Towards sustainable rural landscapes? a multivariate analysis of the structure of traditional tree cropping systems along a human pressure gradient in a mediterranean region

The worldwide increase of human pressure in rural areas has resulted in a progressive fragmentation of agro-forest landscapes. Relatively few studies have identified processes of landscape modification and patch fragmentation reflecting long-term human activity from those caused by recent urbanization stimulated by economic development, population growth and improved accessibility of rural areas. In rural districts dominated by high-quality crop mosaics and exposed to increasing levels of human pressure, urbanization-driven changes in the use of land have determined complex and non-linear processes of landscape fragmentation which deserve further investigation. Multidimensional procedures and data mining are appropriate to explore such transformations, basing on a comprehensive assessment of landscape metrics. The present study investigates changes in land-use and landscape structure (2000–2008) in three districts of Latium (central Italy) featuring different cropping systems, physiographic attributes and level of human pressure. A principal component analysis was run to identify a core set of metrics aimed at (i) evaluating the role of traditional cropping systems in the preservation of traditional agro-forest systems and (ii) inferring the relationship between spatial heterogeneity in rural landscapes and socio-ecological processes of change. Our results indicate that crop intensification has contributed to landscape homogeneity and simplification in all areas studied, in contrast with the effects of urban expansion resulting in a more fragmented and diversified landscape with relict tree crop patches. The findings of this study clarify the contribution of traditional tree crop systems to sustainable structures and functions of rural landscapes by preserving the place-specific eco-mosaic complexity.     

Connection of Isolated Stereoclusters by Combining 13C-RCSA,RDC, and J-Based Configurational Analyses and Structural Revision of a Tetraprenyltoluquinol Chromane Meroterpenoid from Sargassum muticum

The seaweed Sargassum muticum, collected on the southern coast of Galicia, yielded a tetraprenyltoluquinol chromane meroditerpene compound known as 1b, whose structure is revised. The relative configuration of 1b was determined by J-based configurational methodology combined with an iJ/DP4 statistical analysis and further confirmed by measuring two anisotropic properties: carbon residual chemical shift anisotropies (¹³C-RCSAs) and one-bond ¹H-¹³C residual dipolar couplings (¹D_CH-RDCs). The absolute configuration of 1b was deduced by ECD/OR/TD-DFT methods and established as 3R,7S,11R.