Tracking the Transport of Silver Nanoparticles in Soil: a Saturated Column Experiment

Silver nanoparticles (AgNPs) can enter the environment when released from products containing them. As AgNPs enter soil, they are often retained in the soil profile and/or leached to the groundwater. This research assessed the transport of AgNPs in their “particle form” through the soil profile using a series of columns. Three soil types were put into soil columns: LSH (loam with high organic matter (OM)), LSL (loam with low OM), and Sand (no OM). The results showed that AgNP transport and retention in soil as well as particle size changes are affected by soil organic matter (OM) and the cation exchange capacity (CEC) of soil. OM affected the transport and retention of AgNPs. This was evident in the LSH columns where the OM concentration was the highest and the AgNP content the lowest in the soil layers and in the effluent water. The highest transported AgNP content was detected in the Sand columns where OM was the lowest. CEC had an impact on the particle size of the AgNPs that were retained in the soil layers. This was clear in columns packed with high CEC-containing soils (LSL and LSH) where AgNP particle size decreased more substantially than in the columns packed with sand. However, the decrease in AgNP sizes in the effluent water was less than the decrease in particle size of AgNPs transported through but retained in the soil. This means that the AgNPs that reached the effluent were transported directly from the first layer through the soil macropores. This work highlights the ability to track AgNPs at low concentrations (50 μg kg^?1) and monitor the changes in particle size potential as the particles leach through soil all of which increases our knowledge about AgNP transport mechanisms in porous media.     

Factors determining soil nutrient distribution in a small-scaled watershed in the purple soil region of Sichuan Province, China

Determining soil nutrient distribution is critical to identify sites which are at risk of N and P loading. Equally important are determining factors that influence such distribution (e.g. land use, land management, topography, etc.). In this research, soil nutrient distribution and its influencing factors were studied in a small-scaled watershed in the purple soil region of Sichuan Province, China. The watershed is 1.3 km² with a complex land management system including agriculture and forestry. Surface soil samples (0–20 cm) from 48 sites within the watershed were collected in the spring of 1999 and analysed for chemical properties. When spatial distribution patterns of soil organic matter and soil nutrients were considered, several patterns were evident. Soil organic matter and total nitrogen coincided with high soil nutrients in the center of the watershed. Total phosphorus was linked to low soil nutrient contents on hilltops, while total potassium was characterized by low variability and high soil nutrient content throughout the watershed. Water-soluble nutrients in soils were highly variable throughout the watershed. Results of this study indicate that land use, topography and other variables play important roles in controlling the spatial distribution of most soil nutrients. However, the relative roles of these indices were nutrient specific. The relationship was therefore complex. Land use, silt, and sand content contributed to a high level of heterogeneity for soil organic matter and total nitrogen with the former being the dominant factor. Land use, particle size distribution (silt and sand) and topographic factors (slope and elevation) contributed to the variability of total phosphorus. However, particle size distribution and topographic factors were the dominant factors affecting total phosphorus. Elevation influenced the concentration of total potassium and land use controlled the concentration of dissolved phosphorous. No significant relationship was found between the studied characteristics and nitrate nitrogen.     

Dynamic changes of nitrogen and phosphorus losses in ephemeral runoff processes by typical storm events in Sichuan Basin, Southwest China

This study was carried out in the Xujiawan watershed in Sichuan Province, China. The area is characterized by easy weathering of bedrock (sedimentary sandstone and shale) and vulnerability to erosion due to coarse soil texture and weak soil structure. The objective of this study was to understand the dynamics of nitrogen (N) and phosphorus (P) losses during typical storm events. The results showed that runoff generation was sudden and ephemeral, giving rise to flash floods with sharp, narrow hydrographs and short time lags in this type of agricultural ecosystems. The time lag effect of runoff formation depended on soil conditions before storm events. Suspended solids (SS) concentration peaks occurred at the beginning of the storm flow and decreased as rainfall progressed. Meanwhile, SS losses increased at the beginning of runoff flow, then decreased due to flow volume change. Concentrations of NO₃⁻-N were four times higher than NH₄⁺-N in runoff. NO₃⁻-N concentrations first decreased as runoff volume increased until reaching relatively low concentrations, then increased again as runoff volume decreased. Both NH₄⁺-N and dissolved phosphorus (DP) in runoff remained at low concentrations with a small magnitude of variation. Suspended particulate nitrogen (SN) was the dominant N form. Losses of NO₃⁻-N were higher than NH₄⁺-N in the dissolved nitrogen (DN). Suspended particulate nitrogen losses were several times higher than DN in the early period of runoff formation, but the ratio of SN/DN decreased gradually as rainfall progressed, and by the end of the storm event the rate was lower than 1, indicating DN took the main form after the early physical flush. In the early period of storm events, suspended particulate phosphorus (SP)/DP was above 70 and decreased as rainfall progressed, but remained higher than 1, which showed that SP was the main form of P loss. The transport of N, and particularly P, was intimately linked to sediment in the runoff, indicating an obvious soil erosion-associated nutrient transport, especially in relation to P loss.     

Uneven moisture patterns in water repellent soils

In the Netherlands, water repellent soils are widespread and they often show irregular moisture patterns, which lead to accelerated transport of water and solutes to the groundwater and surface water. Under grasscover, spatial variability in soil moisture content is high due to fingered flow, in arable land vegetation and microtopography play a dominant role. Examples are given of uneven soil moisture patterns in water repellent sand, loam, clay and peat soils with grasscover, and in cropped water repellent sandy soils. In addition, the influence of fungi on inducing soil moisture patterns is illustrated as well.     

Autopilot for a combine harvester

This paper describes the design of a robust automatic guidance system for a combine harvester. The automatic steering system controls the harvester based on the measured position of the swath on the field. The swath is detected using a laser scanner. The translation and rotation of the machine are taken into account to recalculate the swath's relative position every time step. With the help of a model of the harvester (derived in this paper), the desired wheel position is calculated in function of the desired bearing change. The desired wheel position is then transmitted over the CAN network of the harvester to the actuator.     

Superfast muscles set maximum call rate in echolocating bats

As an echolocating bat closes in on a flying insect, it increases call emission to rates beyond 160 calls per second. This high call rate phase, dubbed the terminal buzz, has proven enigmatic because it is unknown how bats are able to produce calls so quickly. We found that previously unknown and highly specialized superfast muscles power rapid call rates in the terminal buzz. Additionally, we show that laryngeal motor performance, not overlap between call production and the arrival of echoes at the bat's ears, limits maximum call rate. Superfast muscles are rare in vertebrates and always associated with extraordinary motor demands on acoustic communication. We propose that the advantages of rapid auditory updates on prey movement selected for superfast laryngeal muscle in echolocating bats.