Glass Transition Behavior and Rheological Properties of Surfactants and Gluten‐Surfactant Mixtures

Diacetyltartaric acid esters of monoglycerides (DATEM) and sodium stearoyl lactylate (SSL) displayed thermal events corresponding to glass transition temperature (T_g) and melting of crystalline domains, while monoglycerides (MG) exhibited an endothermic peak corresponding to melting of crystalline structures when heated in a differential scanning calorimeter. The plasticizing effect of water on T_g of gluten exhibited little apparent change in the presence of DATEM, MG, or SSL (glutensurfactant 10:1), in the moisture range of 6.5–21.3% as shown by mechanical spectrometry and differential scanning calorimetry. Glutensurfactant mixtures showed higher G′ and apart from gluten‐SSL, which displayed higher tan δ (G″/G′) at ≤2.51 rad/sec, lower tan δ values than gluten in the frequency range of 0.1–100 rad/sec. DATEM and SSL softened the gluten network before cross‐linking reactions, while MG shifted the onset of cross‐linking reactions to higher temperatures at moisture contents of 30–40%. Complete vitrification of the gluten network occurred at higher temperatures, at the indicated moisture contents, in the presence of surfactants. Softening of the matrix and the delay in cross‐linking of gluten, in the presence of surfactants, might allow for greater expansion of doughs during baking with concomitant increase in loaf volumes.     

Quantification of anthropogenic lead in Slovak forest and arable soils along a deposition gradient with stable lead isotope ratios

Isotope ratios of Pb may provide the opportunity to determine the contribution of Pb from a point source to Pb concentrations in soil. Our objective was to quantify the contribution of anthropogenic Pb to total Pb and chemical Pb fractions in contaminated soil profiles with the help of ²⁰⁶Pb/²⁰⁷Pb isotope ratios. We sampled 5 forest and 5 arable Cambisols along a transect from a Cu smelter and determined Pb concentrations and ²⁰⁶Pb/²⁰⁷Pb isotope ratios in total digests of all horizons and in 7 chemical fractions of the A horizons. In the organic layer under forest, Pb concentrations decreased from 2155 mg kg^—1 at 1.1 km distance from the smelter to 402 mg kg^—1 at 8 km distance; in the Ap horizons, it decreased from 126 to 72 mg kg^—1. In the total digests, ²⁰⁶Pb/²⁰⁷Pb isotope ratios could be explained by simple mixing of smelter‐ and background‐Pb as indicated by the correlation between the inverse of the Pb concentration and the ²⁰⁶Pb/²⁰⁷Pb ratio (r = 0.93). The mean proportion of smelter‐Pb in soil horizons decreased with depth from 87% (Oi) to 21% (C) under forest and from 64% (A) to 30% (B) in the arable soils. The smelter‐Pb proportions in the B horizons ranged from 6 to 66% and were independent of the distance from the smelter indicating variable leaching rates. The ²⁰⁶Pb/²⁰⁷Pb ratios in the chemical fractions could not be explained by a simple mixing model. Thus, the ²⁰⁶Pb/²⁰⁷Pb ratios may be used to determine the contribution of anthropogenic Pb in total digests but not in chemical Pb fractions.     

Pedosedimentary and climatic reconstruction of the last interglacial and early glacial loess–paleosol sequence in South Tadzhikistan

The thick loess–paleosol-sequences in Tadzhikistan, which indirectly record the environmental changes from the Upper Pliocene to the present-day, have been extensively described from a chronostratigraphical and archaeological point of view. The genesis of the soil-sedimentary complexes and their implications for palaeoenvironmental reconstruction in Tadzhikistan, however, have been considered only relatively recently [Bronger, A., Winter, R., Derevjanko, O., Aldag, S., 1993. Loess–paleosol sequences in Tadjikistan as a palaeoclimatic record of the Quaternary in Central Asia. Quaternary Proceedings 4, 69–81; Lomov, S.P., Tursina, T.V., Zhou, L.P., 1996. Magnetic susceptibility of soils: Micromorphology and possible reconstructions of climate. In: Soil micromorphology. Studies in Soil Diversity, Diagnostics, Dynamics, 10th International Working Meeting on Soil Micromorphology. Moscow, Russia, July 8–13, 1996, p. 145]. The pedocomplex of Last Interglacial and Early Glacial age (Oxygen Isotope Stage 5) in the Tagidjar and Darai Kalon sections near the town of Khovaling is represented by three major stages of soil formation. The soil characteristics have been micromorphologically analysed. The distinction between primary and secondary carbonates is of major importance to understand the soil forming processes. The relative distribution of needle fibre calcite (NFC), micritic infillings (M), hypocoatings (CHC), coarse calcitic grains (CCG) and calcified root cells (CRC) provides detailed insights into the environmental conditions prior, during and following pedogenesis. The abundance of coprolitic aggregates (CA) and pupal chambers gives a clear indication of the rate of biological activity which prevailed during the last two soil forming stages. Void pseudomorphs after gypsum crystals (gypsum pseudomorphs) are frequently observed beneath the Cca horizons of the paleosols. Using the present-day climate and soilscape as a reference base, the obtained pedosedimentary events detected in the Tadzhikistan sections provide a detailed palaeoenvironmental record. Indeed, glacial and interglacial climates and soils respond to contemporaneous climatic schemes and soil forming processes, which are still active in the region today. The amount and the seasonal variability of precipitation, mostly, are at the origin of the variable soils formed during glacial and interglacial ages.     

Students’ Preferences in Selecting Information Resources Used to Find Scholarly Information: A Comparative Study Between Undergraduate and Graduate Students

This study compares undergraduate and graduate students’ preferences for information sources. It found that the largest percentage of undergraduates ranked Google Scholar, a scholarly database, as their 1st or 2nd choice for an information source, followed by Google, library scholarly databases, the library catalog, and library staff. The largest percentage of graduate students ranked library scholarly databases as their 1st or 2nd preference, followed by Google Scholar, the library catalog, Google, and library staff. There seems to be a connection between attendance in a library instruction session and the choice of library scholarly online databases.     

Targeted screening of contaminants and physico-chemical behaviors in permanent grass vegetation soils and agricultural soils from Eastern Slovakia

Journal of Soils and Sediments - To evaluate the ecological risk, physico-chemical properties, and the impact of anthropogenic sources on permanent eighteen samples of grass vegetation soils (PGVS)...     

Physiological Aspects of Cadmium and Nickel Toxicity in the Lichens Peltigera rufescens and Cladina arbuscula Subsp. mitis

This study was undertaken with the aim of investigating the effect of Cd²⁺ and Ni²⁺ containing solutions on selected physiological parameters (metal uptake, chlorophyll a fluorescence, assimilation pigment composition, thiobarbituric acid-reactive substance production, and ergosterol content) in the lichens Peltigera rufescens and Cladina arbuscula subsp. mitis growing on historic copper mine-spoil heaps at ?ubietová-Podlipa, Slovakia. Physiological measurements did not confirm significantly higher sensitivity to Cd and Ni of the cyanolichen P. rurescens compared to the green-algal lichen C. arbuscula subsp. mitis. Under natural conditions, C. arbuscula subsp. mitis is able to grow directly on copper mine heaps of Central Slovakia, while P. rufescens grows only on their margins. A crucial factor for this limited distribution of P. rufescens may be, at least in part, the higher intracellular accumulation of metals. Although lichen photobionts are generally regarded as key elements of lichen sensitivity, further research is necessary to elucidate this point since the higher levels of intracellular Cd and Ni do not allow to regard cyanobacterial photobionts of P. rufescens as more sensitive than the eukaryotic ones of C. arbuscula subsp. mitis.     

The effect of an experimentally induced acute mastitis on the test results of an Ostertagia ostertagi milk ELISA

Antibody levels against Ostertagia ostertagi in the milk are a promising parameter to identify dairy cows or herds with production losses due to gastrointestinal nematodes. However, milk antibody levels can be influenced by udder-related factors. In this study, the effect of an experimentally induced mastitis on the test results (ODR) of a milk O. ostertagi ELISA was investigated. Twenty-five cows that were naturally infected with gastrointestinal nematodes, were inoculated in their left udder quarters with Escherichia coli P4:O32 and quarter milk samples were collected at several intervals from 24 h before until 144 h after experimental infection. The effect of the contribution of milk from one or more infected quarters on the bulk tank milk ODR was estimated, based on a titration experiment. The mean O. ostertagi antibody levels of the infected udder quarters were significantly (P < 0.001) higher than those of the uninfected udder quarters at each sampling time post-infection. The largest difference was observed at 24 h post-infection with a mean difference of 0.251 ODR (95%CI: 0.172; 0.330). There was also a significant increase (P < 0.001) in total IgG levels with the largest difference being observed at 24 h post-infection. Highly significant (P < 0.005) correlation coefficients were observed between O. ostertagi ODR, total IgG ODR, Na+ and Cl- ion concentration and log transformed somatic cell counts at 24 h post-infection. The results demonstrate that an acute mastitis causes a flow of specific and non-specific antibodies from serum to milk with a subsequent increase in the O. ostertagi ODR values. The effect of the contribution of milk from infected quarters on the bulk tank milk O. ostertagi ODR was estimated to be minor if the relative number of infected quarters is small (< 3%).     

Mental notes in tracking BVDV carriers

The detection and elimination of animals persistently infected with bovine viral diarrhoea virus (BVDV) is the key to BVD control. This method has proven to be very efficient in eradicating BVDV in a herd. Several pitfalls in the detection procedure can make that some persistently infected (PI) animals do not get identified or are removed too late, supporting the assumption that circulation of the virus could be possible in absence of PI animals. Furthermore the risk of reintroduction is high since the prevalence of BVD is high in the Netherlands and Belgium. Based on both practical experience and literature, here we review critical control points in order to minimise the risk of a false negative BVDV screening.     

Contour furrows for in situ soil and water conservation, Tigray, Northern Ethiopia

In Tigray (Northern Ethiopia), soil moisture has been identified as the most limiting factor in agricultural production; on the other hand, loss of rain water through runoff as well as the induced soil loss has been determined as a critical problem in the region in the last two to three decades. To alleviate the above paradox, the government has mobilized communities and resources for the construction of physical soil and water conservation structures (stone bunds, terraces) in almost all land uses. However, yield improvement was mainly concentrated within the vicinity of the structures and runoff continued to overtop the structures, as no measures for in situ soil conservation were taken. The terwah system, consisting of traditional ploughing followed by making every 1.5–2 m contour furrows, and permanent raised beds with contour furrows at 60–70 cm interval treatments, were considered and evaluated as practices that could increase the efficiency of in situ water utilization and soil conservation. An experiment was started in Gum Selasa, which is one of the drought prone areas in Tigray, whereby runoff volume and sediment load were measured after every rain event. Permanent raised beds with contour furrows at 60–70 cm interval significantly (P < 0.05) reduced runoff volume, runoff coefficient and soil loss as compared to traditional ploughing: 255, 381 and 653 m³ ha⁻¹ runoff was recorded from permanent bed, terwah and traditional ploughing, respectively during the whole cropping season. The above runoff induced 4.7 t ha⁻¹ soil loss from permanent bed, 7.6 t ha⁻¹ from terwah and 19.5 t ha⁻¹ from traditional ploughing. Overall, contour furrows and permanent raised beds can be part of the ongoing intensification process which includes physical soil and water conservation, slope reforestation, irrigation development and agro forestry in crop lands. Moreover, the use of permanent raised beds if combined with crop mulching and crop diversification is an important component for the development of sustainable conservation agriculture practices in the region.