Substituting urea by organic wastes for improving maize yield in alkaline soil

Abstract

Nitrogen (N) deficiency is a very common problem of alkaline soils. Incorporation of organic residues with urea could be promising practice for improving soil properties and crop yield. This study was aimed, to evaluate the responses of two maize cultivar (Azam and Jalal) to organic wastes and Urea (sole organic residues i.e. seed cake (SC), poultry manure (PM), press mud (PrM) and mineral nitrogen (urea) and their combinations with urea (25%, 50% or 75%) applied at 150?kg N ha^?1 under field conditions. Significant differences were recorded for leaf area index, plant height, number of grains ear^?1, 1000 grain weight, biological and grain yield to N sources. Maize cultivar Jalal performed significantly better than Azam for all tested traits. The performance of both cultivars was significantly better when N was applied as either SC/PM with urea at 25:75, SC and PM with urea at 25:25:50, 100% sole urea, SC/PrM with urea at 50:50, or all organic N sources (25%) with urea (75%). Integration of organic wastes with urea gave the higher maize yield however, it was similar to the yield obtained from sole urea but due to allied environmental and health hazards, the sole use of urea could not be encouraged.     

Impact of urea and farm yard manure on nitrate concentration in soil profile and productivity of wheat crop

Abstract

During the last century, concerns about nitrate presence in the groundwater have tremendously increased worldwide, mainly because of its detrimental consequences on environment and human health. There are different factors contributing their past in nitrate pollution, farm manure is given due consideration. Knowing above facts, a field study was performed to check the effect of different farm yard manure (FYM) levels with urea on nitrate distribution in the soil profile and yield of wheat crop. The experiment was set out in a randomized complete block design, consisted of application of nitrogen at 125?kg ha^?1 from urea, 80?kg ha^?1 of N from urea +10 tons FYM ha^?1 and 20 tons FYM ha^?1 with three replications. Wheat (cultivar S7ehar-2006) was sown as test crop. Soil samples were examined to measure the nitrate concentration from four different depths (0–25, 25–50, 50–75, and 75–100?cm) after harvesting. Results showed that the straw yield, total biomass, spike length, and number of grains per spike and 1000-grain weight were significantly influenced by fertilizer strategies. All manure treatments significantly affected the infiltration rate and concentration of nitrate at different depths of the soil profile. Farm yard manure showed greater nitrate concentration up to 50?cm depth as compared to alone urea and combined application, while at the depth of 100?cm, combined application of urea and FYM showed a minimum concentration of nitrates than alone application of either urea or FYM.     

Silicon biostimulant enhances the growth characteristics and fortifies the bioactive compounds in common and Tartary buckwheat plant

Journal of Crop Science and Biotechnology - Silicon is a potential biostimulant that has been used to enhance the yield and quality of plant products. Therefore, we aimed to evaluate the effect of...     

Kinetics and Energetics of Azo Dye Decolorization by Pycnoporus sanguineus

Trypan Blue, an azo dye, was decolorized using the self-immobilizing fungal biomass of Pycnoporus sanguineus. The extent and the rate of dye decolorization were directly proportional to the initial dye concentration (20–60 mg L^?1) and the reaction temperature (25–45°C). Mass transfer within and outside the pellets did not limit dye degradation. The apparent kinetics of the decolorization reaction followed a first-order behavior. Activation energy for the biological decolorization was calculated at 23 kJ mol^?1. The decolorization process was endothermic with the enthalpy and entropy values calculated at 45.6 kJ mol^?1 and 146 J mol^?1 K^?1, respectively. Based on the value of Gibbs free energy change, the decolorization reaction under the conditions studied was non-spontaneous below 39°C but was spontaneous at higher temperatures.     

Influence of Molecular Weight and Degree of Deacetylation of Low Molecular Weight Chitosan on the Bioactivity of Oral Insulin Preparations

The objective of the present study was to prepare and characterize low molecular weight chitosan (LMWC) with different molecular weight and degrees of deacetylation (DDA) and to optimize their use in oral insulin nano delivery systems. Water in oil nanosized systems containing LMWC-insulin polyelectrolyte complexes were constructed and their ability to reduce blood glucose was assessed in vivo on diabetic rats. Upon acid depolymerization and testing by viscosity method, three molecular weights of LMWC namely, 1.3, 13 and 18 kDa were obtained. As for the DDA, three LMWCs of 55%, 80% and 100% DDA were prepared and characterized by spectroscopic methods for each molecular weight. The obtained LMWCs showed different morphological and in silico patterns. Following complexation of LMWCs with insulin, different aggregation sizes were obtained. Moreover, the in vivo tested formulations showed different activities of blood glucose reduction. The highest glucose reduction was achieved with 1.3 kDa LMWC of 55% DDA. The current study emphasizes the importance of optimizing the molecular weight along with the DDA of the incorporated LMWC in oral insulin delivery preparations in order to ensure the highest performance of such delivery systems.     

Low Molecular Weight Chitosan–Insulin Polyelectrolyte Complex: Characterization and Stability Studies

The aim of the work reported herein was to investigate the effect of various low molecular weight chitosans (LMWCs) on the stability of insulin using USP HPLC methods. Insulin was found to be stable in a polyelectrolyte complex (PEC) consisting of insulin and LMWC in the presence of a Tris-buffer at pH 6.5. In the presence of LMWC, the stability of insulin increased with decreasing molecular weight of LMWC; 13 kDa LMWC was the most efficient molecular weight for enhancing the physical and chemical stability of insulin. Solubilization of insulin-LMWC polyelectrolyte complex (I-LMWC PEC) in a reverse micelle (RM) system, administered to diabetic rats, results in an oral delivery system for insulin with acceptable bioactivity.     

Different Culture Metabolites of the Red Sea Fungus Fusarium equiseti Optimize the Inhibition of Hepatitis C Virus NS3/4A Protease (HCV PR)

The endophytic fungus Fusarium equiseti was isolated from the brown alga Padina pavonica, collected from the Red Sea. The fungus was identified by its morphology and 18S rDNA. Cultivation of this fungal strain in biomalt-peptone medium led to isolation of 12 known metabolites of diketopeprazines and anthraquinones. The organic extract and isolated compounds were screened for their inhibition of hepatitis C virus NS3/4A protease (HCV PR). As a result, the fungal metabolites showed inhibition of HCV protease (IC₅₀ from 19 to 77 μM), and the fungus was subjected to culture on Czapek’s (Cz) media, with a yield of nine metabolites with potent HCV protease inhibition ranging from IC₅₀ 10 to 37 μM. The Cz culture extract exhibited high-level inhibition of HCV protease (IC₅₀ 27.6 μg/mL) compared to the biomalt culture extract (IC₅₀ 56 μg/mL), and the most potent HCV PR isolated compound (Griseoxanthone C, IC₅₀ 19.8 μM) from the bio-malt culture extract showed less of an inhibitory effect compared to isolated ω-hydroxyemodin (IC₅₀ 10.7 μM) from the optimized Cz culture extract. Both HCV PR active inhibitors ω-hydroxyemodin and griseoxanthone C were considered as the lowest selective safe constituents against Trypsin inhibitory effect with IC₅₀ 48.5 and 51.3 μM, respectively.     

Medicinal plants in old-growth, degraded and re-growth forests of NW Pakistan

Many old-growth forest stands in northwest Pakistan have been structurally transformed as a consequence of logging and livestock grazing, some of which are thereafter left to secondary succession. These forests represent an important resource for local inhabitants who gather and sell medicinal plants as part of their livelihood. With this in mind, the main objectives of our study were: (1) to assess differences in the structure of the tree layer and the abundance of medicinal plants among differently transformed forests, (2) to evaluate the recovery potential of medicinal plants under re-growth forests, and (3) to assess relationships between tree stand structural characteristics and the occurrence of medicinal plants.The first step of the study involved creating an approximate map covering an area of 90 km² for five forest-use types (old-growth forest, forest degraded by logging, derived woodland, agroforest and re-growth forest). Fifteen plots per forest-use type were randomly allocated at altitudes ranging from 2200 m to 2400 m asl, within which the abundance of 10 locally important medicinal herb species was assessed.The study stands differed greatly in tree basal area, which was highest in old-growth forest (48 m² ha⁻¹), lowest in agroforest areas (6 m² ha⁻¹) and intermediate in re-growth forest (20 m² ha⁻¹). All ten medicinal plant species were encountered in old-growth and in re-growth forests, but only five of these species also occurred on agroforest plots. The mean coverage of study medicinal plants was highest in old-growth forest (7%), low in forest degraded by logging, derived woodland and agroforest (0.3-2%), and intermediate in re-growth forest (4%). The Jaccard abundance based similarity index indicates a considerable similarity (0.6) between re-growth and old growth forest for both trees and medicinal plants. The overall abundance of medicinal plants increased with increasing tree basal area and canopy cover. The abundance of some particular species decreased; however, the most sought-after medicinal species Bergenia ciliata, Valeriana jatamansi and Viola cancescens increased with tree basal area within specific forest-use type and also across forest-use types. In conclusion, our data suggest that anthropogenic forest degradation leads to a reduction in the abundance of economically viable medicinal plants for the study region. It is further indicated that this can be reversed if degraded forests are allowed to regenerate.     

Adsorption Kinetics of Acid Red on Activated Carbon Web Prepared from Acrylic Fibrous Waste

In this work, activated carbon (AC) web was prepared using physical activation under the layer of charcoal in high temperature furnace. The carbonization of acrylic fibrous waste was performed at different temperatures (800 °C, 1000 °C, and 1200 °C) with heating rate of 300 °C/h and at different holding time. At 1200 °C, the heating rate of 300 °C/h and no holding time provided better results of surface area as compared to carbonization at 800 °C and 1000 °C. The activated carbon web (AC) prepared at 1200 °C was used for removal of Acid Red 27 dye from aqueous media by varying different parameters like initial concentration of dye, stirring speed, adsorbent dosage, and pH. The results were evaluated using non-linear forms of Langmuir and Freundlich isotherms. The Freundlich isotherm was found to describe the results more effectively because of non-homogenous surface of activated carbon web. Further, the kinetics of adsorption was examined using linear and nonlinear forms of pseudo 1st order and pseudo 2nd order.