合成条件对氧气氧化合成水钠锰矿的影响

A pot experiment was conducted to determine the dynamics of soil microbial biomass in a rainfed soil under wheat cultivation at the University of Arid Agriculture, Rawalpindi, Pakistan. The treatments applied were: 1) a control (CK), 2) NPK (0.44-0.26-0.18 g pot^-1), 3) farmyard manure (FYM, 110 g pot^-1), 4)poultry manure (PM, 110 g pot^-1), 5) FYM (110 g pot^-1) NPK (0.44-0.26-0.18 g pot^-1), 6) poultry manure (PM, 110 g pot^-1) NPK (0.44-0.26-0.18 g pot^-1), 7) FYM (110 g pot^-1) NPK(S) (0.44-0.26-0.18 g pot^-1 one half of the NPK at sowing and the other half one month after sowing), and 8) PM (110 g pot^-1) NPK(S) (0.44-0.26-0.18 g pot^-1, one half of the NPK applied at sowing and the other half one month after sowing). The experiment was laid out using a completely randomized design with three replications. Microbial biomass C, N and P contents increased continuously from the beginning of the experiment up to the three-leaf stage. A slight decline was observed at the tillering stage in all treatments except with the organic manures NPK(S) treatments. After tillering there was an increase in all treatments to the recorded maximum point at the full heading stage in all treatments except with the organic manures NPK(S) treatments. In the FYM NPK(S) and PM NPK(S) treatments; however, there was a continuous increase in microbial biomass up to the heading stage. At the harvesting stage a sharp decline was noted in all treatments. The C:N ratio of microbial biomass in tested soil ranged from 7.8 to 11.3, while C:P ratio of microbial biomass in the tested soil ranged from 22.6 to 35.1 throughout all growth stages of the wheat crop.     

菜籽饼肥不同用量对烤烟产量及质量的影响

试验研究了菜籽饼肥不同用量对烤烟产量和质量的影响。结果表明,施25%熟饼肥 75%复合肥的处理烤烟产量、产值最高,在施用饼肥纯N占25%以上时,随着饼肥用量的增加,烤烟产量、产值呈下降态势。饼肥用量相同时,腐熟饼肥产量、产值高于生饼肥。25%熟饼肥 75%复合肥处理的烟叶内在化学品质协调性较好,单施复合肥或单施菜籽饼肥(包括生饼和熟饼肥)都不利于烟叶内在化学品质的协调。     

关于中国农地整理中预测性环境影响评价问题

农地整理作为中国现阶段土地整理的主要形式，对其进行环境影响评价是必要的。在此背景下，该文对农地整理中环境影响评价进行综合分析，指出了农地整理中环境影响评价现状及存在的问题等，并从景观、土壤、生物多样性、水资源、植被、大气等几个方面，对农地整理存在的潜在环境影响进行了分析，在此基础上提出了建立农地整理环境影响评价制度、农地整理环境影响评价的内涵和方法体系，以期对农地整理中环境影响评价有所借鉴。     

Characterization of intergeneric hybrids of <Emphasis Type="Italic">Erianthus rockii</Emphasis> and <Emphasis Type="Italic">Saccharum</Emphasis> using molecular markers

Erianthus rockii, a wild relative of sugarcane, is drought and cold tolerant, and both are potentially important agronomic traits to the sugarcane industry worldwide. As such it is of interest as a source of parental germplasm to sugarcane breeders and is currently being used in sugarcane introgression programs in both China and Australia. To date morphological characters have been used to verify the putative hybrids produced. Two crosses were generated between two different Saccharum species and two E. rockii accessions. Over 400 AFLP markers were used to identify the intergeneric hybrid progeny as well as determine hybrid diversity. Both crosses generated hybrids but efficiency levels were very different and are probably related to the different Saccharum parent used in each cross. Cross 1 was between a Saccharum officinarum and E. rockii and generated 100% hybrid progeny. Cross 2, however, was between a sugarcane hybrid (S. officinarum × Saccharum spontaneum) and E. rockii and only 10% of the progeny were intergeneric hybrids. Inheritance of markers in the progeny was analysed and for both crosses there were equal numbers of markers from both parents indicating n + n transmission of chromosomes. This is the first verification of E. rockii hybrids with molecular markers. It may now be possible to exploit genes of value from E. rockii in sugarcane breeding programs.     

关于淤地坝管护问题的探讨

随着淤地坝建设的大规模开展,加强管护在淤地坝的运行中显得越来越重要。山西省探索出了产权制度改革、“护坝田”制度等行之有效的办法,在一定程度上保障了坝系工程的安全运行和效益的持续发挥。针对淤地坝管护中存在的问题,提出了进一步推向市场、依法管护、深化产权制度改革等建议。     

碳铵粒肥在非石灰性水稻土上深施的氮素供应状况

碳铵压粒深施是提高碳钱肥效、减少损失的一项技术措施.现已在生产上推广应用.为了明确碳铁粒肥深施省肥增产的机理,我们在1976-1977年应用Nu标记肥料进行了盆栽试验和田间试验.另文(本所长效肥工作组,1978)对1976年的试验结果作了总结,初步阐明碳钱粒肥深施除具有一般氮肥深施减少肥料氮素气态损失和随水流失的作用外,还具有集中施肥的好处,能够减少肥料氮素在土壤中的固定,增进作物对肥料氮素的吸收.本文是1977年试验结果的初步总结,目的是说明碳按粒肥在水稻土上深施的氮素供应状况.     

长江三峡花岗岩区林地优先流影响因子分析

为了研究三峡地区花岗岩林地优先流影响因子，在长江三峡地区曲溪小流域内选定的实验坡面下部，垂直开挖了一个长度为2．9m、深度为2．60m的土壤剖面。在降雨过程中观察优先流过程，分析降雨对优先流的影响。同时对该地区的土壤物理性质和土壤渗透特性进行了测定，分析其对优先流的影响。分析结果表明，影响长江三峡花岗岩区优先流产流的降雨量在26mm（24h降雨量）以上。长江三峡库区的降雨可分为递减降雨型、均匀降雨型、突发降雨型及峰值降雨型4种类型，不同降雨类型对应的优先流过程都表现出相应的降雨过程特征。不同降雨类型的优先流出现时间也各有差异，峰值降雨型降雨产生的优先流出现时间最早，其次是突发降雨型、递减降雨型、均匀降雨型。当一场降雨中的最大降雨强度〉0．075mm／min时，就有可能产生优先流。非毛管孔隙比例较大的土壤中容易形成优先流。研究区林下土壤中粗颗粒含量呈现出由上层至下层逐渐增多的趋势。对于较深层次土壤来说，它们含有的较粗颗粒有利于优先流的形成。优先流的存在使距地表83～110cm土层中土壤稳渗速率较其他土层得以大幅度提高，土层内快速运动的水流又加速了优先流的形成与发展。     

Turnover of interlayer ammonium in loess-derived soil grown with winter wheat in the Shaanxi Province of China

Summary The turnover of interlayer NH _inf4 ^sup+ in a loess-derived agricultural soil from the Shaanxi Province in China was studied. The concentration of ¹⁵N-labeled interlayer NH _inf4 ^sup+ and total interlayer NH _inf4 ^sup+ (labeled + unlabeled) in a soil grown with winter wheat was significantly higher at the beginning of the season (March) than when the crop was mature (June). In a further experiment with winter wheat it was shown that under field conditions the concentration of interlayer NH _inf4 ^sup+ decreased significantly in the two upper soil layers (0–20 and 20–55 cm) during March and in the deeper soil layer (55–75 cm) during April. When the heading stage of wheat was reached, about 200 kg N ha^-1 of interlayer NH _inf4 ^sup+ had been released. During the following growth period (heading until flowering of wheat) the concentration of interlayer NH _inf4 ^sup+ increased significantly in the upper soil layers. Fertilizer application in the form of 70 kg N ha^-1 as urea led to a considerable increase in the nitrate concentration in the upper soil layer but had no influence on the level of interlayer NH _inf4 ^sup+ concentration. It is concluded that interlayer NH _inf4 ^sup+ takes part in the N cycle of the soil and that it contributes to the N nutrition of the crop. NH _inf4 ^sup+ originating from the mineralization of soil organic N may be rapidly incorporated into the interlayer of clay minerals and later released, when the N demand of the crop is high.     

Interactive responses of gala apple fruit volatile production to controlled atmosphere storage and chemical inhibition of ethylene action

Gala apples exposed to the ethylene action inhibitor 1-methylcyclopropene (1-MCP) for 12 h at 20 degrees C were stored at 1 degrees C in air or a controlled atmosphere (CA) maintained at 1 kPa O2 and 2 kPa CO2. Volatile compounds were measured after 4, 12, 20, and 28 weeks plus 1 or 7 days at 20 degrees C. Treatment with 1-MCP and then storage in air or CA or storage in CA without 1-MCP treatment reduced volatile production as compared to apples not treated with 1-MCP stored in air. The reduced production of esters, alcohols, aldehydes, acetic acid, and 1-methoxy-4-(2-propenyl)benzene was observed. Ester production by fruit stored in CA decreased throughout the storage period regardless of previous 1-MCP treatment. The production of esters, alcohols, aldehydes, acetic acid, and 1-methoxy-4-(2-propenyl)benzene by 1-MCP-treated fruit stored in air plus 7 days at 20 degrees C increased after 20 or 28 weeks of storage. Continuous exposure to 417 micromol m(-3) ethylene for 7 days at 20 degrees C after 12 or 28 weeks of storage stimulated production of many volatile compounds, primarily esters and alcohols, by fruit stored in CA or 1-MCP-treated apples stored in air. However, exposure to ethylene had no effect on the production of aldehydes or acetic acid.     

A novel heavy metal chelating agent sixthio guanidine acid for in situ remediation of soils contaminated with multielements: its synthesis,solidification, biodegradability,and leachability

Purpose

The main objectives of the study were to (1) develop a one-step facile procedure for synthesizing a new chemical amendment agent with three chelating groups for solidifying multiple heavy metals, called sixthio guanidine acid (SGA), using guanidine hydrochloride and carbon disulfide as raw reactants and (2) assess its biodegradability, solidification effectiveness, and leachability in remedying soils contaminated with multiple heavy metals of various concentrations compared with other traditional amendment agents.

Materials and methods

Polluted soil samples were collected near a metalliferous mining site of Qixiashan in the southeast of Nanjing, China. Their concentrations were determined at 22.15–320 mg kg^?1 for As, 3.30–29.31 mg kg^?1 for Cd, 115.66–158.65 mg kg^?1 for Ni, 165.04–1677.06 mg kg^?1 for Pb, and 355.6–2426.91 mg kg^?1 for Zn. Biodegradability of SGA was assessed in accordance with GB/T 21831-2008 and OECD-301D. Total concentration of heavy metals was determined according to ISO11466:1995. A modified three-step sequential Community Bureau of Reference (BCR) extraction procedure was used to examine speciation of heavy metals in the soil sample, and concentrations of heavy metals were measured by using inductively coupling plasma optical emission spectrometry (ICP-OES). Leachate extraction tests were carried out before and after the soil sample was solidified with different amendments in accordance with HJ/T 557-2009.

Results and discussion

It is found that the optimal conditions for SGA synthesis are a molar ratio of 4:1, a reaction temperature of 40 °C, and a reaction time of 2 h. Under such conditions, SGA yield is achieved as high as 91.5 %. The bioavailability and mobility of As, Cd, Ni, Pb, and Zn in highly contaminated soils can be reduced via using SGA. Our results indicate that SGA is nonbiodegradative and much more effective than other traditional chemical amendment agents in that it is highly effective in comprehensively solidifying As, Cd, Ni, and Pb.

Conclusions

SGA has the potential for comprehensive in situ remediation of soils contaminated with several heavy metal elements of various concentration levels, and such findings may be used as a guide to design new chemical amendment agents for rehabilitating soils contaminated with heavy metals.