With the electro–ultrafiltration (EUF) technique, the plant availability of several plant nutrients in soils can be characterized. The basic principle of EUF is that an electric field is induced using platinum electrodes. Ions in the soil suspension move either to the cathode or to the anode and are filtrated through ultra‐membrane filters. In the standard EUF procedure, two extractions steps are used: 30 min at 20°C and 5 min at 80°C. However, the determination of micronutrients and heavy metals with the standard EUF procedure is not possible, because the solubility of these elements in water is low and most of the watersoluble elements are precipitated when passing the platinum electrodes. The addition of DTPA, a well known complexing agent, during a third EUF fraction (5 min at 80°C) enables extraction of micronutrients and heavy metals. Highest concentrations in the 33 soils of the study were found for iron, followed by zinc, manganese, lead, copper, and nickel. Lower concentrations were obtained for cobalt, chromium, cadmium, and molybdenum. For two soils, the EUF/DTPA procedure was compared to CaCl2/DTPA and EDTA soil extraction methods, showing that higher or comparable amounts were found with CaCl2/DTPA and much higher amounts with the EDTA method. These results reveal that the EUF/DTPA technique in principle can be used for the determination of plant‐available micronutrients and heavy metals. However, in a next step the relationship between EUF/DTPA‐extractable elements and their availability for plants needs to be quantified. 相似文献
Partition coefficients KP of nonylphenol (NP) in soil were determined for 193 soil samples which differed widely in content of soil organic carbon (SOC), hydrogen activity, clay content, and in the content of dissolved organic carbon (DOC). By means of multiple linear regression analysis (MLR), pedotransfer functions were derived to predict partition coefficients from soil data. SOC and pH affected the sorption, though the latter was in a range significantly below the pKa of NP. Quality of soil organic matter presumably plays an important but yet not quantified role in sorption of NP. For soil samples with SOC values less than 3 g kg?1, model prediction became uncertain with this linear approach. We suggest that using only SOC and pH data results in good prediction of NP sorption in soils with SOC higher than 3 g kg?1. Considering the varying validity of the linear model for different ranges of the most sensitive parameter SOC, a more flexible, nonlinear approach was tested. The application of an artificial neuronal network (ANN) to predict sorption of NP in soils showed a sigmoidal relation between KP and SOC. The nonlinear ANN approach provided good results compared to the MLR approach and represents an alternative tool for prediction of NP partitioning coefficients. 相似文献
A new method for permanent registration of pH value in mineral soil input of an acid forest soil The organic top layers of acid forest soils in low mountain ranges of Germany which receive acid precipitation are of special ecological interest to the observation for their saisonal chemical behaviour. Root systems of young spruce forests tend to accumulate in these layers because of Al-toxicity in mineral soil. Conventional procedures for a weekly sampling of soil solution do not account for short term events. Thus, a measuring device for permanent pH-logging of soil solution in mineral soil input was developed. A microprocessor controls the vacuum in the ceramic cups containing pH-glass electrodes in order to maintain steady water flux into the cups. The accuracy of the measured pH was tested with a theoretical equilibrium modell concerning CO2-degassing and with a laboratory experiment. Below pH 4.7 no influence of CO2-losses on the pH inside the cups occurs. Permanent measurements in mineral soil of a spodosol in The Fichtelgebirge showed fluctuations of higher pH values immediately after precipitation and decreasing values later on. In late spring this behaviour is not yet pronounced. 相似文献
A database which holds results of field and laboratory experiments on the impact of subsoil compaction on physical and mechanical soil parameters and on crop yields and environmental impact is being developed within the EU sponsored concerted action (CA) project “Experiences with the impact of subsoil compaction on soil, crop growth and environment and ways to prevent subsoil compaction”. The database accumulates and can provide all available data from the participants of the European Union countries, and is compatible with the European Soil Database and other related databases.
More than 600 sets of data (Excel workbooks) from participants from the European Union, plus Poland, Switzerland and Norway are included in the database. Through a similar EU sponsored CA, Eastern European countries are expected to deliver 260 sets of data thus bringing the total number of Excel workbooks to approximately 860. In total, the database will contain approximately 13,500 data spreadsheets.
The objective of the database is to collect data on subsoil compaction, to store it in a structured format and to make it available for analysis and use. Thereby it will enable elucidation of the impact of subsoil compaction on soil properties, crop yields and environment and evaluate the vulnerability of soils to compaction. 相似文献
At the end of waste disposal in 2005, a temporary mineral system was constructed to cover the waste body of the municipal landfill in Rastorf (N Germany). The aim of this study was to evaluate the effectiveness of this temporary cover system in limiting the infiltration of surface water into the waste body. The numerical modeling for the hydrological year 2012 was performed in FEFLOW 6.0. The required input data for modeling were achieved by laboratory measurements of the saturated hydraulic conductivity and the water retention characteristics of the mineral layers. The assumed initial and boundary conditions were based on in‐situ measurements of matrix potential and volumetric water content at three different measuring points by tensiometers, FDR sensors and observed meteorological conditions. The model was applied according to Darcy's and Richards' equations for variably saturated flow. Our results allowed assessing the components of water balance for a temporary cover system, especially water seepage into the waste body. The correlation between the measured and modeled volumetric soil water content in the layered temporary cover system was observed (R2 = 0.56 to 0.90). Deviations between the measured and modeled values are superficially related to the soil´s heterogeneity. In conclusion, the measured and modeled water balance parameters indicate that the temporary coverage system remains effective in limiting the infiltration rate. However, our studies revealed that the calculated and measured water seepage exceeded the values allowable by the German regulations. Additional studies have to assess variations in the soil water characteristics caused by weather‐related wetting and drying cycles and influence of waste settlement changing the profile of slope. 相似文献
Anoestrous dairy cows in seasonally calving herds in the Macalister Irrigation District of Gippsland, Victoria were treated at the start of the mating period with a progesterone releasing intravaginal device (CIDR). The CIDR was inserted for 7 days and 400 IU of PMSG was injected intramuscularly at removal. There was no clinically useful difference among cows receiving the CIDR, a placebo and untreated cows in the interval from treatment to either first oestrus or conception, the conception rate to first service or percent pregnant by the end of mating. Analyses of data from 2-year-old cows, older cattle, cows calved at least 45 days or cows calved at least 55 days and cows treated 3 weeks after the start of mating did not show improved reproductive performance following treatment with the CIDR. 相似文献