abundant, low-cost livestock products, whether that be for packaged meat, dairy products, or eggs. With concentration of livestock operations comes the challenge of managing manures. When sufficient land is available and nutrients are needed, livestock manure is an excellent nutrient source and land application is the preferred method of recycling this resource. However, when livestock production is constrained in a geographical area and animal densities are high, manure may become an environmental liability with potentially greater risk for runoff and leaching of nutrients, emission of odors, ammonia, and greenhouse gases, and release to the environment of pathogens and chemicals of emerging concern. Addressing these challenges now and into the future requires learning from mistakes and adopting successful approaches. We describe different levels of integration between livestock and crop producers in New York, British Columbia, and the south-eastern US as learning opportunities to improve economic and environmental sustainability. Examples show that effective solutions should recognize (1) manure has value and is not just a cost, (2) farmers, farm advisors, extension educators, nutrient management planners, crop advisors, nutritionists, state agency personnel, regulators, and university researchers need to be active participants in development of solutions, and (3) change to a sustainable future requires a combination of government regulation and outcome-based incentives.     

Thirty years of change and the future of Alaskan fisheries: Shifts in fishing participation and diversification in response to environmental,regulatory and economic pressures

Heterogeneity in human responses and decision‐making can contribute to the resilience of social–ecological systems in the face of environmental, political and economic pressures. In fishery systems worldwide, the ability of harvesters to maintain a diverse portfolio of fishing strategies is important for building adaptive capacity. We used a case‐study approach to examine the complexity of factors that inhibit or promote diversification in fisheries of Alaska, one of the major fishing regions of the world. Through a combination of harvest records and literature review, we explored shifts in participation and portfolio diversity in Alaskan fisheries over three decades. The four case‐studies examined the responses of fishers, fleets and communities to multiple, intersecting pressures, including biological declines, market and price dynamics, fishery privatization and the 1989 Exxon Valdez oil spill. These cases illustrate how stressors acting at multiple scales can encourage or constrain opportunities for diversification, and that these opportunities may be spread inequitably across participants. Overall, we found evidence for reduced participation and increasing specialization in Alaskan commercial fisheries. While numerous factors explain these trends, policies like individual quota systems and the increasing cost of entry into fisheries are forcing consolidation at local to regional scales. A portfolio approach to managing fisheries that reduces barriers to diversification and includes broad representation of resource users and communities in management may help to maintain opportunity and choice for fishers.     

Crop structure in winter oats and the effect of nitrogen on quality-related characters

The relationship between panicle structure and oat grain quality characteristics was examined in a winter oat (Avena sativa) experiment, cv. Gerald, fertilized with 80 and 200 kg/ha N. Spikelets on each whorl were counted and separated into primary, secondary, and tertiary grains, which were counted and weighed, and the kernels extracted manually and weighed. Tiller and whorl rank had relatively small effects on weight per grain and kernel content. Nitrogen application significantly increased weight per primary and secondary grain on the main stem and T1, the first tiller, while spikelet and grain numbers increased only on T1. However, weight per grain and kernel contents in all whorls on both the main stem and T1 were not significantly affected by nitrogen. Although kernel contents were significantly affected by nitrogen application on some occasions, increases and decreases were less than 2.5%. Across the whole plant, numbers of primary and secondary grains increased at the higher nitrogen application, but weight per primary grain and kernel contents were unaffected. However, weight per secondary grain significantly increased at the higher nitrogen application, thus improving uniformity of grain size which is of value to millers.     

Simulation Model for Composting Cellulosic (Bagasse) Substrates

A dynamic model of aerobic composting with solid substrates was developed as a first step to predict the rate of decomposition of cellulosic materials. The model was based on heat and mass transfer principles and reaction kinetics of biological processes. The relations describing the rates of reaction and the degradability potential of the substrates were determined based on laboratory-scale experiments. The model was developed using a graphical software package, Stella II® (which was able to solve feedback loops encountered in actual composting processes.

The model was validated with temperature, oxygen distribution and mass degradation accompanying the composting of bagasse. Experimental setups consisted of 30 gallon drum reactors, continuously aerated. Temperature and oxygen in exhaust gases were monitored on an hourly basis and measurements of moisture content, pH and volatile solids were done on a weekly basis.

The data fit with the model was excellent for mass degraded and temperatures for the first 10 days. From day 10 to 14, the deviations between model predictions (as solved with Stella II®) and actual measurements did not exceed 2.6 percent. The concentrations of oxygen in outlet gases showed fair agreement between predicted and experimental values. Simulating the model with varying airflow rates showed that the maximum mass breakdown rates occurred for airflow rates of 0.12 kg dry air/(kg dry compost.hr) while maintaining the temperatures below 50°C, through a temperature feedback control strategy.     

Maintaining Genetic Resources of Peach Palm (<Emphasis Type="Italic">Bactris gasipaes</Emphasis> Kunth): The Role of Seed Migration and Swidden-fallow Management in Northeastern Peru

Knowledge of the effects of farmer practices on population genetic parameters of peach palm (Bactris gasipaes Kunth) is relevant to the improvement and conservation of the palm’s genetic resources. Microsatellite markers were used to assess genetic diversity and population structure of peach palm in swidden-fallow agroforestry systems in northeastern Peru. The study covered eight communities, comprising two study areas 160 km apart – one occupied by indigenous Amerindians and the other by mixed race campesinos. Simultaneous analysis of an ex situ peach palm germplasm collection provided a means to compare population genetic parameters. Farmers who were surveyed on seed selection practices for peach palm reported that an average of only four palms (4.3 for campesino and 1.5 for indigenous populations) were used to provide seed for the establishment of the forest gardens sampled. As expected, inbreeding coefficients observed within communities were relatively high (f = 0.105 − 0.210), however, observed heterozygosities within communities were also high (0.625–0.741). A metapopulation approach was used to describe migration within and among regions, implying a hierarchical structure of gene flow which maintains relatively high levels of genetic diversity. Seed migration was found to occur over longer distances (≤600 km) and at a higher frequency (46% of palms sampled) in the indigenous study area, and a proportionally greater number of alleles was found (49 vs. 43 over three loci) with twice as many private alleles occurring only in the indigenous populations. The farmers’ practice of preserving remnant palms through successive swidden generations may have contributed to the maintenance of alleles by reducing the severity of founder effects. Although the campesino study area exhibited a significant (20% of the variation; p < 0.01) isolation-by-distance relationship across 35 km distance, in general, both study populations had relatively limited genetic structure (θ = 0.012–0.03), which is believed to have resulted from the exchange of seeds over long distances and periods of time.     

Intensification of New Zealand beef farming systems

This study used whole-farm management, nutrient budgeting/greenhouse gas (GHG) emissions and feed formulation computer tools to determine the production, environmental and financial implications of intensifying the beef production of typical New Zealand (NZ) sheep and beef farming systems. Two methods of intensification, feeding maize silage (MS) or applying nitrogen (N) fertiliser, were implemented on two farm types differing in the proportions of cultivatable land to hill land (25% vs. 75% hill). In addition, the consequences of intensification by incorporating a beef feedlot (FL) into each of the farm types were also examined.Feeding MS or applying N fertiliser substantially increased the amount of beef produced per ha. Intensifying production was also associated with increased total N leaching and GHG emissions although there were differences between the methods of intensification. Feeding MS resulted in lower environmental impacts than applying N even after taking into account the land to grow the maize for silage. Based on 2007/08 prices, typical NZ sheep and beef farms were making a financial loss and neither method of intensification increased profitability with the exception of small annual applications of N, especially to the 75% hill farm. These small annual additions of N fertiliser (<50 kg N/ha/yr applied in autumn and late winter) resulted in only small increases in annual N leaching (from 11 to 14 kg N/ha) and GHG emissions (from 3280 to 4000 kg CO₂ equivalents/ha). Limited N applications were particularly beneficial to 75% hill farms because small increases in winter carrying capacity resulted in relatively large increases in the utilisation of pasture growth during spring and summer than the 25% hill farms. Intensification by incorporating a beef feedlot reduced environmental emissions per kg of beef produced but considerably decreased profitability due to higher capital, depreciation and labour costs. The lower land-use capability farm type (75% hill) was able to intensify beef production to a proportionally greater extent than the higher land-use capability farm (25% hill) because of greater potential to increase pasture utilisation associated with a lower initial farming intensity and inherent constraints in the pattern of pasture supply.