Structure of a thiol monolayer-protected gold nanoparticle at 1.1 A resolution

Structural information on nanometer-sized gold particles has been limited, due in part to the problem of preparing homogeneous material. Here we report the crystallization and x-ray structure determination of a p-mercaptobenzoic acid (p-MBA)-protected gold nanoparticle, which comprises 102 gold atoms and 44 p-MBAs. The central gold atoms are packed in a Marks decahedron, surrounded by additional layers of gold atoms in unanticipated geometries. The p-MBAs interact not only with the gold but also with one another, forming a rigid surface layer. The particles are chiral, with the two enantiomers alternating in the crystal lattice. The discrete nature of the particle may be explained by the closing of a 58-electron shell.     

Novel Colloidal Interactions in Anisotropic Fluids

Small water droplets dispersed in a nematic liquid crystal exhibit a novel class of colloidal interactions, arising from the orientational elastic energy of the anisotropic host fluid. These interactions include a short-range repulsion and a long-range dipolar attraction, and they lead to the formation of anisotropic chainlike structures by the colloidal particles. The repulsive interaction can lead to novel mechanisms for colloid stabilization.     

溴虫腈与哒螨灵对朱砂叶螨的联合作用

为明确溴虫腈与哒螨灵的联合杀螨活性,采用玻片浸渍法测定了溴虫腈与哒螨灵不同配比混剂对朱砂叶螨雌成螨的杀螨活性,并以共毒因子法和共毒系数法评价混剂的增效作用。结果表明,溴虫腈和哒螨灵对朱砂叶螨雌成螨处理后24 h的致死中质量浓度(LC50)分别为8.80、17.69mg/L;溴虫腈与哒螨灵的质量比为49∶51、47∶53、45∶55时增效最明显,对朱砂叶螨处理后24 h的共毒系数分别为177.94、178.49、173.73,LC50分别为6.65、6.72、7.00 mg/L,其毒力分别是哒螨灵的2.66倍、2.63倍、2.53倍。因此,45%~49%溴虫腈与51%~55%哒螨灵混合具有显著的增效作用。     

Amplification of Bovine Viral Diarrhoea Virus Introduced into an In Vitro Embryo Production System Via Oocytes from Persistently Infected Cattle

The purpose of this study was to determine whether or not embryos derived from in vitro fertilization of oocytes from persistently infected (PI) cattle would contain infectious virus. Three in vitro embryo production treatment groups were assessed: 1) oocytes and uterine tubal cells (UTC) free of bovine viral diarrhoea virus (BVDV) (negative control), 2) oocytes free of BVDV fertilized and cultured in media containing UTC obtained from PI heifers, and 3) oocytes from PI heifers fertilized and cultured in media containing UTC free of BVDV. The developmental media, UTC and embryos (individual or groups of five) were assayed for virus. Virus was not isolated from any samples in treatment group 1. As shown in previous studies, a proportion of embryo samples were positive for BVDV in treatment group 2. In treatment group 3, the virus associated with the oocytes contaminated the developmental media and infected susceptible co-culture cells used during fertilization and culture. In addition, 65% (11/17) of the degenerated ova from treatment group 3 had infectious virus associated with them. While none of the ova developed into transferable embryos, the study did confirm that use of oocytes from PI cows could lead to amplification of BVDV and cross contamination during in vitro embryo production.     

以全产业链思维优化甘肃省“粮改饲”生产力布局

用全产业链思维优化“粮改饲”生产力布局具有重要的现实意义和理论价值。本文以甘肃省为例,总结甘肃省“粮改饲”工作已取得的工作成效和不足,论述了“粮改饲”构建全产业链的必要性,初步探讨了甘肃省“粮改饲”全产业链模式和布局优化,并提出完善相关支持政策、培育壮大龙头企业、高度重视品牌建设和创新科技带动引领4条对策建议。 [关键词]全产业链|粮改饲|生产力布局|甘肃省