Effects of heat treatment on brittleness of <Emphasis Type="Italic">Styrax tonkinensis</Emphasis> wood

A new approach is proposed for the evaluation of the brittleness of heat-treated Styrax tonkinensis wood. Heat treatment made wood more brittle when wood was heated at a higher temperature or for a longer time. The brittleness increased to four times that of the control when wood was heated at 200°C for 12 h. For treatment at 160°C, the increase in brittleness without any change in weight is thought to be possibly caused by the relocation of lignin molecules. At higher temperatures, loss of amorphous polysaccharides due to degradation is thought to become the main factor affecting brittleness. The crystallites that were newly formed after 2 h of treatment showed brittleness that was different from that of the inherent crystallites remaining after 12 h of heat treatment. This inherent crystalline cellulose possibly plays a role in brittleness. There is also the possibility of using color to predict the brittleness of heat-treated wood.     

Ecophysiological and genetic variation in seedling traits and in first-year field performance of eight <Emphasis Type="Italic">Acacia senegal</Emphasis> provenances in the Blue Nile,Sudan

The genetic variation in seed weight, seed number per kg and seedling traits was compared among eight Acacia senegal provenances originating from the clay plain (east) and sand plains (west) of the gum belt in Sudan. The main objective of this study was to identify germplasm sources of A. senegal that have a good seed germination capacity and seedling traits suitable for reforestation in the clay-soil part of the dryland gum belt in the Blue Nile region in Sudan. A specific objective was to tentatively explore the adaptive strategy of A. senegal populations. Seventeen-week-old seedlings were planted in the field at spacing of 3 m × 3 m, giving 100 trees per plot and replication; within a randomized complete block design with four replications. The experimental site was in the clay plain region. Seed variables showed significant differences. Clay plain provenances showed considerable variation in seed weight and seed number. They had the smallest seed weight but the highest seed number, while the sand (western) provenances had the largest seed weight but lowest seed number. Seedling branch number, root length, root to shoot ratio and shoot dry weight differed significantly among the provenances 12 weeks after germination. Clay provenances had the highest branch number and shoot dry weight but the shortest roots and lowest root to shoot ratio. This was interpreted as showing better adaptation to the site in these local provenances in comparison to those originating from the western sandy soil regions. High positive correlations were observed between seedling variables, such as root nodule and branch numbers; this could be used for early selection. The variation was greater between provenance groups than within them, suggesting that especially selection among groups would yield genetic gain.     

Influence of different forest conversion strategies on ground vegetation and tree regeneration in pine (<Emphasis Type="Italic">Pinus sylvestris</Emphasis> L.) stands: a case study in NE Germany

The conversion of anthropogenic into more natural, self-regenerating forests is one of the major objectives of forestry throughout Europe. In this study, we present investigations on permanent plots with different silvicultural treatment in NE German pine stands. Management of old-growth pine stands on acidic and nutrient-poor sandy sites differs in fencing, thinning, and planting of certain tree species. The investigations were carried out on the community, population, and individual level of the pine forest ecosystems. Thus, vegetation changes, size and height of tree populations, and height increment of tree individuals were observed over a time span of 6 years. Special attention was paid to short-lived tree species such as, e.g., Frangula alnus and Sorbus aucuparia, as well as to Fagus sylvatica as one of the most typical forest tree species of Central Europe. Vegetation changes are interpreted as a consequence of natural regeneration of formerly degraded forest sites, involving an increase in nutrient availability. High browsing pressure can be considered as a key factor for the inhibition of tree seedlings and growth of saplings. Some Sorbus aucuparia individuals, however, succeeded in growing out of the browsing height also in unfenced stands. Few found specimens of Fagus sylvatica proved that this species is able to establish spontaneously on these relatively dry, acidic sites under continental climate influence. Such natural regeneration processes, also including spontaneous rejuvenation of trees, can be integrated into silviculture as passive forest conversion management. An active management like thinning of stands, planting of trees, and fencing can accelerate forest conversion with regard to height growth and species number of trees.     

Nickel-catalyzed carbonization of wood for coproduction of functional carbon and fluid fuels I: production of crystallized mesoporous carbon

Japanese larch wood loaded with nickel (1%–4%) alone or with nickel and calcium (0.25%–1.5%) was carbonized at 800°–900°C for 0–120min with a heating rate of 5°–20°C min⁻¹ in a helium flow of 5.8−46.4 ml STP cm⁻² min⁻¹ to examine the influence of these variables on the crystallization of carbon (the formation of T component) and the development of mesoporosity. From the obtained results, reaction conditions suitable for effective production of carbon with the dual functions of adequate electroconductivity and adsorption capacity in liquid phase were established, thereby explaining the factors that govern the process. It was also confirmed that mesopore having a diameter of about 4 nm was selectively produced at the cost of specific (BET) surface area in parallel with the formation of T component. This result provided good insight into how the simultaneous dual function could be realized.     

Chemical analysis of the product in acid-catalyzed solvolysis of cellulose using polyethylene glycol and ethylene carbonate

Degradation and decomposition of cellulose were studied in an acid-catalyzed solvolysis treatment of biomass using polyethylene glycol (PEG) and ethylene carbonate (EC). The solvolysis reaction was followed by a typical reaction system of wood liquefaction that uses sulfuric acid catalyst at 140° or 150°C at atmospheric pressure. The methods of fractionation and chemical analysis of the degraded cellulose in the solvolyzed product are discussed. The solvolyzed product was separated into several fractions, and they were hydrolyzed to release glucose and levulinic acid to determine the quantity of glucosides and levulinates in the solvolysis product. The data clearly showed that the solvolysis reaction had the same mechanism when using PEG or EC. Degradation of cellulose leads to the formation of glucosides, which then decompose, resulting in a levulinic acid structure, and producing a water-insoluble fraction. The conversion rates of both glucosides and levulinates strongly depend on the reaction conditions of the solvolysis. In particular, EC promotes faster conversion of the reactions. The method discussed here is a chemical analytical technique for characterization of the products of wood liquefaction.     

Mechanical properties of wood in an unstable state due to temperature changes,and analysis of the relevant mechanism IV: effect of chemical components on destabilization of wood

In order to investigate the effects of chemical components and matrix structure on the destabilization of quenched wood, we examined the physical and mechanical properties of steam-treated wood, hemicellulose-extracted wood, and delignified wood, which were treated at different levels. For steam-treated and hemicellulose-extracted wood,the relative relaxation modulus of the quenched sample was lower than that of the respective control sample. For delignified wood, the relative relaxation modulus fell with weight loss and reached a minimum value at a certain weight loss, and subsequently increased significantly. The hygroscopicity of all treated samples changed slightly by steaming, whereas increased with removing the component. More-over, the average volumetric swelling per 1% MC at 100% relative humidity (RH) was less than at 75% RH and 93% RH for component-removed wood. It was clear that a void structure existed. As a result, the destabilization evaluated by the fluidity (1 - E _t/E ₀) of steam-treated wood was influenced by the amount of adsorbed water. For component-removed wood, destabilization increased temporarily at lower weight loss because of nonuniform cohesive structure. At high weight loss, destabilization will decreased because capillary-condensed water gathered in the voids and obstructed the motion of adsorbed water. However, the destabilization of all treated wood changed less than that of chemically modified wood.     

Differences in spectral trajectory with stand volume development between Japanese larch and Japanese oak in Hokkaido,Japan

Our objective was to investigate the differences in the spectral trajectory of the LANDSAT Thematic Mapper with stand volume development between Japanese larch (Larix kaempferi) and Japanese oak (Quercus mongolica var. crispula) in the experimental forest of Kyushu University, Hokkaido, Japan. We used nonlinear regression and a categorical variable to investigate the relationship between spectral reflectance factor and stand volume for each forest type. This research showed that the reflectance factor of Japanese larch and Japanese oak reached saturation and that both forest types had different spectral trajectories with stand development. In addition, we found that middle of development stage (stand volume was between 100 and 200 m³/ha) of each forest type had similarity in reflectance factor.     

Characterization of proanthocyanidin in hot water extract isolated from <Emphasis Type="Italic">Pinus radiata</Emphasis> bark

Proanthocyanidins (PAs) in the hot water extract prepared from Pinus radiata bark were isolated by a Sephadex LH-20 chromatography. The PAs were characterized using UV/Visible, FT-IR and ¹³C nuclear magnetic resonance (NMR) spectroscopic techniques, matrix-assisted laser desorption/ionization time of flight (MALDI-TOF) mass spectrometry (MS), and gel permeation chromatography (GPC) analysis. Bate-Smith acidic alcoholysis and FT-IR spectrum of the PAs indicated the predominant presence of the procyanidin (PC) structure. The ¹³C NMR spectrum revealed that the PAs comprise PC (94%) together with a small amount of prodelphinidin (PD, 6%), and also that they contain the higher trans configuration rather than the cis configuration of C2–C3. The MALDI-TOF MS results obviously proved the presence of PD units, but the maximum degree of polymerization (DP) was limited to octamer. The average molar mass (Mw, Mn), polydispersity (Mw/Mn), and DP of the pine bark PAs were 3,800 (Mw), 1,200 (Mn), 3.2, and 13, respectively.     

PEG bulking of wood cell walls as affected by moisture content and nature of solvent

Movement of polyethylene glycol (PEG) 1000 from wood cell lumens into adjacent cell walls was studied for different cell wall moisture contents (MCs) and PEG solvents; relative amounts of PEG that penetrated into the cell walls were estimated by Raman microscopy. It was shown that samples treated with PEG from chloroform solution adsorb less PEG than samples treated with PEG-water solution even in the case of samples with open cell wall structure near fibre saturation point MC. Reconditioning of PEG-chloroform treated samples at high relative humidities enhanced PEG bulking of cell walls, but not to the maximum amounts observed with PEG-water treatments. Raman microscopy was a useful tool for estimating relative PEG amounts in the cell walls.     

Contamination and browning in tissue culture of Platanus occidentalis L.

Twigs of 2–3-year-old Platanus occidentalis L. were used as experimental material to find the causes for the contamination and browning in the initial stages of tissue cultures. To compare the degree of browning of explants picked off from different growing seasons, the experimental material was excised from trees on each of the first ten days in January, March, May and July, 2006. The results indicated that the contamination and browning rates of the material cut off in January (14.2% and 30.6%, respectively) and March were somewhat lower than those in July. The pretreatment of soaking the explants in different anti-oxidants and absorbents at the same time could diminish some side effects. The pretreatment of using 10 g·L–1 vitamin C reduced the contamination and brown-ing rate effectively. An orthogonal experiment showed that the optimal factor and level arrangement is 0.5 mg·L–1 BA, 2.0 g·L–1 ac-tive carbon and 1.5 g·L–1 PVP which resulted in a browning rate of only 16.5%. In general, sampling period, physical properties and pretreatment of explants are the main factors responsible for the contamination and browning of material in the initial stages of P. occidentalis tissue cultures.