Reactions of phosphorus with sediments in fresh and marine waters

Abstract. The interactions of P with soils and sediments are examined in the context of transport processes from land, through rivers to estuaries and coastal waters. In soil erosion, selective size fractionation and preferential sorption to finer solids is crucial in the transport of P to water courses. Problems in quantifying the sorption affinity and equilibrium phosphate concentration (EPC) of mixtures of different soils and sediments are identified. Riverine transport of P by suspended solids is usually very important and examples of the changes in the amount and composition of particulate P (PP) concentration during storm events are discussed. Increased P content of solids during the first autumn storms, probably reflect the resuspension of accumulated stream bed-deposits. The fate of P in estuaries and their importance as possible long-term sinks of P are discussed. The relatively high concentrations of dissolved P associated with riverine inputs are to some extent buffered by the relatively high concentrations of suspended sediments resulting from tidal flows. Phosphorus may be released during transport to the sea due to decreases in the EPC, increases in salinity and release from bottom sediments as a result of low oxygen conditions.     

Influence of organic by-products and nitrogen source on chemical and microbiological status of an agricultural soil

We assessed the influence of the addition of four municipal or agricultural by-products (cotton gin waste, ground newsprint, woodchips, or yard trimmings), combined with two sources of nitrogen (N), [ammonium nitrate (NH₄NO₃) or poultry litter] as carbon (C) sources on active bacterial, active fungal and total microbial biomass, cellulose decomposition, potential net mineralization of soil C and N and soil nutrient status in agricultural soils. Cotton gin waste as a C source promoted the highest potential net N mineralization and N turnover. Municipal or agricultural by-products as C sources had no affect on active bacterial, active fungal or total microbial biomass, C turnover, or the ratio of net C:N mineralized. Organic by-products and N additions to soil did not consistently affect C turnover rates, active bacterial, active fungal or total microbial biomass. After 3, 6 or 9 weeks of laboratory incubation, soil amended with organic by-products plus poultry litter resulted in higher cellulose degradation rates than soil amended with organic by-products plus NH₄NO₃. Cellulose degradation was highest when soil was amended with newsprint plus poultry litter. When soil was amended with organic by-products plus NH₄NO₃, cellulose degradation did not differ from soil amended with only poultry litter or unamended soil. Soil amended with organic by-products had higher concentrations of soil C than soil amended with only poultry litter or unamended soil. Soil amended with organic by-products plus N as poultry litter generally, but not always, had higher extractable P, K, Ca, and Mg concentrations than soil amended with poultry litter or unamende soil. Agricultural soil amended with organic by-products and N had higher extractable N, P, K, Ca and Mg than unamended soil. Since cotton gin waste plus poultry litter resulted in higher cellulose degradation and net N mineralization, its use may result in faster increase in soil nutrient status than the other organic by-products and N sources that were tested. Received: 15 May 1996     

Conservation tillage and macropore factors that affect water movement and the fate of chemicals

A thorough understanding of how conservation tillage influences water quality is predicated on knowledge of how tillage affects water movement. This paper summarizes the effects of conservation tillage on water movement and quality mainly based on long-term experiments on Luvisols at the North Appalachian Experimental Watershed near Coshocton, OH, USA. Conservation tillage can have a much larger effect on how water moves through the soil than it does on the total amount percolating to groundwater. Soil macroporosity and the proportion of rainfall moving through preferential flow paths often increase with the adoption of conservation tillage and can contribute to a reduction in surface runoff. In some medium- and fine-textured soils most of the water that moves to the subsoil during the growing season (May–October) is probably transmitted by macropores. If a heavy, intense storm occurs shortly after surface application of an agricultural chemical to soils with well-developed macroporosity, the water transmitted to the subsoil by the macropores may contain significant amounts of applied chemical, up to a few per cent, regardless of the affinity of the chemical for the soil. This amount can be reduced by an order of magnitude or more with the passage of time or if light rainstorms precede the first major leaching event. Because of movement into the soil matrix and sorption, solutes normally strongly adsorbed by the soil should only be subject to leaching in macropores in the first few storms after application. Even under extreme conditions, it is unlikely that the amount of additional adsorbed solute transported to groundwater will exceed a few per cent of the application when conservation tillage is used instead of conventional tillage. In the case of non-adsorbed solutes, such as nitrate, movement into the soil matrix will not preclude further leaching. Therefore, when recharge occurs during the dormant season thorough flushing of the soil, whether macropores are present or not, can move the remaining solutes to groundwater. Thus, the net effect of tillage treatment on leaching of non-adsorbed solutes should be minimal.     

Identification of (poly)phenolic compounds in concord grape juice and their metabolites in human plasma and urine after juice consumption

Analysis of Concord grape juice by HPLC with ESI-MS(n), PDA, and fluorescence detection resulted in the identification and quantification of 60 flavonoids and related phenolic compounds, which were present at an overall concentration of 1508 ± 31 μmol/L. A total of 25 anthocyanins were detected, which were mono- and di-O-glucosides, O-acetylglucosides, O-p-coumaroyl-O-diglucosides, and O-p-coumaroylglucosides of delphinidin, cyanidin, petunidin, peonidin, and malvidin. The anthocyanins represented 46% of the total phenolic content of the juice (680 μmol/L). Tartaric esters of hydroxycinnamic acids, namely, trans-caftaric and trans-coutaric acids, and to a lesser extent trans-fertaric acid accounted for 29% of the phenolic content, with a total concentration of 444 μmol/L, of which 85% comprised trans-caftaric acid. Free hydroxycinnamic acids were also quantified but contributed to <1% of the total phenolic content (8.4 μmol/L). The other groups of polyphenolic compounds present in the juice, accounting for 24% of the total, comprised monomeric and oligomeric units of (epi)catechin and (epi)gallocatechin (248 μmol/L), flavonols (76 μmol/L), gallic acid (51 μmol/L), and trans-resveratrol (1.5 μmol/L). The bioavailability of the (poly)phenolic compounds in 350 mL of juice was investigated following acute intake by healthy volunteers. Plasma and urine were collected over 0-24 h and analyzed for parent compounds and metabolites. In total, 41 compounds, principally metabolites, were identified.     

Earthworm-Processed Organic Wastes as Components Of Horticultural Potting Media for Growing Marigold and Vegetable Seedlings

We germinated and grew tomato, pepper, lettuce, and marigold seedlings in a standard commercial soilless plant growth medium (Metro-Mix 360), and in coir/perlite and peat/perlite-based container media substituted with 10% or 20%, by volume, of vermicompost derived from pig manure or food wastes. Half of the treatments were watered with liquid inorganic fertilizer while the other half received only water. Germination rates of tomato, pepper, lettuce, and marigold seeds in the coir/perlite mixture did not differ significantly from that in Metro-Mix 360. However, the germination rate of tomato, pepper and lettuce seedlings was very low in the peat/perlite mixture. Substituting some of the peat/perlite mixtures with equal amounts of vermicomposts, particularly pig manure vermicompost, enhanced germination rates greatly, making it comparable to that in the commercial medium (Metro-Mix 360). Pepper, lettuce, and marigold seedlings grown in Metro-Mix 360, which already contains a starter nutrient fertilizer in its formulation, had greater root and shoot dry weights than those grown in the control media (coir/perlite mix and peat/perlite mix). Substituting coir/perlite and peat/perlite mixtures with 10% or 20% of either vermicompost enhanced the growth of seedlings significantly, resulting in an overall plant growth as good as and sometimes better than that in Metro-Mix 360. When the plants were provided daily with a complete fertilizer solution, marigold seedlings in peat-based substrate with 20% pig waste vermicompost, and lettuce seedlings in both coir and peat-based substrates, mixed with 20% food wastes vermicompost, produced greater shoot dry weights than those grown in the commercial potting medium. The growth enhancements tended to be greater in peat/perlite-based mixes than in coir/perlite-based mixes, more so with the addition of pig manure vermicompost than with food waste vermicompost. Earthworm-processed pig manure and food wastes would be suitable materials for inclusion into the formulation of soilless potting media, since substitution of these media with relatively low concentrations of vermicomposts can promote plant growth.     

Growth and magnesium uptake of tall fescue lines at high and low potassium levels 1

Five tall fescue (Festuca arundinacea Schreb.) clonal lines with diverse root and xylem diameters were grown in nutrient solutions with magnesium (Mg) concentrations of 42, 125 and 250 μM and potassium K concentrations of 133 and 333 μM. Leaf Mg concentrations increased with increasing Mg rates at both low and high K concentrations. The tall fescue line with the largest root and xylem diameters had low leaf Mg concentrations, indicating a possible increased Mg tetany potential when consumed by cattle. The response of the K/(Mg+Ca) ratio in the plant, an indicator of tetany potential, to varying solution Mg at low and high K was determined for each of the five lines. No Mg effects or interactions were significant. Line, K, and line x K effects were all significant for the K/(Mg+Ca) ratios. The line with the largest root and xylem diameters had the highest tetany potential (highest cation ratio). Higher solution K gave higher K/(Mg+Ca) ratios.     

Predicting soil workability and fragmentation in tillage: a review

Soil workability and friability are required parameters to consider when creating suitable seedbeds for crop establishment and growth. Knowledge of soil workability is important for scheduling tillage operations and for reducing the risk of tillage‐induced structural degradation of soils. A reliable evaluation of soil workability implies a distinctive definition of the critical water content (wet and dry limits) for tillage. In this review, we provide a comprehensive assessment of the methods for determining soil workability, and the effects of soil properties and tillage systems on soil workability and fragmentation. The strengths and limitations of the different methods for evaluating the water content for soil workability, such as the plastic limit, soil water retention curve (SWRC), standard Proctor compaction test, field assessment, moisture‐pressure‐volume diagram, air permeability and drop‐shatter tests are discussed. Our review reveals that there is limited information on the dry limit and the range of water content for soil workability for different textured soils. We identify the need for further research to evaluate soil workability on undisturbed soils using a combination of SWRC and the drop‐shatter tests or tensile strength; (i) to quantify the effects of soil texture, organic matter and compaction on soil workability; and (ii) to compare soil water content for workability in the field with theoretical soil workability, thereby improving the prediction of soil workability as part of a decision support system for tillage operations.     

A new hoe share design for weed control: measurements of soil movement and draught forces during operation

This research introduces a new share design (L-share) that reduces the undesired random soil movement, providing a more controlled disturbance of the upper soil layer. Purpose: The aim of this study was to evaluate draught forces and soil movements when operating the new share. Materials and Methods: Experiments were conducted in a laboratory set-up using a soil bin with a fine loamy soil texture. The soil was compacted to a bulk density of 1500?kg?m^?3, with a penetration index of 486?kPa and a mean water content of 10%. The cultivation depths were 30, 50 and 70?mm and the operation speeds were 0.84, 1.67 and 2.31?m?s^?1. Cubes were used to measure soil movement by recording the displacement from their initial positions. The soil surface and furrow profile were measured by using a 2D laser range scanner. Results: The results showed that increasing operation speed and cultivation depths generally increased draught forces and soil movement. Changing the cultivation depth from 30 to 50?mm resulted in a 63% greater longitudinal force (F_x), and 71% greater F_x when increasing the cultivation depth from 50 to 70?mm. Conclusion: The study showed that the new L-share mounted on a modified spring tine only causes minor soil movement and thereby minimising the undesirable soil movement.     

High-latitude forcing of the South American summer monsoon during the Last Glacial

The climate of the Last Glacial period (10,000 to 110,000 years ago) was characterized by rapid millennial-scale climate fluctuations termed Dansgaard/Oeschger (D/O) and Heinrich events. We present results from a speleothem-derived proxy of the South American summer monsoon (SASM) from 16,000 to 50,000 years ago that demonstrate the occurrence of D/O cycles and Heinrich events. This tropical Southern Hemisphere monsoon reconstruction illustrates an antiphase relationship to Northern Hemisphere monsoon intensity at the millennial scale. Our results also show an influence of Antarctic millennial-scale climate fluctuations on the SASM. This high-resolution, precisely dated, tropical precipitation record can be used to establish the timing of climate events in the high latitudes of the Northern and Southern Hemispheres.     

Vesicular glutamate transporters 1 and 2 target to functionally distinct synaptic release sites

Vesicular glutamate transporters (VGLUTs) 1 and 2 show a mutually exclusive distribution in the adult brain that suggests specialization for synapses with different properties of release. Consistent with this distribution, inactivation of the VGLUT1 gene silenced a subset of excitatory neurons in the adult. However, the same cell populations exhibited VGLUT1-independent transmission early in life. Developing hippocampal neurons transiently coexpressed VGLUT2 and VGLUT1 at distinct synaptic sites with different short-term plasticity. The loss of VGLUT1 also reduced the reserve pool of synaptic vesicles. Thus, VGLUT1 plays an unanticipated role in membrane trafficking at the nerve terminal.