Buckminsterfullerane: the inside story

The stereoisomers of fully reduced buckminsterfullerene C(60)H(60) have been investigated with the molecular mechanics program MM3. Although it might be expected that chemical reduction would deliver all of the hydrogens to the outside, the symmetric structure produced in this way is predicted to be highly strained. Moving just one hydrogen to the inside is predicted to decrease the energy by 53 kilocalories (kcal) per mole. Putting additional hydrogens on the inside further lowers the predicted energy (depending on the steric relations between them). The miniimum energy isomer is predicted to have ten hydrogens inside with C(1) symmetry and to have an energy 400 kcal/mol less than that of the all-outside isomer. These results suggest that a process which could achieve isomerization would produce a mixture of isomers, most of which with ten hydrogens on the inside.     

Equatorial X-ray Emissions: Implications for Jupiter's High Exospheric Temperatures

Observations with the High Resolution Imager on the Rontgensatellit reveal x-ray emissions from Jupiter's equatorial latitudes. The observed emissions probably result from the precipitation of energetic (>300 kiloelectron volts per atomic mass unit) sulfur and oxygen ions out of Jupiter's inner radiation belt. Model calculations of the energy deposition by such heavy ion precipitation and of the resulting atmospheric heating rates indicate that this energy source can contribute to the high exospheric temperatures(>800 kelvin at 0.01 microbar) measured by the Galileo probe's Atmospheric Structure Instrument. Low-latitude energetic particle precipitation must therefore be considered, in addition to other proposed mechanisms such as gravity waves and soft electron precipitation, as an important source of heat for Jupiter's thermosphere.     

A major food web component in the orinoco river channel: evidence from planktivorous electric fishes

Deep-water sampling of the Orinoco River main channel resulted in the collection of an unexpectedly high abundance and diversity of specialized fishes. Twenty-eight of the more than 60 species collected belong to the Gymnotiformes(New World electric or knife fishes). One of the more numerous of these, a recently described species of the genus Rhabdolichops, consumes large numbers of very small planktonic Crustacea and insect larvae. These items are captured in the very swift, turbid, and deep waters of the Orinoco. Although the strong dependence of the river food web on terrestrial and floodplain food sources is well known, the specialized capabilities of Rhabdolichops and of other fishes that occur with it indicate a significant extension of the river food web into the main channel.     

Evidence for highly reflecting materials on the surface and subsurface of vensus

Radar images at a 12.5-centimeter wavelength made with the Goldstone radar interferometer in 1980 and 1986, together with lunar radar images and recent Venera 15 and 16 data, indicate that material on the surface and subsurface of Venus has a Fresnel reflectivity in excess of 50 percent. Such high reflectivities have been reported on the surface in mountainous regions. Material of high reflectivity may also underlie lower reflectivity surficial materials of the plains regions, where it has been excavated by impact cratering in some areas.     

Human taste papilla stimulation: stability of quality judgments over time

Human taste papillae are sensitive to two or more chemical stimuli. Individual papillae produce stable response patterns (quality and intensity) over a month's time. Hence, the response pattern does not appear to be affected by turnover of receptor cells.     

Key considerations in the approach to congenital heart disease in dogs and cats

Congenital heart disease is an important subset of all cardiovascular disease in dogs and cats that is present at birth and most often detected in young animals but can be diagnosed in adulthood. The range of abnormalities that can occur during development of the heart is vast incorporating simple and complex defects, varying degrees of severity and clinical presentations that include heart failure and cyanosis. While some defects do not result in morbidity in an individual animal, others cause severe clinical signs and death at a young age. Advances in imaging and expanding treatment options offer increasingly more possibilities in the diagnosis and management of congenital heart disease which is the focus of this review. The objective is to provide a broad overview of current practice and highlight key aspects to guide practitioners in their approach to congenital heart disease diagnosis and knowledge of available treatment options.     

A comparison of genetic relationship measures in strawberry (Fragaria × ananassa Duch.) based on AFLPs, RAPDs, and pedigree data

Nineteen of the major strawberry (Fragaria × ananassa Duch.) cultivars grown in the UnitedStates and Canada were examined for AFLP markerpolymorphisms. For the AFLP reactions, the EcoRI-ACC primer was used in combination with fourMseI primers (MseI-CAC, MseI-CAG,MseI-CAT, or MseI-CTT). Each set ofprimers produced 46–66 scorable fragments ranging insize between 50 and 500 bp. The polymorphic fragmentsproduced from each set of primers were more thansufficient to distinguish among all the cultivars,demonstrating the usefulness of AFLP markers forcultivar identification. Similarity coefficients werecalculated based on data from 228 AFLP markers anddata from 15 previously characterized RAPD markers. The RAPD markers had been specifically selected forfingerprinting purposes because they succesfullydistinguish 41 strawberry cultivars, including the 19cultivars analyzed in this study. Separatedendrograms were constructed based on analysis of theAFLP and RAPD marker data using a neighbor-joiningalgorithm. The dendrograms were compared and found tobe very different. Correlations between similaritycoefficients calculated from AFLP marker data,similarity coefficients calculated from RAPD markerdata, and coefficients of coancestry calculated frompedigree information were evaluated. Interestingly,a better correlation with the coefficients ofcoancestry was observed with the RAPD marker data thanwith the AFLP marker data.