全文获取类型
收费全文 | 7029篇 |
免费 | 350篇 |
国内免费 | 6篇 |
专业分类
林业 | 487篇 |
农学 | 148篇 |
基础科学 | 36篇 |
1316篇 | |
综合类 | 1224篇 |
农作物 | 228篇 |
水产渔业 | 559篇 |
畜牧兽医 | 2684篇 |
园艺 | 197篇 |
植物保护 | 506篇 |
出版年
2023年 | 59篇 |
2022年 | 75篇 |
2021年 | 147篇 |
2020年 | 151篇 |
2019年 | 178篇 |
2018年 | 180篇 |
2017年 | 150篇 |
2016年 | 177篇 |
2015年 | 162篇 |
2014年 | 185篇 |
2013年 | 264篇 |
2012年 | 476篇 |
2011年 | 599篇 |
2010年 | 296篇 |
2009年 | 240篇 |
2008年 | 493篇 |
2007年 | 521篇 |
2006年 | 462篇 |
2005年 | 431篇 |
2004年 | 407篇 |
2003年 | 380篇 |
2002年 | 387篇 |
2001年 | 68篇 |
2000年 | 50篇 |
1999年 | 63篇 |
1998年 | 51篇 |
1997年 | 50篇 |
1996年 | 42篇 |
1995年 | 47篇 |
1994年 | 43篇 |
1993年 | 43篇 |
1992年 | 30篇 |
1991年 | 34篇 |
1990年 | 32篇 |
1989年 | 34篇 |
1988年 | 28篇 |
1987年 | 26篇 |
1986年 | 24篇 |
1985年 | 35篇 |
1984年 | 26篇 |
1983年 | 27篇 |
1982年 | 20篇 |
1981年 | 15篇 |
1980年 | 23篇 |
1979年 | 23篇 |
1978年 | 14篇 |
1977年 | 15篇 |
1975年 | 11篇 |
1974年 | 11篇 |
1973年 | 17篇 |
排序方式: 共有7385条查询结果,搜索用时 15 毫秒
91.
Paige E Boyle Michael D Richardson Mary C Savin Douglas E Karcher Daniel A Potter 《Pest management science》2019,75(8):2071-2078
Earthworm activity is beneficial in most natural and agricultural systems, but excessive earthworm casting is a problem on sports fields worldwide. Expulsion of soil‐rich earthworm fecal matter, or casts, as mounds of soil on the turf canopy can muddy the surface, reduce photosynthesis, and lead to thinning, weed invasion and surface softening. Casts affect ball roll on sports fields, cause fouling of maintenance equipment, and dull mower blades. Build‐up of cast material on reel mower units can affect height and quality of cut. Casting activity is dependent on environmental conditions such as soil texture, temperature, moisture, pH, and organic matter. Response to environmental conditions varies by species. Management options are limited, because no pesticides are specifically labeled for earthworm control at this time, and cultural control methods such as soil modification, turfgrass clipping removal, and sand topdressing have limited and inconsistent efficacy. Products containing plant‐derived saponins and irritants show promise for earthworm management. Pest management practices to mitigate excessive earthworm casting will likely need to be species‐specific, but limited knowledge of earthworm identification by end‐users further inhibits the efficacy of control measures. © 2019 Society of Chemical Industry 相似文献
92.
Journal of Plant Diseases and Protection - A broad range of different Fusarium (F.) species is associated with Fusarium head blight (FHB) on barley and the corresponding negative effects in... 相似文献
93.
Robert J. Diaz Lars Johan Hansson Rutger Rosenberg Paul C. Gapcynski Michael A. Unger 《Water, air, and soil pollution》1993,66(3-4):251-266
It is possible to rapidly detect the presence of high concentrations of sediment associated hydrocarbons using a sediment profile camera and simultaneously evaluate the general sedimentological and biological character of a contaminated area. In sediments that were heavily contaminated with hydrocarbons from spills and chronic long-term additions the presence of hydrocarbons was seen about 50% of the time in the sediment profile images as unique features, ‘H spots’. The presence of these features was related to the concentration of hydrocarbons in the sediment. In highly contaminated muddy sediments ‘H spots’ were found in images collected at stations that had from 270 to 610 ppt total hydrocarbons. Sedimentological and biological information obtained from the sediment profile images confirmed the impacted nature of Elizabeth River sediments. Sediment profile imaging provide a means of obtaining an overall evaluation of the quality of a habitat and impacts on that habitat from pollution related environmental disturbances. While qualitative, an advantage of sediment profile image data is that they can be evaluated in less than a day and used to quickly locate inclusions of hydrocarbons in the sediments for further quantitative chemical or biological sampling, or mapping of heavily contaminated areas. 相似文献
94.
Dry deposition of fly ash emitted by a coal-fired power plant has been calculated using a surface depletion Gaussian plume model. The subject plant is located in the southwestern United States. Soil samples collected downwind of this power plant have been chemically analyzed for selected trace elements (As, B, F, Hg, Se, Sr, U, and V) to determine concentration vs. distance trends. Gaussian plume deposition calculations predict very little increase of trace element concentrations in soils, except for those elements highly concentrated in fly ash emissions compared to soils. Trace element soil concentrations as a function of downwind distance generally confirm these predictions, with the possible exception of Se. 相似文献
95.
Metsulfuron methyl sorption-desorption in field-moist soils 总被引:4,自引:0,他引:4
Berglöf T Koskinen WC Duffy MJ Norberg KA Kylin H 《Journal of agricultural and food chemistry》2003,51(12):3598-3603
Pesticide sorption coefficients (K(d)) are generally obtained using batch slurry methods. As a consequence, the results may not adequately reflect sorption processes in field-moist or unsaturated soil. The objective of this study was to determine sorption of metsulfuron methyl, a weak acid, in field-moist soils. Experiments were performed using low density (i.e., 0.3 g mL(-)(1)) supercritical fluid carbon dioxide (SF-CO(2)) to convert anionic metsulfuron methyl to the molecular species and remove it from the soil water phase only, thus allowing calculation of sorption coefficients (K(d)) at low water contents. K(d) values for sorption of the metsulfuron methyl molecular species on sandy loam, silt loam, and clay loam soil at 11% water content were 120, 180, and 320 mL g(-)(1), respectively. Using neutral species K(d) values, the pK(a) of metsulfuron methyl, and the pH of the soil, we could successfully predict the K(d) values obtained using the batch slurry technique, which typically has a predominance of anionic species in solution during the sorption characterization. This application of supercritical fluid extraction to determine sorption coefficients, combined with sulfonylureas' pK(a) values and the soil pH, will provide an easy method to predict sorption in soil at different pH levels. 相似文献
96.
Weber HA Zart MK Hodges AE Molloy HM O'Brien BM Moody LA Clark AP Harris RK Overstreet JD Smith CS 《Journal of agricultural and food chemistry》2003,51(25):7352-7358
The characterization of herbal materials is a significant challenge to analytical chemists. Goldenseal (Hydrastis canadensis L.), which has been chosen for toxicity evaluation by NIEHS, is among the top 15 herbal supplements currently on the market and contains a complex mixture of indigenous components ranging from carbohydrates and amino acids to isoquinoline alkaloids. One key component of herbal supplement production is botanical authentication, which is also recommended prior to initiation of efficacy or toxicological studies. To evaluate material available to consumers, goldenseal root powder was obtained from three commercial suppliers and a strategy was developed for characterization and comparison that included Soxhlet extraction, HPLC, GC-MS, and LC-MS analyses. HPLC was used to determine the weight percentages of the goldenseal alkaloids berberine, hydrastine, and canadine in the various extract residues. Palmatine, an isoquinoline alkaloid native to Coptis spp. and other common goldenseal adulterants, was also quantitated using HPLC. GC-MS was used to identify non-alkaloid constituents in goldenseal root powder, whereas LC-MS was used to identify alkaloid components. After review of the characterization data, it was determined that alkaloid content was the best biomarker for goldenseal. A 20-min ambient extraction method for the determination of alkaloid content was also developed and used to analyze the commercial material. All three lots of purchased material contained goldenseal alkaloids hydrastinine, berberastine, tetrahydroberberastine, canadaline, berberine, hydrastine, and canadine. Material from a single supplier also contained palmatine, coptisine, and jatrorrhizine, thus indicating that the material was not pure goldenseal. Comparative data for three commercial sources of goldenseal root powder are presented. 相似文献
97.
Frogs are in decline worldwide, and are known to be sensitive indicators of environmental change. Floodplains of the Murray-Darling Basin in southeastern Australia have been altered in many ways by livestock grazing, by the introduction of exotic fish, and by changes to flooding regimes. These changes have led to declines in wetland condition and hence to the availability of habitat for wetland frogs. This study examined relationships between frogs, wetland condition and livestock grazing intensity at 26 wetlands on the floodplain of the Murrumbidgee River. Frog communities, species richness, and some individual species of frogs declined with increased grazing intensity. Wetland condition also declined with increased grazing intensity, particularly the aquatic vegetation and water quality components. There were clear relationships between frog communities and wetland condition, with several taxa responding to aquatic and fringing vegetation components of wetland condition. Thus, grazing intensity appeared to influence frog communities through changes in wetland habitat quality, particularly the vegetation. Reduced stocking rates may result in improved wetland condition and more diverse frog communities. River management to provide natural seasonal inundation of floodplain wetlands may also enhance wetland condition, frog activity and reproductive success. 相似文献
98.
Using the soil gas radon as an indicator for ground contamination by non-aqueous phase-liquids 总被引:1,自引:0,他引:1
Michael Schubert Klaus Freyer Hans-Christian Treutler Holger Weiß 《Journal of Soils and Sediments》2001,1(4):217-222
1 The Problem One of the major problems facing risk assessment at polluted industrial sites and military bases is subsurface contamination
by non-aqueous phase-liquids (NAPLs), since tracing the extent of a NAPL plume using conventional methods (drive point profiling)
is usually associated with difficulties. In an effort to trace subsurface contamination as precisely as possible, monitoring
points are placed in the area that might be affected by contaminants, and groundwater and soil samples are taken to the laboratory
for analysis. However, the final number of monitoring points is hardly ever sufficient for distinctive contamination mapping,
and this may ultimately result in an unsuitable remediation action being taken.
2 Objectives To obtain a more detailed image of a subsurface NAPL plume and, hence, to facilitate remediation measures that are best suited
for the site in question, a denser network of monitoring points is desirable. The aim of the investigation described in this
paper was therefore to develop a new detection method for subsurface NAPL contamination, which is based on an easily accessibleindicator for NAPLs rather than on the analysis of soil and groundwater samples taken at the site. Based on the good solubility of
radon in NAPLs, the idea was put forward that subsurface NAPL contamination should have an influence on the natural radon
concentration of the soil gas. Provided this effect is significant, it would be possible to carry out a straightforward radon
survey on an appropriate sampling grid covering the suspected site and thus enabling the NAPL contamination to be detected
by the localization of anomalous low radon concentrations in the soil. The overall aim of the investigation was to assess
the general suitability of the soil-gas radon concentration as an indirect tracer for NAPL contamination in the ground.
3 Methods The partitioning coefficient KNAPL/air is one of the most influential parameters governing the decrease of the radon concentration in the soil gas in the presence
of a subsurface NAPL contamination. Since NAPL mixtures such as gasoline, diesel fuel and paraffin are among the most important
NAPLs regarding remediation activities, laboratory experiments were performed to determine the radon-partitioning coefficient
for these three NAPL mixtures.
Field experiments were carried out as well. The aim of the field experiments was to test the use of the soil-gas radon concentration
as a tracer for NAPL contamination on-site. For the field experiments, each site was covered with a suitable grid of soil
gas sampling points. Finally, the lateral radon distribution pattern achieved on each of the sites was compared to the respective
findings of the earlier research performed by conventional means.
4 Results and Discussion The results of the laboratory experiments clearly show a very strong affinity of radon to the NAPL mixtures examined. The
partitioning coefficients achieved correspond to those published for pure NAPLs (Clever 1979) and are thus in the expected
range. The results of the field experiments showed that the minimum radon concentrations detected match the respective NAPL
plumes traced previously.
5 Conclusions Both the results of the lab experiments and the on-site findings demonstrate that the soil-gas radon concentration can be
used as an indicator for subsurface NAPL contamination. The investigation showed that NAPL-contaminated soil volumes give
rise to anomalous low soil-gas radon concentrations in the close vicinity of the contamination. The reason for this decrease
in the soil-gas radon concentration is the good solubility of radon in NAPLs, which enables the NAPLs to accumulate and ‘trap’
part of the radon available in the soil pores.
6 Recommendations and Outlook Further research is required into contamination with rather volatile NAPLs such as BTEX. Further research is also needed to
examine whether it is possible to not only localize a NAPL plume, but also to obtain some quantitative information about the
subsurface NAPL contamination. The authors also believe that additional investigations should be carried out to study the
ability of the method to not just localize a NAPL contamination, but also to monitor on-site, clean-up measures. 相似文献
99.
Kapasakalidis PG Rastall RA Gordon MH 《Journal of agricultural and food chemistry》2006,54(11):4016-4021
The total phenol and anthocyanin contents of black currant pomace and black currant press residue (BPR) extracts, extracted with formic acid in methanol or with methanol/water/acetic acid, were studied. Anthocyanins and other phenols were identified by means of reversed phase HPLC, and differences between the two plant materials were monitored. In all BPR extracts, phenol levels, determined by the Folin-Ciocalteu method, were 8-9 times higher than in the pomace extracts. Acid hydrolysis liberated a much higher concentration of phenols from the pomace than from the black currant press residue. HPLC analysis revealed that delphinidin-3-O-glucoside, delphinidin-3-O-rutinoside, cyanidin-3-O-glucoside, and cyanidin-3-O-rutinoside were the major anthocyanins and constituted the main phenol class ( approximately 90%) in both types of black currant tissues tested. However, anthocyanins were present in considerably lower amounts in the pomace than in the BPR. In accordance with the total phenol content, the antioxidant activity determined by scavenging of 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) radical cation, the ABTS(*)(+) assay, showed that BPR extracts prepared by solvent extraction exhibited significantly higher (7-10 times) radical scavenging activity than the pomace extracts, and BPR anthocyanins contributed significantly (74 and 77%) to the observed high radical scavenging capacity of the corresponding extracts. 相似文献
100.
Putzbach K Krucker M Albert K Grusak MA Tang G Dolnikowski GG 《Journal of agricultural and food chemistry》2005,53(3):671-677
The structures of biosynthetic deuterated carotenoids in labeled vegetables were investigated: (all-E)-lutein and (all-E)-beta-carotene from spinach, and (all-E)-beta-carotene and (all-E)-alpha-carotene from carrots. The vegetables were grown hydroponically using a nutrient solution enriched with deuterium oxide (D(2)O) and were extracted using matrix solid-phase dispersion (MSPD). Deuterium enrichment in the carotenoid molecules was determined by liquid chromatography-mass spectrometry (LC-MS). (all-E)-Lutein and (all-E)-beta-carotene in spinach showed partial deuteration from (2)H(1) to (2)H(12), with the abundance maximum at (2)H(5). (all-E)-beta-Carotene and (all-E)-alpha-carotene from carrots showed partial deuteration from (2)H(1) to (2)H(17), with the abundance maximum at (2)H(11). The (1)H NMR spectra of the four deuterated carotenoids showed additional signals for all methyl groups and decreased signal intensity for the olefinic protons and the methylene protons in the ring. These differences are due to isotopic effects and are based on the substitution of protons by deuterium atoms. The deuteration was distributed randomly throughout the carotenoid molecules. 相似文献