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The kinetics of a first-order, solid-solid phase transition were investigated in the prototypical nanocrystal system CdSe as a function of crystallite size. In contrast to extended solids, nanocrystals convert from one structure to another by single nucleation events, and the transformations obey simple unimolecular kinetics. Barrier heights were observed to increase with increasing nanocrystal size, although they also depend on the nature of the nanocrystal surface. These results are analogous to magnetic phase transitions in nanocrystals and suggest general rules that may be of use in the discovery of new metastable phases.  相似文献   
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The amplitude of the parity-nonconserving transition between the 6S and 7S states of cesium was precisely measured with the use of a spin-polarized atomic beam. This measurement gives Im(E1pnc)/beta = -1.5935(56) millivolts per centimeter and provides an improved test of the standard model at low energy, including a value for the S parameter of -1.3(3)exp (11)theory. The nuclear spin-dependent contribution was 0.077(11) millivolts per centimeter; this contribution is a manifestation of parity violation in atomic nuclei and is a measurement of the long-sought anapole moment.  相似文献   
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The aim of this study was to establish expected average parameters for barking in normal suburban dogs in New Zealand (defined as dogs with no history of problem or nuisance barking) that are left alone for 8 hours during the day, with indoor/outdoor access, and are walked daily. Parameters evaluated over the 8-hour period were the average number of barking episodes, average length of each episode, and average total amount of barking (in seconds). The effects of age and sex on these parameters were assessed. Clients from 2 different Auckland veterinary practices were offered the opportunity to participate in the study (n = 60). Participants were provided with a voice-operated tape recorder (Sony M-200MC Microcassette Recorder) and a written instruction sheet. They recorded their dogs daily over 8 hours for 5 days. Data were then recorded onto a spreadsheet by the investigator, and averages were evaluated using the Windows XLS system. Further analysis was done using the PASW 18 statistical analysis system. Box plots were constructed to evaluate variation between and within dogs. On average, dogs barked between 4 and 5 times over 8 hours. The average length of each episode was 30 seconds, and the average total amount of barking in 8 hours was 129 seconds. Younger dogs (younger than 5 years) tended to bark more frequently than older dogs. These parameters provide a baseline against which barking complaints may be measured.  相似文献   
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Objective To investigate the distribution and prevalence of mucormycosis in platypus (Ornithorhynchus anatinus) from the Inglis, Emu and Black-Detention catchment areas in north-west Tasmania. Procedure A field study was performed and resulted in the examination of 44 wild platypuses; in addition, one dead platypus and two live platypuses were examined after they were independently submitted to a local veterinary clinic. Results No cases of mucormycosis were conclusively diagnosed. One platypus with signs consistent with those previously described in cases of mucormycosis was captured in the Emu River catchment. However, laboratory tests did not provide a definitive diagnosis for the lesion. Two platypuses from the Inglis catchment area had signs very similar to those previously described in cases of mucormycosis, but laboratory tests found Corynebacterium ulcerans to be the likely cause of the cutaneous ulcers on one of these platypuses and an unidentified fungal agent to be the cause of a cutaneous nodule in the other. Conclusions These findings do not prove that mucormycosis is absent from the populations studied. However, they may indicate that the prevalence of disease is low. The possibility that Mucor amphibiorum is present in a subclinical form in platypuses, or infecting another reservoir, is not excluded. The findings also suggest that caution should be exercised when diagnosing mucormycosis based on clinical findings alone and raise the possibility that some cases may have been incorrectly diagnosed.  相似文献   
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Soil organic carbon(SOC) has primary importance in terms of soil physics, soil fertility and even of climate change control. One hundred soil samples were taken from an intensively cultivated Cambisol to quantify SOC redistribution triggered by soil erosion under a subhumid climate, by the simultaneous application of diffuse reflectance(240–1 900 nm) and traditional physico-chemical methods.The representative sample points were collected from the solum along the slopes at the depth of 20–300 cm with a mean SOC content of 12 g kg~(-1). Hierarchical cluster analyses were performed based on the determined SOC results. The spatial pattern of the groups created were similar, and even though the classifications were not the same, diffuse reflectance had proven to be a suitable method for soil/sediment classification even within a given arable field. Both organic and inorganic carbon distributions were found to be a proper tool for estimations of past soil erosion processes. The SOC enrichment was found on two sedimentary spots with different geomorphological positions. Soil organic matter composition also differed between the two spots due to selective deposition of the delivered organic matter. The components with low-molecular-weight reached the bottom of the slope where they could leach into the profile, while the more polymerised organic matter compositions were delivered and deposited even before on a higher segment of the slope in an aggregated form. This spatial difference appeared below the uppermost tilled soil layer as well, referring the lower efficiency of conventional ploughing tillage in soil spatial homogenisation.  相似文献   
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