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961.
Simultaneous Removal of Phosphate and Nitrate in Wastewater Using High-Capacity Anion-Exchange Resin 总被引:1,自引:0,他引:1
Yeon-Seok Kim Young-Hang Lee Byungryul An Sung-A Choi Jong-Hoon Park Jong-Soo Jurng Sang-Hyup Lee Jae-Woo Choi 《Water, air, and soil pollution》2012,223(9):5959-5966
The removal of nutrients in wastewater is a critical issue in water treatment because released nutrients can cause serious adverse effects in water systems or the aquatic environment. In this study, a high-performing polymeric anion-exchange resin was developed for the removal of nutrients from wastewater. The resins were prepared by chloromethylation followed by amination under preferred conditions. The resins were investigated for the removal of nutrients such as phosphate, nitrate, and fluoride from water. The density of functional groups on the synthesized resin was approximately 33?% higher than on commercialized resins, and the specific surface area of synthesized resin was increased by approximately tenfold compared with commercialized resins. The adsorption capacity of synthesized resins (AMP16-FeCl3) for anions was 285.8?mg/g, which was approximately three times higher than the capacity of commercialized resin (AMP16-OH). A study of the effects of the types of counterions and functional groups found that resins having hydroxide ion as a counterion showed higher capacity and selectivity for phosphate ion and that dimethylethanolamine as a resin functional group of resin was more efficient than trimethylamine. 相似文献
962.
Chang?Hoon?Lee Sang?Yoon?Kim Maria?B.?Villamil Prabhat?Pramanik Chang?Ok?Hong Pil?Joo?KimEmail author 《Biology and Fertility of Soils》2012,48(4):435-442
Cultivation of green manure plants during the fallow season in rice paddy soil has been strongly recommended to improve soil
properties. However, green manuring may impact greenhouse gas emission, methane (hereafter, CH4) in particular, under the flooded rice cultivation and thus, application of chemical amendments being electron acceptors
can be an effective mitigation strategy to reduce CH4 emissions in irrigated rice (Oryza sativa L.) field amended with green manure. To investigate the effect of iron (Fe) slag silicate fertilizer (hereafter, silicate
fertilizer), which was effective in reducing CH4 emission and increasing rice productivity, in green manure-amended paddy soil, the aboveground biomass of Chinese milk vetch
(hereafter, vetch) was added at rates of 0, 10, 20, and 40 Mg (fresh weight) ha−1 before the application of silicate fertilizer, which was added at rates of 0 and 2.3 Mg ha−1. Silicate fertilization reduced the seasonal CH4 flux by ca. 14.5% and increased rice yield by ca. 15.7% in the control (no vetch application) treatment. However, CH4 production was increased by silicate fertilization in vetch-treated soil particularly at the initial rice growing stage,
which was probably due to the enhanced decomposition of added organic matters by the silicate liming effect. In conclusion,
silicate fertilization is not effective in reducing CH4 production in green manure-amended rice paddy soils and its use should be properly controlled. 相似文献
963.
964.
965.
Jae?Whan?ChoEmail author Yong?Chae?Jung Sun?Hwa?Lee Byoung?Chul?Chun Yong-Chan?Chung 《Fibers and Polymers》2003,4(3):114-118
The prepolymer and the final polyurethane (PU) block copolymer were synthesized by reacting 4,4-methylene bis(phenylisocyanate)
with poly(tetramethylene glycol) and the prepolymer with 1,4-butanediol as a chain extender, respectively, to investigate
the relation between phase separation and it’s resulting properties. According to FT-IR data, the phase separation of hard
and soft segments in the prepolymer and the PU block copolymer grew bigger by increasing the hard segment content, and the
PU showed more dominant phase separation than the prepolymer. The heat of fusion due to soft segments decreased in both the
prepolymer and the PU by increasing the hard segment content, whereas the heat of fusion due to hard segments increased in
the PU did not appear in the prepolymers. The breaking stress and modulus of the prepolymer increased by increasing the hard
segment content, and the elongation at break decreased gradually, and the PU showed the highest breaking stress and modulus
at 58 % hard segment content. However, the best shape recovery of the PU was obtained at 47 % hard segment content due to
the existence of proper interaction among the hard segments for shape memory effect. Consequently, the mechanical properties
and shape memory effect of the PU were influenced by the degree of phase separation, depending on the incorporation of chain
extender as well as the hard segment content. 相似文献
966.
Kyung?Min?Yoo Seok?Won?Lee Jae?Ryoun?YounEmail author Do?Heum?Yoon Young?Eun?Cho Jae-Pil?Yu Hyung?Sang?Park 《Fibers and Polymers》2003,4(2):89-96
A vertebral cage is a hollow medical device which is used in spine surgery. By implanting the cage into the spine column,
it is possible to restore disc and relieve pressure on the nerve roots. Most cages have been made of titanium alloys but they
detract the biocompatibility. Currently PEEK (polyether ether ketone) is applied to various implants because it has good properties
like heat resistance, chemical resistance, strength, and especially biocompatibility. A new shape of vertebral cage is designed
and injection molding of PEEK is considered for production. Before injection molding of the cage, it is needed to evaluate
process conditions and properties of the final product. Variables affecting the shrinkage of the cage are considered, e.g.,
injection time, packing pressure, mold temperature, and melt temperature. By using the numerical simulation program, MOLDFLOW,
several cases are studied. Data files obtained by MOLDFLOW analysis are used for stress analysis with ABAQUS, and shrinkage
and residual stress fields are predicted. With these results, optimum process conditions are determined. 相似文献
967.
Epoxidized polybutadiene (EPB) was prepared by polybutadiene (PB) withm-chloroperbenzoic acid (MCPBA) in homogeneous solution. EPB was blended with poly(3-hydroxybutyrate) (PHB) up to 30 wt% by solution-precipitation procedure. The thermal decomposition of PHB/EPB blends was studied by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and differential thermal analysis (DTA). The thermograms of PHB/EPB blends contained a two-step degradation process, while that of pure PHB sample exhibited only one-step degradation process. This degradation behavior of PHB/EPB blends, which have a higher thermal stability as measured by maximum decomposition temperature and residual weight, is probably due to crosslinking reactions of the epoxide groups in the EPB component with the carboxyl chain ends of PHB fragments during the degradation process, and the occurrence of such reactions can be assigned to the exothermic peaks in their DTA thermograms. 相似文献
968.
Sang?Youn?Oh Dong?Il?YooEmail author Younsook?Shin Wha?Seop?Lee Seong?Mu?Jo 《Fibers and Polymers》2002,3(1):1-7
Cellulose carbonate was prepared by the reaction of cellulose pulp and CO2 with treatment reagents, such as aqueous ZnCl2 (20–40 wt%) solution, acetone or ethyl acetate, at −5–0°C and 30–40 bar (CO2) for 2 hr. Among the treatment reagents, ethyl acetate was the most effective. Cellulose carbonate was dissolved in 10% sodium
hydroxide solution containing zinc oxide up to 3 wt% at −5–0°C. Intrinsic viscosities of raw cellulose and cellulose carbonate
were measured with an Ubbelohde viscometer using 0.5 M cupriethylenediamine hydroxide (cuen) as a solvent at 20°C according
to ASTM D1795 method. The molecular weight of cellulose was rarely changed by carbonation. Solubility of cellulose carbonate
was tested by optical microscopic observation, UV absorbance and viscosity measurement. Phase diagram of cellulose carbonate
was obtained by combining the results of solubility evaluation. Maximum concentration of cellulose carbonate for soluble zone
was increased with increasing zinc oxide content. Cellulose carbonate solution in good soluble zone was transparent and showed
the lowest absorbance and the highest viscosity. The cellulose carbonate and its solution were stable in refrigerator (−5°C
and atmospheric pressure). 相似文献
969.
Tiger T.T. Lee Wei-Ming Leu Hsueh-Hui Yang Balance C.M. Chen Jason T.C. Tzen 《Journal of Cereal Science》2006,44(3):333-341
A recombinant polypeptide containing the precursor protein of a sesame storage protein, 2S albumin, fused to the C-terminus of a sesame oleosin was expressed in transgenic rice seeds under the control of a rice glutelin promoter. The recombinant polypeptide of 32 kDa, equivalent to the resultant molecular mass of sesame oleosin (15 kDa) and prepro-2S albumin (17 kDa), was detected in the endoplasmic reticulum fraction of maturing transgenic rice seeds, but not in the purified oil bodies or the soluble extract of transgenic seeds. However, sesame oleosin presumably fused with a 2 kDa C-terminal appendix originating from the signal sequence of prepro-2S albumin, was found in the purified oil bodies, and mature sesame 2S albumin apparently processed into two subunits (9 and 4 kDa) linked by disulfide bonds was detected in extracts of transgenic seeds. Immunogold labeling revealed that the sesame oleosin and 2S albumin were separately located in oil bodies and protein bodies of embryo cells of transgenic rice seeds. While sesame 2S albumin was also detected in protein bodies of endosperm cells of transgenic seeds, the co-expressed sesame oleosin, probably degraded due to the lack of oil bodies in this tissue, and was not detected. The results provide a new technique for introducing two recombinant polypeptides separately into rice oil bodies and protein bodies from one expression construct. 相似文献
970.
Sung Ok Sohn So Min Lee Yun Mi Kim Jeong Hyun Yeum Jin Hyun Choi Han Do Ghim 《Fibers and Polymers》2007,8(2):163-167
A durable aroma finishing for PET fabric was carried out by adopting poly(vinyl acetate) (PVAc) nanoparticles containing lavender
oil (LO) in core. Relatively small size of PVAc nanoparticles (ca. 244 nm of mean particle diameter) was expected to resist
the frictional destruction of the particles, which is frequently observed in cases of microcapsules. PVAc nanoparticles containing
LO in core were prepared by emulsification-diffusion method and their application as an aroma releasing agent for PET fabrics
was assessed through the observation of releasing profiles of LO in ethanol for experimental acceleration. Melamine-formaldehyde
(MF) microcapsules containing LO were also prepared and treated on fabrics for comparison. PVAc nanoparticles treated on PET
fabric showed higher initial releasing amount, which was ascribed to the enhanced surface area. After 2 days of releasing,
PET fabric treated with PVAc nanoparticles showed slower and more stable releasing profile and reached about 12 ppm of cumulative
release after 16 days, which was under two thirds of that with MF microcapsules. PVAc nanoparticles can be used as an agent
for durable aroma finishing of PET fabrics. 相似文献